3278-38-4

Basic information

• Product Name: S-phenyl O-ethylxanthate
• Synonyms: S-phenyl O-ethylxanthate
• CAS NO: 3278-38-4
• Molecular Weight: 198.31
• Mol File: 3278-38-4.mol
• Article Data: 13

Chemical Properties

• CAS DataBase Reference: S-phenyl O-ethylxanthate(CAS DataBase Reference)
• NIST Chemistry Reference: S-phenyl O-ethylxanthate(3278-38-4)
• EPA Substance Registry System: S-phenyl O-ethylxanthate(3278-38-4)

Safety Data

• Hazardous Substances Data: 3278-38-4(Hazardous Substances Data)

Upstream product

• 16911-89-0 phenyl chlorodithioformate 
• 64-17-5 ethanol 
• 51676-65-4 O-ethyl S-(2,4-dinitrophenyl) dithiocarbonate 
• 108-98-5 thiophenol 
• 51676-67-6 O-ethyl S-(2,4,6-trinitrophenyl) dithiocarbonate 
• 591-50-4 iodobenzene 
• 140-89-6 potassium ethyl xanthogenate 
• 108-86-1 bromobenzene 
• 140-90-9 sodium O-ethyl dithiocarbonate 
• 369-57-3 benzenediazonium tetrafluoroborate 
• 930-69-8 sodium thiophenolate 
• 2812-73-9 Chlor(thioameisensaeure)-O-ethylester 
• 111-34-2 -butyl vinyl ether 
• 6415-38-9 benzenediazonium sulphate 

Downstream Products

• 108-98-5 thiophenol 
• 5308-12-3 O-ethyl N-(4-methylphenyl)thiocarbamate 
• 22001-51-0 O-ethyl N-(4-chlorophenyl)thiocarbamate 
• 22007-38-1 O-ethyl N-(4-methoxyphenyl)thiocarbamate 
• 3111-89-5 O-ethyl-N-phenylthiocarbamate 
• 77876-27-8 ethyl-pentachlorophenyl sulfide 
• 1147550-11-5 ammonium thiocyanate 
• 7570-92-5 cyclohexyl phenyl sulphide 
• 139-66-2 diphenyl sulfide 
• 1129-70-0 pentyl phenyl sulfide 
• 3699-01-2 4-tolyl phenyl sulfide 
• 699-12-7 2-(phenylthio)ethanol 
• 100-68-5 methyl-phenyl-thioether 
• 622-38-8 Ethyl phenyl sulfide 

Relevant articles and documents

Synthesis and antimicrobial properties of esters of 2-alkyl-3-aryl-2-(O-alkyl-dithiocarbonato)propionic acid

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A Novel Method for the Direct Synthesis of Symmetrical and Unsymmetrical Sulfides and Disulfides from Aryl Halides and Ethyl Potassium Xanthogenate

An efficient and new method for the synthesis of disulfides and sulfides via the reaction of aryl halides with ethyl potassium xanthogenate in the presence of MOF-199 is described. O -Ethyl- S -aryl carbonodithioate has a key role as an intermediate in this procedure; it was converted into symmetrical diaryl disulfides in DMF. Additionally, this could be applied to the synthesis of unsymmetrical aryl alkyl(aryl′) disulfides by the reaction with S -alkyl(aryl) sulfurothioates (Bunte salts) as well as unsymmetrical aryl alkyl(aryl′) sulfides in DMSO.

Synthesis of unsymmetrical sulfides using ethyl potassium xanthogenate and recyclable copper catalyst under ligand-free conditions

The synthesis of unsymmetrical sulfides has been achieved in good to excellent yields with inexpensive ethyl potassium xanthogenate via cross-coupling reaction using recyclable CuO nanoparticles under ligand-free conditions.The copper oxide nanoparticles can be recovered and reused up to five cycles without loss of activity.

Reactions of arenediazonium tetrafluoroborates with inorganic and organic salts

Arenediazonium tetrafluoroborates were reacted with inorganic and organic salts under anionarylation reaction conditions in the presence of strong nucleophiles (O,O-dimetyl dithiophosphate, N,N-diethyldithiocarbamate, and O-alkyl dithiocarbonate anions) and in the absence of catalysts [Cu(I) and Fe(II) salts] to obtain in high yields (dimethoxythiophosphinoylmercapto)-, (N,N-diethylthiocarbamoylmercapto)-, and (alkoxythiocarbonylmercapto)benzenes. The products of the reactions of arenediazonium tetrafluoroborates with potassium thiocyanate were identified and their compositions were determined. These reactions are proposed to occur by a radical mechanism, both under catalytic and noncatalytic conditions.