500772-23-6

Basic information

• Product Name: Thiophene, 2,3,5-tribromo-4-phenyl-
• CAS NO: 500772-23-6
• Molecular Formula: C10H5Br3S
• Molecular Weight: 396.928
• Mol File: 500772-23-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Thiophene, 2,3,5-tribromo-4-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Thiophene, 2,3,5-tribromo-4-phenyl-(500772-23-6)
• EPA Substance Registry System: Thiophene, 2,3,5-tribromo-4-phenyl-(500772-23-6)

Safety Data

• Hazardous Substances Data: 500772-23-6(Hazardous Substances Data)

Upstream product

• 6051-52-1 2-phenylbut-3-en-2-ol 
• 2288-18-8 2-phenyl-1,3-butadiene 
• 19698-46-5 2,5-Dibromo-3-phenylthiophene 
• 2404-87-7 3-phenylthiophene 

Downstream Products

• 1884-68-0 tetraphenylthiophene 
• 500772-30-5 2-(5-methylthien-2-yl)-3,5-diphenyl-6-[5-dimethyl(chloromethyl)silylthien-2-yl]dithieno[3,2-b:2',3'-d]thiophene-4,4-dioxide 
• 500772-29-2 2-bromo-3,5-diphenyl-6-(5-methylthien-2-yl)-dithieno[3,2-b:2',3'-d]thiophene-4,4-dioxide 
• 500772-28-1 2-(5-methylthien-2-yl)-3,5-diphenyl-dithieno[3,2-b:2',3'-d]thiophene-4,4-dioxide 
• 500772-27-0 2-bromo-3,5-diphenyl-dithieno[3,2-b:2',3'-d]thiophene-4,4-dioxide 
• 500772-26-9 3,5-diphenyldithieno[3,2-b:2',3'-d]thiophene-4,4-dioxide 
• 500772-25-8 3,5-diphenyldithieno[3,2-b:2',3'-d]thiophene 
• 500772-24-7 3-phenyl-4-[(4-phenylthien-3-yl)thio]thiophene 
• 23062-41-1 3-bromo-4-phenylthiophene 

Relevant articles and documents

Redox-Divergent Construction of (Dihydro)thiophenes with DMSO

Thiophene-based rings are one of the most widely used building blocks for the synthesis of sulfur-containing molecules. Inspired by the redox diversity of these features in nature, we demonstrate herein a redox-divergent construction of dihydrothiophenes, thiophenes, and bromothiophenes from the respective readily available allylic alcohols, dimethyl sulfoxide (DMSO), and HBr. The redox-divergent selectivity could be manipulated mainly by controlling the dosage of DMSO and HBr. Mechanistic studies suggest that DMSO simultaneously acts as an oxidant and a sulfur donor. The synthetic potentials of the products as platform molecules were also demonstrated by various derivatizations, including the preparation of bioactive and functional molecules.