32507-38-3

Basic information

• Product Name: Benzenamine, 4-(1E)-1,3-butadienyl-N,N-dimethyl-
• CAS NO: 32507-38-3
• Molecular Formula: C12H15N
• Molecular Weight: 173.258
• Mol File: 32507-38-3.mol
• Article Data: 15

Chemical Properties

• CAS DataBase Reference: Benzenamine, 4-(1E)-1,3-butadienyl-N,N-dimethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenamine, 4-(1E)-1,3-butadienyl-N,N-dimethyl-(32507-38-3)
• EPA Substance Registry System: Benzenamine, 4-(1E)-1,3-butadienyl-N,N-dimethyl-(32507-38-3)

Safety Data

• Hazardous Substances Data: 32507-38-3(Hazardous Substances Data)

Upstream product

• 100-10-7 4-dimethylamino-benzaldehyde 
• 1730-25-2 allylmagnesium bromide 
• 20432-35-3 3-(4-dimethylamino-phenyl)-propenal 
• 1560-54-9 allyltriphenylphosphonium bromide 
• 762-72-1 allyl-trimethyl-silane 
• 590-13-6 (Z)-1-propenyl bromide 
• 18708-16-2 p-(dimethylamino)benzaldehyde tosylhydrazone 
• 91788-88-4 allyl-triethylphosphonium-bromide 
• 62982-11-0 1-(4-(N,N-dimethylamino)phenyl)-1,3-butadiene 
• 1779-49-3 Methyltriphenylphosphonium bromide 
• 106-99-0 buta-1,3-diene 
• 7353-91-5 4-dimethylaminophenylmagnesium bromide 

Downstream Products

• 100036-19-9 3-(4-Dimethylamino-phenyl)-cyclohex-4-ene-1,1,2,2-tetracarbonitrile 
• 100036-05-3 2-(4-Dimethylamino-phenyl)-6,6-bis-trifluoromethyl-cyclohex-3-ene-1,1-dicarbonitrile 
• 54372-65-5 2-(trans-2-N,N-Dimethylanilinoethenyl)-1,1-dichlorcyclopropan 

Relevant articles and documents

In-chain functionalized syndiotactic 1,2-polybutadiene by a Ziegler-Natta iron(III) catalytic system

Copolymerization of 1,3-butadiene with four 1-substituted 1,3-diene comonomers bearing amino and alkyoxy groups by a Ziegler-Natta iron(iii) catalytic system to access in-chain functionalized syndiotactic 1,2-polybutadiene is reported herein. The polar co

Base-Mediated Site-Selective Hydroamination of Alkenes

We present a base-mediated hydroamination protocol, using substoichiometric amounts of a hydrosilane and potassium tertbutoxide, that operates under mild conditions at 30 °C. Many aryl- and heteroatom-substituted olefins as well as arylamines are tolerated, affording the desired products with complete regioselectivity. Preliminary mechanistic investigations reveal a non-radical pathway for hydroamination. A sequential remote hydroamination strategy involving an initial Fe-catalysed olefin isomerisation followed by our base-mediated hydroamination was also developed to directly access-arylamines from terminal aliphatic alkenes.

Photoinduced Palladium-Catalyzed Carbofunctionalization of Conjugated Dienes Proceeding via Radical-Polar Crossover Scenario: 1,2-Aminoalkylation and beyond

A photoinduced palladium-catalyzed 1,2-carbofunctionalization of conjugated dienes has been developed. This mild modular approach, which does not require employment of exogeneous photosensitizers and external oxidants, allows for efficient and highly regio- and stereoselective synthesis of a broad range of allylic amines from readily available 1,3-dienes, alkyl iodides, and amines. Employment of O- and C-nucleophiles toward oxyalkylation and dialkylation products was also demonstrated. A putative π-allyl palladium radical-polar crossover path is proposed as a key event in this three-component coupling process. The utility of this protocol is highlighted by its application for derivatization of several amine-containing drugs.