158009-86-0

Basic information

• Product Name: (S_S,3R)-(+)-methyl 3-[N-(p-toluenesulfinyl)amino]-3-(phenyl)propanoate
• Synonyms: (S_S,3R)-(+)-methyl 3-[N-(p-toluenesulfinyl)amino]-3-(phenyl)propanoate
• CAS NO: 158009-86-0
• Molecular Weight: 317.409
• Mol File: 158009-86-0.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: (S_S,3R)-(+)-methyl 3-[N-(p-toluenesulfinyl)amino]-3-(phenyl)propanoate(CAS DataBase Reference)
• NIST Chemistry Reference: (S_S,3R)-(+)-methyl 3-[N-(p-toluenesulfinyl)amino]-3-(phenyl)propanoate(158009-86-0)
• EPA Substance Registry System: (S_S,3R)-(+)-methyl 3-[N-(p-toluenesulfinyl)amino]-3-(phenyl)propanoate(158009-86-0)

Safety Data

• Hazardous Substances Data: 158009-86-0(Hazardous Substances Data)

Upstream product

• 79-20-9 acetic acid methyl ester 
• 153277-49-7 (S)-N-benzylidene-4-toluenesulfinamide 
• 1517-82-4 (1R,2S,5R,SS)-(-)-menthyl p-toluenesulfinate 
• 100-52-7 benzaldehyde 
• 1517-82-4 (-)-menthyl p-toluenesulfinate 
• 350479-90-2 (S,E)-N-benzylidene-4-methylbenzenesulfinamide 

Downstream Products

• 1079366-88-3 (R)-2-phenyl-1-(toluene-4-sulfonyl)azetidine 
• 936011-91-5 (S)-2-phenyl-1-tosylazetidine 
• 936012-06-5 C₁₆H₁₇NO₄S 
• 1287731-51-4 (2S,3R)-(+)-methyl 2-methyl-3-[(S)-(4-methylphenylsulfinamido)]-3-phenylpropanoate 
• 103-26-4 Methyl cinnamate 
• 1287731-73-0 (2S,3R)-(+)-N,2-dimethyl-3-[(S)-(4-methylphenylsulfinamido)]-3-phenylpropanamide 
• 1287731-69-4 (2S,3R)-(+)-2-methyl-3-[(S)-(4-methylphenylsulfinamido)]-1,3-diphenylpropan-1-one 
• 1287731-68-3 (2S,3R)-(+)-2-methyl-3-[(S)-(4-methylphenylsulfinamido)]-1-butyl-3-phenylpropan-1-one 
• 1287731-67-2 (2S,3R)-(+)-4-N-[(S)-(p-toluenesulfinyl)]amino-3-methyl-4-phenylbutan-2-one 
• 1287731-53-6 (2S,3R)-(+)-methyl 2-benzyl-3-[(S)-(4-methylphenylsulfinamido)]-3-phenyl-propanoate 
• 1287731-52-5 (2S,3R)-(+)-methyl 2-(2-propenyl)-3-[(S)-(4-methylphenylsulfinamido)]-3-phenylpropanoate 
• 158009-88-2 (R)-3-[(S)-3-Benzyloxy-2-((S)-2-tert-butoxycarbonylamino-butyrylamino)-propionylamino]-3-phenyl-propionic acid methyl ester 
• 158009-87-1 (R)-3-((S)-3-Benzyloxy-2-tert-butoxycarbonylamino-propionylamino)-3-phenyl-propionic acid methyl ester 
• 212560-68-4 (R)-ethyl 5-[(tert-butoxycarbonyl)amino]-5-phenylpentanoate 

Relevant articles and documents

Stereoselective synthesis of activated 2-arylazetidines via imino-aldol reaction

A simple and efficient synthetic route to substituted N-sulfinyl and N-sulfonyl azetidines is described involving imino-aldol reaction of ester enolates with racemic and non-racemic aldimines for obtaining β-amino esters as a key step. These β-amino ester

δ-Amino β-keto Esters, a designed polyfunctionalized chiral building block for alkaloid synthesis. Asymmetric synthesis of (R)-(+)-2-phenylpiperidine and (-)-SS20846A

δ-Amino β-keto esters 3 and 11 are designed polyfunctionalized chiral building blocks for alkaloid synthesis and are prepared in one step from the corresponding sulfinimine (N-sulfinyl imine). Concise highly enantioselective four-step syntheses of 2-phenylpiperidine (7) and SS20846A (14) from 3 and 11, respectively, are described.

Asymmetric Synthesis of (R)-(+)-β-Phenylalanine from (S)-(+)-Benzylidene-p-toluenesulfinamide. Regeneration of the Sulfinimine Precursor

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