50766-67-1

Basic information

• Product Name: 2-(3,4-DIMETHOXY-PHENYL)-[1,3]DITHIANE
• Synonyms: 2-(3,4-DIMETHOXY-PHENYL)-[1,3]DITHIANE
• CAS NO: 50766-67-1
• Molecular Formula: C₁₂H₁₆O₂S₂
• Molecular Weight: 256.38424
• Mol File: 50766-67-1.mol
• Article Data: 16

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 2-(3,4-DIMETHOXY-PHENYL)-[1,3]DITHIANE(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(3,4-DIMETHOXY-PHENYL)-[1,3]DITHIANE(50766-67-1)
• EPA Substance Registry System: 2-(3,4-DIMETHOXY-PHENYL)-[1,3]DITHIANE(50766-67-1)

Safety Data

• Hazardous Substances Data: 50766-67-1(Hazardous Substances Data)

Upstream product

• 109-80-8 1.3-propanedithiol 
• 120-14-9 3,4-dimethoxy-benzaldehyde 

Downstream Products

• 99545-24-1 2-(2,2-dimethoxyethyl)-2-(3,4-dimethoxyphenyl)-1,3-dithiane 
• 25001-57-4 justicidin A 
• 102349-11-1 2-hydroxy-1-(3,4-dimethoxyphenyl)-2-(2-<β-(N-ethoxycarbonyl-N-methyl)aminoethyl>-4,5-methylenedioxyphenyl)-ethanone 1,3-propylenedithioacetal 
• 88939-59-7 2<2-(1-tosyl-3,4,4-trimethylimidazolidinyl)>-3,4-dimethoxyphenyl-1,3-dithiane 
• 155855-91-7 2-(3,4-dimethoxyphenyl)-2-<4-<(tert-butyldimethylsilyl)oxy>-3-methoxybenzyl>-1,3-dithiane 
• 104072-34-6 2-(3,4-Dimethoxy-phenyl)-2-pent-4-enyl-[1,3]dithiane 
• 120-14-9 3,4-dimethoxy-benzaldehyde 
• 106053-24-1 2-deutero-2-(3,4-dimethoxyphenyl)-1,3-dithiane 
• 138596-87-9 (2''S)-2-(3',4'-Dimethoxyphenyl)-2-(N-t-butoxycarbonyl-2''-methylenepyrrolidine)-1,3-dithiane 
• 128155-62-4 2-(3,4-Dimethoxyphenyl)-2-thiomethoxy-1,3-dithiane 
• 62096-77-9 4-[2-(3,4-Dimethoxy-phenyl)-[1,3]dithian-2-yl]-dihydro-furan-2-one 
• 254973-58-5 2-(3,4-Dimethoxyphenyl)-2-(trimethylsilyl)-1,3-dithiane 
• 2150-38-1 methyl 3,4-dimethoxybenzoate 
• 93-07-2 Veratric acid 

Relevant articles and documents

Visible-light mediated facile dithiane deprotection under metal free conditions

Visible light mediated facile and selective dithiane deprotection under metal free conditions is developed. Eosin Y (1 mol%) proved to be an effective catalyst for the dithiane deprotection under the ambient photoredox conditions. The standard household compact fluorescent light source (CFL bulb) proved to be effective under open-air conditions in aqueous acetonitrile at room temperature. The protocol that exhibits a broad substrate scope and functional group tolerance has been shown to expand to a range of transformations for the electron-rich and -deficient thioacetals and thioketals. The synthetic utility of this protocol has also been demonstrated by gram-scale application.

Design, synthesis, and evaluation of DNA topoisomerase II-targeted nucleosides

We developed novel nucleoside-based topoisomerase II selective inhibitors and showed that small structural units, such as catechols, are essential for DNA topoisomerase II inhibitory activity. Moreover, nucleoside analogues containing TBS and 1,3-dithian

Synthesis of chiral α-diarylacetic esters by stereospecific 1,2-aryl migration promoted by in situ generated acetals from benzoins

A simple protocol for the synthesis of α-diarylacetic esters from benzoins is described. In situ generated acetal assists rapid 1,2-aryl migration in a stereospecific manner, paving the way to make enantioenriched α-diarylacetic esters from easily accessi