4281-17-8Relevant articles and documents
Intramolecular Hydrogen-Atom Transfer in 2-Alkylbenzoyloxyl Radicals as Studied by Transient Absorption Kinetics and Product Analyses on Photodecomposition of Bis(2-alkylbenzoyl) Peroxides
Wang, Jun,Tsuchiya, Masahiro,Tokumaru, Katsumi,Sakuragi, Hirochika
, p. 1213 - 1219 (2007/10/02)
The pulsed-laser excitation of bis(2-methylbenzoyl) peroxide at 308 nm in acetonitrile afforded a broad absorption band at 500-800 nm due to 2-methylbenzoyloxyl radicals.The decay of this band accompanied the growth of another band at 350 nm due to 2-carboxybenzyl radicals produced by an intramolecular hydrogen-atom transfer from the neighboring 2-methyl group; the rate constant was 1.7*107 s-1 at 23 deg C, the activation energy and frequency factor being 17 kJ mol-1 and 1010.5 s-1, respectively.The rates for intramolecular hydrogen-atom transfer in2-MeCH2C6H4CO2. and 2-PhCH2C6H4CO2. are much higher than that in 2-CH3C6H4CO2., since the parent peroxides, (2-MeCH2C6H4CO2)2 and (2-PhCH2C6H4CO2)2, exhibited only 350-nm bands ascribable to the corresponding 2-carboxybenzyl radicals, even immediately after laser excitation.The pulsed-laser photolyses of the above-mentioned peroxides afforded PhCH2R, 2-HOCOC6H4CH(R)CH2CN, and 2-HOCOC6H4CHRCHRC6H4CO2H-2 (R=H, Me and Ph) as the main products in acetonitrile.The formation of PhCH2R is explained in terms of the contribution of two-bond fission of the O-O and C(α)-C bonds of the peroxide in the excited singlet state in competition with O-O bond cleavage followed by an intramolecular hydrogen-atom transfer.
195. Conventional and Laser Photolysis of a Bisdiazo Compound
Hannemann, Klaus,Wirz, Jakob,Riesen, Andreas
, p. 1841 - 1857 (2007/10/02)
Entirely different product distributions were observed when the bisdiazo compound 1 was irradiated by a conventional lamp (254 nm) on the one hand and by a pulsed excimer laser (248 nm) on the other.Continuous photolysis gave a complex reaction mixture (S
