4235-12-5

Basic information

• Product Name: (S)-S-methyl-S-(4-tolyl)-N-(p-tolylsulfonyl)sulfimide
• CAS NO: 4235-12-5
• Molecular Weight: 307.437
• Mol File: 4235-12-5.mol
• Article Data: 21

Chemical Properties

• CAS DataBase Reference: (S)-S-methyl-S-(4-tolyl)-N-(p-tolylsulfonyl)sulfimide(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-S-methyl-S-(4-tolyl)-N-(p-tolylsulfonyl)sulfimide(4235-12-5)
• EPA Substance Registry System: (S)-S-methyl-S-(4-tolyl)-N-(p-tolylsulfonyl)sulfimide(4235-12-5)

Safety Data

• Hazardous Substances Data: 4235-12-5(Hazardous Substances Data)

Upstream product

• 623-13-2 4-methylphenyl methylsulfide 
• 144-86-5 N-chloro-4-methylbenzenesulfonamide 
• 127-65-1 chloroamine-T 
• 55962-05-5 [N-(p-tolylsulfonyl)imino]phenyliodinane 
• 242461-31-0 [N-(p-toluenesulfonyl)imino](2-tert-butylsulfonyl)phenyliodinane 
• 106-45-6 para-thiocresol 
• 934-72-5 Methyl p-tolyl sulfoxide 
• 40560-76-7 tosyl azide 
• 4547-64-2 4-methoxybenzenesulfonyl azide 
• 941-55-9 4-toluenesulfonyl azide 
• 1240327-54-1 2-(tert-butylsulfonyl)-5-tert-butyl-(tosyliminoiodo)benzene 
• 71996-32-2 N-(5λ⁴-dibenzo[b,d]thiophen-5-ylidene)-4-methylbenzenesulfonamide 
• 70-55-3 toluene-4-sulfonamide 
• 5056-07-5 (S)-methyl p-tolyl sulfoxide 

Downstream Products

• 20414-85-1 S-methyl-S-(p-tolyl)sulfoximine 
• 96-09-3 styrene oxide 
• 20780-53-4 (R)-Styrene oxide 
• 20780-54-5 (S)-styrene oxide 
• 20520-50-7 (R)-S-methyl-S-(4-tolyl)-N-(p-tolylsulfonyl)sulfoximine 
• 140687-75-8 2-(3,4-dimethoxyphenyl)oxirane 
• 28832-82-8 S-methyl-S-p-tolyl-N-(p-tolylsulfonyl)sulfoximine 
• 623-13-2 4-methylphenyl methylsulfide 
• 70-55-3 toluene-4-sulfonamide 
• 58044-92-1 S-methyl-S-(4-tolyl)sulfilimine 

Relevant articles and documents

Octahedral iron(iv)-tosylimido complexes exhibiting single electron-oxidation reactivity

High valent iron species are very reactive molecules involved in oxidation reactions of relevance to biology and chemical synthesis. Herein we describe iron(iv)-tosylimido complexes [FeIV(NTs)(MePy2tacn)](OTf)2 (1(IV)

Sulfonylimino group transfer reaction using imino-λ3-iodanes with I2 as catalyst under metal-free conditions

A new practical procedure of imination for sulfide has been developed. The treatment of (N-tosylimino)-phenyl-λ3-iodane, PhINTs, with various sulfides in the presence of a catalytic amount of I2 under metal-free conditions affords the corresponding N-tosylsulfilimine compounds with moderate to good yields. This facile transfer procedure of the sulfonylimino group can also be applied to triphenylphosphine to produce the respective iminotriphenylphosphoranes in high yields. According to the reaction mechanism studies, the process of imination from (N-tosylimino)-phenyl-λ3-iodane to sulfide under the conditions may involve radical steps within the reaction mechanism.

A Mononuclear Nonheme Iron(V)-Imido Complex

Mononuclear nonheme iron(V)-oxo complexes have been reported previously. Herein, we report the first example of a mononuclear nonheme iron(V)-imido complex bearing a tetraamido macrocyclic ligand (TAML), [(TAML)FeV(NTs)]? (1). The spectroscopic characterization of 1 revealed an S = 1/2 Fe(V) oxidation state, an Fe - N bond length of 1.65(4) ?, and an Fe - N vibration at 817 cm-1. The reactivity of 1 was demonstrated in C - H bond functionalization and nitrene transfer reactions.