27441-79-8Relevant articles and documents
Convergent synthesis of dendrimers via the passerini three-component reaction
Jee, Jo-Ann,Spagnuolo, Lauren A.,Rudick, Jonathan G.
supporting information; experimental part, p. 3292 - 3295 (2012/09/08)
Tuning properties by programming the surface functional group composition of surface-block dendrimers has been limited to dendrimers with only two types of surface functionality (i.e., surface-diblock dendrimers). The Passerini reaction provides dendrimer
Convenient synthesis of pyrrolidines by amphiphilic allylation of imines with 2-methylenepropane-1,3-diols
Kimura, Masanari,Tamaki, Takato,Nakata, Masanori,Tohyama, Katsumi,Tamaru, Yoshinao
supporting information; experimental part, p. 5803 - 5805 (2009/03/11)
(Chemical Equation Presented). A straightforward route: The combination of a palladium catalyst and triethylborane promotes the amphiphilic (nucleophilic-electrophilic) allylation of aldimines, prepared in situ from a wide variety of aromatic and aliphatic aldehydes and amines, with commercially available 2-methylenepropane-1,3-diols to provide pyrrolidines (see scheme).
Studies of intramolecular alkylidene carbene reactions; an approach to heterocyclic nucleoside bases
Hobley, Gerard,Stuttle, Keith,Wills, Martin
, p. 4739 - 4748 (2007/10/03)
A series of investigations into the applications of intramolecular cyclisations of alkylidene carbenes are described. The insertion reaction of the carbene generated from 1,4-di(tert-butyldimethylsilyloxy)-3-benzyloxy-butane-2-one to the benzylic position