52458-10-3

Basic information

• Product Name: Benzene, 1-(1,1-dimethylethyl)-4-(phenylmethoxy)-
• Synonyms: Benzene,1-(1,1-dimethylethyl)-4-(phenylmethoxy);Benzyl 4-tert-butylphenyl ether;1-(Benzyloxy)-4-tert-butylbenzene
• CAS NO: 52458-10-3
• Molecular Formula: C17H20O
• Molecular Weight: 240.345
• Mol File: 52458-10-3.mol
• Article Data: 18

Chemical Properties

• CAS DataBase Reference: Benzene, 1-(1,1-dimethylethyl)-4-(phenylmethoxy)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-(1,1-dimethylethyl)-4-(phenylmethoxy)-(52458-10-3)
• EPA Substance Registry System: Benzene, 1-(1,1-dimethylethyl)-4-(phenylmethoxy)-(52458-10-3)

Safety Data

• Hazardous Substances Data: 52458-10-3(Hazardous Substances Data)

Upstream product

• 98-54-4 para-tert-butylphenol 
• 100-39-0 benzyl bromide 
• 260783-80-0 N,N,N--trimethyl--1--phenylmethanaminium trifluoromethanesulfonate 
• 108-88-3 toluene 
• 253185-03-4 tert-butylbenzene 
• 84563-54-2 bis(4-tert-butylphenyl)iodonium trifluoromethanesulfonate 
• 100-51-6 benzyl alcohol 
• 28528-33-8 4-t-butylphenolate anion 
• 100-44-7 benzyl chloride 

Downstream Products

• 61516-22-1 2-benzyl-4-(tert-butyl)phenol 
• 22543-74-4 4-tert-butylbenzhydrol 
• 1448792-76-4 3-benzyl-5-(tert-butyl)-2-hydroxybenzaldehyde 
• 52458-13-6 4-tert-Butyl-benzhydryl-phenyl-keton 
• 98-54-4 para-tert-butylphenol 
• 52458-11-4 1-benzyloxy-2-bromo-4-tert-butylbenzene 
• 135505-54-3 N-<4-(1,1-Dimethylethyl)phenyl>-N-phenyl-1-naphthalenemethanamine 

Relevant articles and documents

Method for synthesizing aryl benzyl ether compound

The invention discloses a method for synthesizing aryl benzyl ether compounds, which comprises the following steps: by using an iron (III) complex containing 1, 3-di-tert-butyl imidazole cations and having a molecular formula of [(tBuNCH = CHNtBu) CH] [FeBr4] as a catalyst and di-tert-butyl peroxide as an oxidant, carrying out oxidative coupling reaction on phenolic compounds and toluene compounds to synthesize the corresponding aryl benzyl ether compounds. The method is the first example for preparing the aryl benzyl ether compound through the oxidative coupling reaction of the phenolic compound and the toluene compound, which is realized by an iron-based catalyst, and has the advantages of atom economy, environmental friendliness and good substrate applicability.

Transition-Metal-Free and Base-Promoted Carbon-Heteroatom Bond Formation via C-N Cleavage of Benzyl Ammonium Salts

A facile and general method for constructing carbon-heteroatom (C-P, C-O, C-S, and C-N) bonds via C-N cleavage of benzyl ammonium salts under transition-metal-free conditions was reported. The combination of t-BuOK and 18-crown-6 enabled a wide range of substituted benzyl ammonium salts to couple readily with different kinds of heteroatom nucleophiles, i.e. hydrogen phosphoryl compounds, alcohols, thiols, and amines. Good functional group tolerance was demonstrated. The scale-up reaction and one-pot synthesis were also successfully performed.

Jet Colliding and Mixing Efficiency

Two experimental methods, the Nile Red dye extraction and the Williamson ether synthesis in biphasic conditions, were used to characterize the mixing performance of a new cheap impinging jet colliding mixer from Gjosa and to compare it to other commercial