58246-54-1

Basic information

• Product Name: 2-Pyrrolidinemethanol,1-nitroso-,(2S)-(9CI)
• Synonyms: 2-Pyrrolidinemethanol,1-nitroso-,(2S)-(9CI)
• CAS NO: 58246-54-1
• Molecular Formula: C₅H₁₀N₂O₂
• Molecular Weight: 130.15
• Product Categories: PYRROLIDINE
• Mol File: 58246-54-1.mol
• Article Data: 3

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 2-Pyrrolidinemethanol,1-nitroso-,(2S)-(9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Pyrrolidinemethanol,1-nitroso-,(2S)-(9CI)(58246-54-1)
• EPA Substance Registry System: 2-Pyrrolidinemethanol,1-nitroso-,(2S)-(9CI)(58246-54-1)

Safety Data

• Hazardous Substances Data: 58246-54-1(Hazardous Substances Data)

Upstream product

• 23356-96-9 (S)-1-Pyrrolidin-2-yl-methanol 
• 147-85-3 L-proline 

Downstream Products

• 162755-95-5 (S)-2-<(Benzyloxy)methyl>-N-nitrosopyrrolidine 
• 127221-89-0 (S)-(-)-1-amino-2-(hydroxymethyl)pyrrolidine 
• 874290-48-9 (1-Ethyl-propylidene)-((S)-2-trityloxymethyl-pyrrolidin-1-yl)-amine 
• 188053-41-0 N-((S)-2-Hydroxymethyl-pyrrolidin-1-yl)-benzamide 
• 89597-97-7 (2S)-benzyloxymethyl-pyrrolidine 
• 162755-96-6 (S)-1-Amino-2-<(benzyloxy)methyl>pyrrolidine 
• 162755-97-7 (S)-2-<(Benzyloxy)methyl>-N-glutarimidopyrrolidine 
• 162756-00-5 (6R)-N-<(2S)-2-<(Benzyloxy)methyl>pyrrolidino>-6-<(2-bromo-3,4-dimethoxybenzoyl)methyl>-2-piperidinone 
• 164328-20-5 (6R)-N-<(2S)-2-<(Benzyloxy)methyl>pyrrolidino>-6-<(3,4-dimethoxybenzoyl)methyl>-2-piperidinone 

Relevant articles and documents

A highly enantioselective, moderately anti-selective aldol reaction using a novel hydrazone moiety as stereo director

The use of novel hydrazones as stereo directors with a view to develop a highly enantioselective, anti-diastereoselective aldol addition procedure has been investigated. A number of proline-derived hydrazones were produced and their effectiveness in direc

CHIROPTICAL PROPERTIES OF N-NITROSOPYRROLIDINES AND N-NIROSAMINO ACIDS

CD data for a variety of N-nitrosamino acids and N-nitrosopyrrolidines are presented.The effects of nitrosamino group conformation, pyrrolidine ring geometry, different perturbing substituents, and especially intramulecular H-bonding upon the n?* CD band are discussed.Stereochemical conclusions can be made with confidence in many cases, although no sector diagram, as yet published, succesfully correlates all the available chiroptical data in this series of compounds.However, a negative CD band due to the ??* transition was observed for all N-nitrosamines having the L-proline configuration at C-2, regardless of nitroso group conformation; it is suggested that this band be used whenever possible for stereochemical correlations.