500220-31-5

Basic information

• Product Name: (2S,3R)-N-methoxy-N-methyl-3-(tert-butyldimethylsilanyloxy)-5-(4-methoxybenzyloxy)-2-methylpentamide
• Synonyms: (2S,3R)-N-methoxy-N-methyl-3-(tert-butyldimethylsilanyloxy)-5-(4-methoxybenzyloxy)-2-methylpentamide
• CAS NO: 500220-31-5
• Molecular Weight: 425.641
• Mol File: 500220-31-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (2S,3R)-N-methoxy-N-methyl-3-(tert-butyldimethylsilanyloxy)-5-(4-methoxybenzyloxy)-2-methylpentamide(CAS DataBase Reference)
• NIST Chemistry Reference: (2S,3R)-N-methoxy-N-methyl-3-(tert-butyldimethylsilanyloxy)-5-(4-methoxybenzyloxy)-2-methylpentamide(500220-31-5)
• EPA Substance Registry System: (2S,3R)-N-methoxy-N-methyl-3-(tert-butyldimethylsilanyloxy)-5-(4-methoxybenzyloxy)-2-methylpentamide(500220-31-5)

Safety Data

• Hazardous Substances Data: 500220-31-5(Hazardous Substances Data)

Upstream product

• 135362-69-5 3-(4-methoxybenzyl)oxypropan-1-ol 
• 123-11-5 4-methoxy-benzaldehyde 
• 5689-71-4 2-(4-methoxy-phenyl)-[1,3]dioxane 
• 900171-30-4 (3S,4R)-4-[2-(4-methoxybenzyloxy)ethyl]-3-methyloxetan-2-one 
• 18162-48-6 tert-butyldimethylsilyl chloride 
• 866530-02-1 (2S,3R)-N-methoxy-N-methyl-3-hydroxy-5-(4-methoxybenzyloxy)-2-methylpentamide 
• 69739-34-0 t-butyldimethylsiyl triflate 

Downstream Products

• 500220-35-9 (2R,3S,4S,5R)-3,5-Dihydroxy-7-(4-methoxy-benzyloxy)-2,4-dimethyl-heptanoic acid 
• 500220-34-8 (2S,3R,4S,5R)-5-(tert-butyldimethylsilanyloxy)-3-hydroxy-7-(4-methoxybenzyloxy)-2,4-dimethylheptyl 4-methylbenzenesulfonate 
• 500220-29-1 (2S,3R,4S,5R)-5-(tert-butyldimethylsilanyloxy)-3-methoxy-7-(4-methoxybenzyloxy)-2,4-dimethylheptyl 4-methylbenzenesulfonate 
• 500220-33-7 (2S,3R,4S,5R)-5-(tert-butyldimethylsilanyloxy)-7-(4-methoxybenzyloxy)-2,4-dimethylheptane-1,3-diol 
• 900171-38-2 (3R,4S,5R,6S)-3-(tert-butyldimethylsilanyloxy)-5-methoxy-1-(4-methoxybenzyloxy)-4,6-dimethyl-9-decene 
• 866529-95-5 (E,3R,4S,5R,6S)-3-(tert-butyldimethylsilanyloxy)-5-methoxy-1-(4-methoxybenzyloxy)-4,6-dimethyl-8-decene 
• 900171-35-9 (3R,4S)-4-[(2S,3R)-2-(tert-butyldimethylsilanyloxy)-4-(4-methoxybenzyloxy)-1-methylbutyl]-3-methyloxetan-2-one 
• 500220-30-4 (2S,3R)-3-(tert-butyldimethylsilanyloxy)-5-(4-methoxybenzyloxy)-2-methylpentanal 

Relevant articles and documents

Catalytic asymmetric assembly of stereodefined propionate units: An enantioselective total synthesis of (-)-pironetin

Double diastereoselection in alkaloid-catalyzed acyl halide-aldehyde cyclocondensation (AAC) reactions provides a strategy for realizing syn- or anti-selective propionate aldol additions from a common reaction manifold. Matched AAC homologation of enantio