27610-20-4

Basic information

• Product Name: benzene-SO-thioperoxol
• Synonyms: Benzenesulphenic acid
• CAS NO: 27610-20-4
• Molecular Formula: C₆H₆OS
• Molecular Weight: 126.1762
• Mol File: 27610-20-4.mol
• Article Data: 7

Chemical Properties

• Boiling Point: 253.8°C at 760 mmHg
• Flash Point: 124°C
• Density: 1.24g/cm³
• Vapor Pressure: 0.00931mmHg at 25°C
• Refractive Index: 1.635
• CAS DataBase Reference: benzene-SO-thioperoxol(CAS DataBase Reference)
• NIST Chemistry Reference: benzene-SO-thioperoxol(27610-20-4)
• EPA Substance Registry System: benzene-SO-thioperoxol(27610-20-4)

Safety Data

• Hazardous Substances Data: 27610-20-4(Hazardous Substances Data)

Upstream product

• 62076-10-2 (tert-butylsulfinyl)benzene 
• 111-48-8 2,2'-thiobis-ethanol 
• 37559-64-1 methoxymethyl benzenesulfenate 
• 302-04-5 Thiocyanate 
• 71-50-1 acetate 
• 14526-03-5 monochloroacetate 
• 20758-58-1 2-methoxyacetate 
• 29650-96-2 pivaloate 
• 37559-63-0 Methoxymethyl phenyl sulfoxide 
• 85970-50-9 (1-Fluoro-nonane-1-sulfinyl)-benzene 
• 85970-60-1 1-Benzenesulfinyl-1-fluoro-nonan-2-ol 
• 85970-61-2 2-Benzenesulfinyl-2-fluoro-1-phenyl-ethanol 
• 85970-51-0 (1-Fluoro-tridecane-1-sulfinyl)-benzene 
• 85970-52-1 (1-Fluoro-heptadecane-1-sulfinyl)-benzene 

Downstream Products

• 1208-20-4 S-phenyl benzenethiosulfinate 
• 4409-79-4 S-phenyl benzenethiosulfinate 
• 108-98-5 thiophenol 
• 618-41-7 Benzenesulfinic acid 
• 884-09-3 phenyl thiobenzoate 
• 934-87-2 S-phenyl thioacetate 
• 70030-52-3 (E)-S-phenyl 3-phenylprop-2-enethioate 

Relevant articles and documents

NANOSTRUCTURES AND METHODS FOR CHEMICALLY SYNTHESIZING NANOSTRUCTURES

The present invention generally relates to nanostructure compositions, as well as methods for the controlled synthesis of nanostructures, such as carbon nanotubes. In some embodiments, methods involving iterative growth of a nanostructure template to homo

Dual Reactivity of Methoxymethyl Benzenesulfonate in Nucleophilic Substitution

Hydrolysis of methoxymethyl benzenesulfenate is catalyzed by both acid and base.Acid-catalyzed hydrolysis is further accelerated by various nucleophiles like halide ions, thiocyanate, dialkyl sulfide, and the substrate itself.The catalytic constants coincide with those for ethyl benzenesulfenate within 2-fold in magnitude.The nucleophilic reactivity strongly suggests the reaction at the sulfenyl sulfur, but examination of the products from the 18O-labeled substrate showed that the bond cleavage occurs mostly between the oxygen and the proformyl carbon except for the acid-catalyzed water reaction which undergoes the S-O cleavage.A mechanism for a nucleophilic reaction at the sulfur to form a sulfurane intermediate which breaks down with the C-O cleavage is presented.The hydrolysis rate is also strongly dependent on the second order of buffer concentrations in carboxylate and tertiary amine buffer solutions.The third-order term involves both the general acid and the conjugate base of the buffer, and the latter reacts at the sulfur as a nucleophile in the rate-determining step but leads to the C-O cleavage in the same way as the other catalytic nucleophiles.

Nucleophilic Catalysis in the Hydrolysis of Methoxymethyl Benzenesulfenate, a Formaldehyde Acetal

Acid-catalyzed hydrolysis of methoxymethyl benzenesulfenate is accelerated by nucleophiles (Cl-, Br-, I-, R2S, AcO-, tertiary amines, and the substrate itself) through the attack at the proformyl carbon while water attacks at the sulfenyl sulfur.