54053-76-8

Basic information

• Product Name: (3aα,7aα)-Octahydrobenzo[c]thiophene
• Synonyms: (3aα,7aα)-Octahydrobenzo[c]thiophene
• CAS NO: 54053-76-8
• Molecular Formula: C₈H₁₄S
• Molecular Weight: 142.26176
• Mol File: 54053-76-8.mol
• Article Data: 5

Chemical Properties

• Appearance: /
• CAS DataBase Reference: (3aα,7aα)-Octahydrobenzo[c]thiophene(CAS DataBase Reference)
• NIST Chemistry Reference: (3aα,7aα)-Octahydrobenzo[c]thiophene(54053-76-8)
• EPA Substance Registry System: (3aα,7aα)-Octahydrobenzo[c]thiophene(54053-76-8)

Safety Data

• Hazardous Substances Data: 54053-76-8(Hazardous Substances Data)

Upstream product

• 13019-30-2 (±)-1,2-bis(bromomethyl)cyclohexane 
• 59461-66-4 cis-cyclohexane-1,2-diyldimethyl ditosylate 
• 3710-30-3 1,7-Octadiene 
• 15753-50-1 cis-1,2-cyclohexanedimethanol 
• 2484-60-8 cyclohexane-1,2-dicarboxylic acid monomethyl ester 
• 935-79-5 cis-1,2,3,6-tetrahydrophthalic anhydride 
• 13019-30-2 trans-1,2-bis(bromomethyl)cyclohexane 
• 3205-36-5 trans-1,2-bis(hydroxymethyl)cyclohexane di-p-toluene-sulfonate 
• 76155-27-6 (+/-)-trans-2-(hydroxymethyl)cyclohexylmethanol 
• 96836-97-4 diethyl cyclohexane-trans-1,2-dicarboxylate 
• 4841-85-4 trans-1,2-bis(ethoxycarbonyl)-4-cyclohexene 

Downstream Products

• 92278-01-8 (3aR,7aS)-2-(2,5-Dihydroxy-phenyl)-octahydro-benzo[c]thiophenium; chloride 

Relevant articles and documents

Metallacycle transfer from zirconium to main group elements: A versatile synthesis of heterocycles

The reaction of zirconium metallacycles is used to produce a variety of main group heterocycles including borole Diels-Alder dimers, galloles, indacyclopentadienes, siloles, germoles, stannoles, phospholes, arsoles, stiboles, bismoles, thiophenes, selenophenes, dihydrothiophenes, dihydroselenophenes, tetrahydrothiophenes, tetrahydro-selenophenes, stannacyclopentanes, phospholenes, and isothiazoles. An X-ray crytallographic study of the borole DielsAlder dimer of 1-phenyl-2,3,4,5-tetramethylborole is discussed and compared with the structure of 7-norbornenyl carbenium ions. The scope and potential for this metallacycle transfer reaction are delineated.

Zirconium-Mediated Ring Construction from Dienes: Remarkable Effect of Ligands on Stereochemistry

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Reactions of α-Halotetrahydrothiophene 1,1-Dioxides with Strong Bases

This article describes the halogenated sulfones 2, 3, 7, 11, 16 and 18 obtained from the hitherto unknown intermediates 4, 5, 6 and 8, 9, 10 and from 14, 15.An account is given of Ramberg-Baecklund-type reactions undergone by the α-halogenated cyclic sulfones 2a and 7 with bases at high temperature.