33415-27-9Relevant articles and documents
Synthesis and structures of simple (silylmethyl)(methyl)ethers
Mitzel, Norbert W.
, p. 759 - 763 (2003)
The compound Cl3SiCH2OCH3 was prepared by reacting ClCH2OCH3 with the Cl3SiH/NEt 3 reagent. H3SiCH2OCH3 and F 3SiCH2OCH3 were synthesized from Cl 3SiCH2OCH3 by reduction with LiAlH4 and by fluorination with SbF3, respectively. The crystal structures of the low-melting compounds H3SiCH2OCH3 and F3SiCH2OCH3 were determined by X-ray diffraction of in situ grown crystals. Both compounds do not show any observable β-donor-acceptor interactions, but behave structurally like usual dialkylethers or silanes, as is obvious from the structural parameters in H3SiCH2OCH3 (3SiCH2OCH 3 (SiCO 107.1(1), COC 111.2(2)°). Earlier postulates of Si?O interactions in compounds with SiCO units could thus not be confirmed on a structural basis.
METHOD FOR PRODUCING ALKOXY HYDROSILANE
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Paragraph 0050; 0051; 0052, (2013/05/09)
Provided is a method for producing an alkoxyhydrosilane, comprising: a reaction (reaction 1) of a halohydrosilane compound (B) represented by H-SiR2c(CR13-bYb)aX3-a-c wherein R1 is a hydrogen atom or C1-20 hydrocarbon group; R2 is a C1-20 hydrocarbon group; X is a halogen atom; Y is a hetero substituent; a is 1 or 2, b is 1, 2 or 3, and c is 1 or 0, provided that a+c is not more than 2, with an alcohol (C) in an amount of 0.50-0.99 molar equivalents relative to Xs of the halohydrosilane compound (B); followed by a reaction (reaction 2) with an orthoester (D) in an amount of 1.00 molar equivalent or more relative to the residual Si-X in the reaction mixture, to produce an alkoxyhydrosilane compound (A) represented by H-SiR2c(CR13-bYb)a(OR8)3-a-c wherein R8 is a C1-20 hydrocarbon group, and R1, R2, Y, a, b, and c are as defined above.