541546-94-5

Basic information

• Product Name: allyl α,β-D-ribofuranoside
• Synonyms: allyl α,β-D-ribofuranoside
• CAS NO: 541546-94-5
• Molecular Weight: 190.196
• Mol File: 541546-94-5.mol
• Article Data: 10

Chemical Properties

• CAS DataBase Reference: allyl α,β-D-ribofuranoside(CAS DataBase Reference)
• NIST Chemistry Reference: allyl α,β-D-ribofuranoside(541546-94-5)
• EPA Substance Registry System: allyl α,β-D-ribofuranoside(541546-94-5)

Safety Data

• Hazardous Substances Data: 541546-94-5(Hazardous Substances Data)

Upstream product

• 532-20-7 D-Ribose 
• 107-18-6 allyl alcohol 
• 50-69-1 D-ribose 
• 2280-44-6 D-Glucose 

Downstream Products

• 121682-55-1 allyl 2,3,5-tri-O-benzyl-α,β-D-ribofuranoside 
• 331625-54-8 allyl 2,3,5-tri-O-p-methoxybenzyl-D-ribofuranose 
• 331625-80-0 (2S,3R,4R)-2,3,5-tris(4-methoxybenzyloxy)-1,4-pentanediol 
• 637741-29-8 (2R,3R,4S)-1,3,4-tris(4-methoxybenzyloxy)-5-(tert-butyldimethylsiloxy)-2-pentanol 
• 190315-43-6 (2R,3S,4R)-2-(hydroxymethyl)tetrahydrothiophene-3,4-diol 
• 541546-97-8 1,4-anhydro-2,3,5-tri-O-p-methoxybenzyl-4-thio-D-ribitol 
• 331625-55-9 (2R,3R,4S)-1,3,4-Tris-(4-methoxy-benzyloxy)-5-trityloxy-pentan-2-ol 
• 331625-84-4 (2S,3R,4S)-1,3,4-Tris-(4-methoxy-benzyloxy)-5-trityloxy-pentan-2-ol 
• 331626-35-8 (E)-2-Methyl-pentadec-2-enoic acid (1S,2S,3S)-4-hydroxy-2,3-bis-(4-methoxy-benzyloxy)-1-(4-methoxy-benzyloxymethyl)-butyl ester 
• 331625-56-0 (E)-2-Methyl-pentadec-2-enoic acid (1R,2S,3S)-4-hydroxy-2,3-bis-(4-methoxy-benzyloxy)-1-(4-methoxy-benzyloxymethyl)-butyl ester 
• 331626-38-1 (E)-2-Methyl-pentadec-2-enoic acid (1S,2R,3R)-2,3-bis-(4-methoxy-benzyloxy)-1-(4-methoxy-benzyloxymethyl)-3-methoxycarbonyl-propyl ester 
• 331625-57-1 (E)-2-Methyl-pentadec-2-enoic acid (1R,2R,3R)-2,3-bis-(4-methoxy-benzyloxy)-1-(4-methoxy-benzyloxymethyl)-3-methoxycarbonyl-propyl ester 

Relevant articles and documents

Reactivity of vinyl ethers and vinyl ribosides in UV-initiated free radical copolymerization with acceptor monomers

The reactivity of various vinyl ethers and vinyloxy derivatives of ribose in the presence of diethyl fumarate or diethyl maleate was investigated for evaluating the potential of donor-acceptor-type copolymerization applied to unsaturated monomers derived from renewable feedstock. The photochemically induced polymerization of model monomer blends in the bulk state was monitored by infrared spectroscopy. The method allowed us to examine the influence of monomer pair structure on the kinetic profiles. The simultaneous consumption of both monomers was observed, supporting an alternating copolymerization mechanism. A lower reactivity of the blends containing maleates compared with fumarates was confirmed. The obtained kinetic data revealed a general correlation between the initial polymerization rate and the Hansen parameter aeH associated with the H-bonding aptitude of the donor monomer.

Synthesis of Phenolic Glycosides: Glycosylation of Sugar Lactols with Aryl Bromides via Dual Photoredox/Ni Catalysis

Multifarious sugar lactols were efficiently transformed into the corresponding phenolic glycosides by treating with aryl bromides in acetonitrile with Ir[dF(CF3)ppy]2(dtbbpy)(PF6) as a photocatalyst under visible light irr

Stereoselective ribosylation of amino acids

The glycosylation properties of ribofuranosyl N-phenyltrifluoroacetimidates toward carboxamide side chains of asparagine and glutamine were investigated. Conditions were found that promote nearly exclusive formation of the α-anomerically configured N-glycosides. The strategy allows for the synthesis of Fmoc-amino acids suitably modified for the preparation of ADP-ribosylated peptides. Furthermore, ribosylation of serine with these donors proved to be completely α-selective, and for the first time, α-ribosylated glutamic and aspartic acid, the naturally occurring sites for poly-ADP-ribosylation, were synthesized.