267011-74-5

Basic information

• Product Name: (R)-9-Phenyl-1,4-dithia-8-aza-spiro[4.5]decan-7-one
• Synonyms: (R)-9-Phenyl-1,4-dithia-8-aza-spiro[4.5]decan-7-one
• CAS NO: 267011-74-5
• Molecular Weight: 265.4
• Mol File: 267011-74-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (R)-9-Phenyl-1,4-dithia-8-aza-spiro[4.5]decan-7-one(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-9-Phenyl-1,4-dithia-8-aza-spiro[4.5]decan-7-one(267011-74-5)
• EPA Substance Registry System: (R)-9-Phenyl-1,4-dithia-8-aza-spiro[4.5]decan-7-one(267011-74-5)

Safety Data

• Hazardous Substances Data: 267011-74-5(Hazardous Substances Data)

Upstream product

• 267011-72-3 methyl (S_S,R)-(+)-methyl 3-oxo-5-phenyl-5-(p-toluenesulfinylamino)pentanoate 
• 158009-86-0 (S_S,3R)-(+)-methyl 3-[N-(p-toluenesulfinyl)amino]-3-(phenyl)propanoate 
• 350479-90-2 (S,E)-N-benzylidene-4-methylbenzenesulfinamide 
• 540-63-6 ethane-1,2-dithiol 
• 267011-73-4 (R)-(+)-6-phenylpiperidine-2,4-dione 

Downstream Products

• 3466-80-6 (R)-(+)-6-phenylpiperidine 
• 212560-70-8 (+)-(6R)-6-phenylpiperidin-2-one 

Relevant articles and documents

δ-Amino β-keto Esters, a designed polyfunctionalized chiral building block for alkaloid synthesis. Asymmetric synthesis of (R)-(+)-2-phenylpiperidine and (-)-SS20846A

δ-Amino β-keto esters 3 and 11 are designed polyfunctionalized chiral building blocks for alkaloid synthesis and are prepared in one step from the corresponding sulfinimine (N-sulfinyl imine). Concise highly enantioselective four-step syntheses of 2-phenylpiperidine (7) and SS20846A (14) from 3 and 11, respectively, are described.