49759-56-0

Basic information

• Product Name: Z-DL-Phe(3F)-OMe
• CAS NO: 49759-56-0
• Molecular Weight: 331.344
• Mol File: 49759-56-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Z-DL-Phe(3F)-OMe(CAS DataBase Reference)
• NIST Chemistry Reference: Z-DL-Phe(3F)-OMe(49759-56-0)
• EPA Substance Registry System: Z-DL-Phe(3F)-OMe(49759-56-0)

Safety Data

• Hazardous Substances Data: 49759-56-0(Hazardous Substances Data)

Upstream product

• 49864-42-8 2-Benzyloxycarbonylamino-2-(3-fluoro-benzyl)-malonic acid monomethyl ester 
• 186581-53-3 diazomethane 
• 126693-47-8 Z-DL-Phe(3F) 
• 456-88-2 3-fluorophenylalanine 
• 501-53-1 benzyl chloroformate 
• 37447-35-1 2-benzyloxycarbonylaminomalonic acid dimethyl ester 
• 49759-51-5 2-Benzyloxycarbonylamino-2-(3-fluoro-benzyl)-malonic acid dimethyl ester 
• 456-41-7 1-(Bromomethyl)-3-fluorobenzene 

Downstream Products

• 49759-64-0 Cbz-L-m-FPhe 
• 126693-47-8 Z-DL-Phe(3F) 
• 19883-77-3 L-3-fluorophenylalanine 

Relevant articles and documents

α-chymotrypsin-catalysed peptide synthesis via the kinetically controlled approach using activated esters as acyl donors in organic solvents with low water content: Incorporation of non-protein amino acids into peptides

The α-chymotrypsin-catalyzed peptide synthesis via the kinetically controlled approach using activated esters as acyl donors in orgnanic solvents with low water content was presented. The methyl esters of N-Z derivatives of racemic non-protein amino acids were chosen as carboxy components. They allowed the peptide-bond formation and optical resolution simultaneously to yield homochiral peptides. This method is useful for the incorporation of non-protein amino acids into peptides.