500220-30-4Relevant articles and documents
Total synthesis of gem-difluoromethylenated analogues of pironetin
Lin, Jing,Qing, Feng-Ling,Yue, Xuyi,Huang, Peng,Cui, Daxiang
experimental part, p. 267 - 275 (2010/04/02)
The straightforward synthesis of four gem-difluoromethylenated analogues of pironetin is described. Our synthesis features the efficient construction of the key intermediates through the indium--mediated gem-difluoropropargylation of aldehydes with the fl
Total synthesis of (-)-pironetin
Dias, Luiz C.,De Oliveira, Luciana G.,De Sousa, Marcio A.
, p. 265 - 268 (2007/10/03)
(Matrix presented) The asymmetric total synthesis of pironetin, a compound that shows plant growth regulatory activity, immunosuppressive as well as a remarkable antitumoral activity, is described. The approach involves the use of three very efficient Eva