4280-60-8

Basic information

• Product Name: Benzene, 1,1'-(1,10-decanediyl)bis[4-methoxy-
• CAS NO: 4280-60-8
• Molecular Formula: C24H34O2
• Molecular Weight: 354.533
• Mol File: 4280-60-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Benzene, 1,1'-(1,10-decanediyl)bis[4-methoxy-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1,1'-(1,10-decanediyl)bis[4-methoxy-(4280-60-8)
• EPA Substance Registry System: Benzene, 1,1'-(1,10-decanediyl)bis[4-methoxy-(4280-60-8)

Safety Data

• Hazardous Substances Data: 4280-60-8(Hazardous Substances Data)

Upstream product

• 14469-84-2 1-(para-anisyl)-5-bromopentane 
• 104-92-7 1-bromo-4-methoxy-benzene 
• 4101-68-2 1,10-dibromodecane 
• 79023-06-6 5-(4-methoxyphenyl)pentanoic acid ethyl ester 
• 4609-10-3 5-(4-methoxyphenyl)-5-oxopentanoic acid 
• 7508-04-5 5-(4-methoxyphenyl)pentanoic acid 
• 14374-54-0 5-(4-methoxyphenyl)pentan-1-ol 
• 60-29-7 diethyl ether 
• 123-11-5 4-methoxy-benzaldehyde 
• 13139-86-1 4-methoxyphenyl magnesium bromide 

Downstream Products

• 1384578-59-9 1,10-bis(3-formyl-4-methoxyphenyl)decane 
• 3682-97-1 4,4'-decanediyl-di-phenol 

Relevant articles and documents

Triply Threaded [4]Rotaxanes

[4]Rotaxanes featuring three axles threaded through a single ring have been prepared through active metal template synthesis. Nickel-catalyzed sp3-sp3 homocouplings of alkyl bromide "half-threads" through 37- and 38-membered 2,2′:6′,2″-terpyridyl macrocycles generate triply threaded [4]rotaxanes in up to 11% yield. An analogous 39-membered macrocycle produced no rotaxane products under similar conditions. The constitutions of the [4]rotaxanes were determined by NMR spectroscopy and mass spectrometry. Doubly threaded [3]rotaxanes were also obtained from the reactions but no [2]rotaxanes were isolated, suggesting that upon demetalation the axle of a singly threaded rotaxane can slip through a macrocycle that is sufficiently large to accommodate three threads.

THE PREPARATION OF α,ω-BIS-PARA-ANISYLALKANES

An improved method for the preparation of a homologous series of α,ω-bis-para-anisylalkanes is described.