33026-37-8

Basic information

• Product Name: (rac)-3-phenyl-3-methylcyclohexanone
• Synonyms: (rac)-3-phenyl-3-methylcyclohexanone
• CAS NO: 33026-37-8
• Molecular Weight: 188.269
• Mol File: 33026-37-8.mol
• Article Data: 21

Chemical Properties

• CAS DataBase Reference: (rac)-3-phenyl-3-methylcyclohexanone(CAS DataBase Reference)
• NIST Chemistry Reference: (rac)-3-phenyl-3-methylcyclohexanone(33026-37-8)
• EPA Substance Registry System: (rac)-3-phenyl-3-methylcyclohexanone(33026-37-8)

Safety Data

• Hazardous Substances Data: 33026-37-8(Hazardous Substances Data)

Upstream product

• 1193-18-6 3-methylcyclohexen-2-one 
• 100-59-4 phenylmagnesium chloride 
• 100-58-3 phenylmagnesium bromide 
• 10345-87-6 3-phenylcyclohex-2-enone 
• 75337-05-2 4-methyl-2-cyclohexenone 
• 618-41-7 Benzenesulfinic acid 
• 71-43-2 benzene 
• 24388-23-6 2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole 
• 98-80-6 phenylboronic acid 
• 71478-47-2 phenylmanganese(II) chloride 
• 591-51-5 phenyllithium 
• 917-54-4 methyllithium 

Downstream Products

• 197523-43-6 2-(3-Hydroxy-propyl)-5-methyl-5-phenyl-cyclohexanol 
• 197523-47-0 3-{4-Methyl-4-phenyl-2-[1-trimethylsilanyl-meth-(Z)-ylidene]-cyclohexyl}-propan-1-ol 
• 197523-49-2 3-{4-Methyl-4-phenyl-2-[1-trimethylsilanyl-meth-(Z)-ylidene]-cyclohexyl}-propionaldehyde 
• 197523-50-5 4-{4-Methyl-4-phenyl-2-[1-trimethylsilanyl-meth-(Z)-ylidene]-cyclohexyl}-butan-2-ol 
• 197523-51-6 4-{4-Methyl-4-phenyl-2-[1-trimethylsilanyl-meth-(Z)-ylidene]-cyclohexyl}-butan-2-one 
• 197523-44-7 5-Methyl-5-phenyl-2-(3-triisopropylsilanyloxy-propyl)-cyclohexanol 
• 197523-45-8 5-Methyl-5-phenyl-2-(3-triisopropylsilanyloxy-propyl)-cyclohexanone 
• 197523-46-9 {1-Methyl-4-(3-triisopropylsilanyloxy-propyl)-3-[1-trimethylsilanyl-meth-(Z)-ylidene]-cyclohexyl}-benzene 
• 135616-24-9 4-Methyl-2-oxo-4-phenyl-cyclohexanecarboxylic acid methyl ester 
• 15954-46-8 1-(4-(1-methylcyclohexyl)phenyl)ethan-1-one 
• 63007-39-6 [4-(1-Methyl-cyclohexyl)-phenyl]-acetic acid 

Relevant articles and documents

A Pd(II)-Functionalized Covalent Organic Framework for Catalytic Conjugate Additions of Arylboronic Acids to β,β-Disubstituted Enones

A palladium(II)-functionalized covalent organic framework (Pd@TpBpy COF) constructed from 1,3,5-triformylphloroglucinol (Tp) and [2,2′-bipyridine]-5,5′-diamine (Bpy) is reported as a recyclable catalyst for conjugate additions in aqueous media. Additions

Synthesis of Cyclohexanones through a Catalytic Cationic Cyclization of Alkynols or Enynes

A novel procedure for the synthesis of cyclohexanones from alkynol or enyne derivatives through a cationic cyclization has been developed. The key points to obtain the six-membered ring derivatives are the use of starting materials containing a terminal alkyne, the use of tetrafluoroboric acid as a promoter of the cationic cyclization, and the appropriate selection of 1,1,1,3,3,3-hexafluoropropan-2-ol (HFIP) as solvent. This strategy can be extended to the biomimetic cationic cyclization of several terpene-derived polyenynes.

Palladium complexes with chiral imidazole ligands as potential catalysts for asymmetric C[sbnd]C coupling reactions

Two palladium complexes of the type [Pd(im)2Cl2] containing chiral imidazole ligands (im?=?1-bornyloxymethylene imidazole, 1-fenchyloxymethylyne imidazole) were synthesized and structurally characterized. The square planar structure of one of the complexes was confirmed by the X-ray analysis. The new palladium complexes were tested as catalysts in various C[sbnd]C bond forming reactions, namely Suzuki–Miyaura, carbonylative Suzuki–Miyaura, asymmetric Heck-type coupling reactions and asymmetric conjugate addition of phenylboronic acid to heterocyclic acceptors. In all the reactions the cross-coupling products were obtained with high yield and selectivity under mild conditions. In case of coupling of 2,3-dihydrofuran with phenylboronic acid ee value ca. 10 was observed.