35947-99-0

Basic information

• Product Name: 1-Propanone, 2-azido-1-phenyl-
• CAS NO: 35947-99-0
• Molecular Formula: C9H9N3O
• Molecular Weight: 175.19
• Mol File: 35947-99-0.mol
• Article Data: 21

Chemical Properties

• CAS DataBase Reference: 1-Propanone, 2-azido-1-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Propanone, 2-azido-1-phenyl-(35947-99-0)
• EPA Substance Registry System: 1-Propanone, 2-azido-1-phenyl-(35947-99-0)

Safety Data

• Hazardous Substances Data: 35947-99-0(Hazardous Substances Data)

Upstream product

• 2114-00-3 2-bromo-1-phenyl-1-propanone 
• 4767-01-5 2-methyl-3-oxo-3-phenylpropionic acid 
• 37471-46-8 1-phenyl-1-trimethylsiloxypropene 
• 66323-99-7 trimethyl[(Z)-(1-phenyl-1-propenyl)oxy]silane 
• 87456-64-2 α-tosyloxypropiophenone 
• 873-66-5 1-propenylbenzene 
• 93-55-0 1-phenyl-propan-1-one 
• 98990-64-8 4-Nitro-benzenesulfonic acid 1-methyl-2-oxo-2-phenyl-ethyl ester 
• 637-50-3 1-phenylpropene 

Downstream Products

• 10130-23-1 2-methyl-3-phenylquinoxaline 
• 716-79-0 2-phenyl-1H-benzoimidazole 
• 114208-60-5 Benzoyl-3-hydroxy-4-methyl-3-dihydro-3,4-isoquinoleine 
• 114196-67-7 2,3-dihydro-2-(methyl-1 phenacyl)-1H isoindol-1-one 
• 159434-78-3 (-)-(1R,2S)-2-Azido-1-(tert-butyldimethylsiloxy)-1-phenylpropane 
• 159434-79-4 (-)-(1R,2R)-2-Azido-1-(tert-butyldimethylsiloxy)-1-phenylpropane 
• 54600-85-0 2,5-dimethyl-3,6-diphenylpyrazine 
• 614-17-5 N-ethylbenzamide 
• 93-55-0 1-phenyl-propan-1-one 
• 1644121-05-0 2,2-bis(4,5,6,7,8,9-hexahydro-1H-cycloocta[d][1,2,3]triazol-1-yl)-1-phenylpropan-1-one 
• 23012-31-9 2,4-dimethyl-5-phenyloxazole 
• 72739-14-1 (-)-Cathinone hydrochloride 
• 76333-53-4 (+)-(2R)-2-Amino-1-phenyl-1-propanone hydrochloride 
• 900517-57-9 ethyl (Z)-(4-hydroxy-5-methyl-4-phenylpyrrolidin-2-ylidene)acetate 

Relevant articles and documents

Electrochemical Difunctionalization of Styrenes via Chemoselective Oxo-Azidation or Oxo-Hydroxyphthalimidation

Atom- and step-economic oxo-azidation and oxo-hydroxyphthalimidation of styrenes have been developed under mild electrolytic conditions, respectively. Various valuable alpha-azido or hydroxyphthalimide aromatic ketones were synthesized efficiently from readily available styrenes, azides, and N-hydroxyphthalimides. Mechanism studies show that two different pathways involved in these two transformations.

Chemo- and Enantioselective Oxidative α-Azidation of Carbonyl Compounds

We report high-performance I+/H2O2 catalysis for the oxidative or decarboxylative oxidative α-azidation of carbonyl compounds by using sodium azide under biphasic neutral phase-transfer conditions. To induce higher reactivity especially for the α-azidation of 1,3-dicarbonyl compounds, we designed a structurally compact isoindoline-derived quaternary ammonium iodide catalyst bearing electron-withdrawing groups. The nonproductive decomposition pathways of I+/H2O2 catalysis could be suppressed by the use of a catalytic amount of a radical-trapping agent. This oxidative coupling tolerates a variety of functional groups and could be readily applied to the late-stage α-azidation of structurally diverse complex molecules. Moreover, we achieved the enantioselective α-azidation of 1,3-dicarbonyl compounds as the first successful example of enantioselective intermolecular oxidative coupling with a chiral hypoiodite catalyst.

Method for preparing alpha-azidoketone compounds based on photocatalysis

The invention discloses a method for preparing alpha-azidoketone compounds based on photocatalysis. The method is based on a reaction formula shown in the description, wherein R is optionally-substituted aryl, heteroaryl or 1-12 carbon alkyl; R is o