3034-79-5

Basic information

• Product Name: bis(o-toluoyl) peroxide
• Synonyms: bis(o-toluoyl) peroxide;Di-(2-methylbenzoyl)-peroxid;Bis-(2-methylbenzoyl)-peroxide;di-(2-methylbenzoyl)peroxide, = 13% water;Bis-(o-methylbenzoyl) peroxide;Einecs 221-231-5;Peroxide, bis(2-methylbenzoyl)
• CAS NO: 3034-79-5
• Molecular Formula: C₁₆H₁₄O₄
• Molecular Weight: 270.27996
• EINECS: 221-231-5
• Mol File: 3034-79-5.mol
• Article Data: 8

Chemical Properties

• Melting Point: 74 °C(Solv: methanol (67-56-1))
• Boiling Point: 373.4°C (rough estimate)
• Flash Point: 176.5°C
• Appearance: /
• Density: 1.2117 (rough estimate)
• Vapor Pressure: 1.41E-06mmHg at 25°C
• Refractive Index: 1.5447 (estimate)
• CAS DataBase Reference: bis(o-toluoyl) peroxide(CAS DataBase Reference)
• NIST Chemistry Reference: bis(o-toluoyl) peroxide(3034-79-5)
• EPA Substance Registry System: bis(o-toluoyl) peroxide(3034-79-5)

Safety Data

• RIDADR: 3112
• HazardClass: 5.2
• PackingGroup: II
• Hazardous Substances Data: 3034-79-5(Hazardous Substances Data)

Usage

InChI:InChI=1/C16H14O4/c1-11-7-3-5-9-13(11)15(17)19-20-16(18)14-10-6-4-8-12(14)2/h3-10H,1-2H3

Upstream product

• 95-49-8 2-methylchlorobenzene 
• 933-88-0 ortho-toluoyl chloride 
• 98-88-4 benzoyl chloride 
• 16331-45-6 p-ethylbenzoyl chloride 
• 28788-62-7 4-butylbenzoyl chloride 
• 1711-06-4 3-Methylbenzoyl chloride 

Downstream Products

• 118-90-1 ortho-methylbenzoic acid 
• 6639-40-3 1,2-bis(2-chlorophenyl)ethane 
• 23597-23-1 2-methyl-benzoic acid o-tolyl ester 
• 4281-17-8 2,2'-(ethane-1,2-diyl)bisbenzoic acid 
• 98589-01-6 2-<2,2,2-Trichlor-ethyl>-benzoesaeure 
• 51908-28-2 2-(β-cyanoethyl)benzoic acid 
• 87-41-2 2-benzofuran-1(3H)-one 
• 17849-38-6 2-Chlorobenzyl alcohol 
• 89-98-5 2-chloro-benzaldehyde 
• 100313-78-8 2-<2,2-Dichlor-vinyl>-benzoesaeure 
• 1174895-52-3 2-(2'-methyl-[1,1'-biphenyl]-2-yl)pyridine 
• 1349700-49-7 2-(pyridin-2-yl)phenyl 2-methylbenzoate 
• 1333261-95-2 4-chlorobutyl 2-methylbenzoate 
• 32317-26-3 7-methyl-6-phenylphenanthridine 

Relevant articles and documents

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Uncatalyzed, on water oxygenative cleavage of inert C-N bond with concomitant 8,7-amino shift in 8-aminoquinoline derivatives

Oxygenative cleavage of an inert CAr-NH2 bond with concomitant 1,2 amine migration in 8-aminoquinoline derivatives is reported in water at room temperature. The reaction is highly atom- and step-economical as both C- and N-containing fragments of the C-N bond cleavage are incorporated into the target molecule and is effected without the need for N-oxide. The reaction is scalable to gram level, and the products are useful as electrophilic partners for coupling reactions, ligands in catalysis and bioactive compounds.

Copper-catalyzed Csp3-O cross-coupling of unactivated alkyl halides with organic peroxides

An efficient Cu-catalyzed Csp3-O coupling of peroxides with haloalkanes is described. High yields of products were achieved under mild conditions. Significantly, in addition to primary alkyl halides, secondary alkyl halogenated hydrocarbons could also be applied to this system. The new reaction system could tolerate a wide range of organic peroxides.