60434-95-9Relevant articles and documents
Synthesis and structural characterization of (2E,3E)-N1,N 2-Bis(4-chlorobenzylidene)ethane-1,2-diamine
Liang, Zu-Pei,Li, Jian
, p. 663 - 665 (2013)
Present compound (2E,3E)-N1,N2-bis(4- chlorobenzylidene)ethane-1,2-diamine (C16H14C 14N2, Mr = 305.19) was synthesized and characterized by elemental analysis, FT-IR, 1H NMR and single crystal X-ray diffraction. The crystal belongs to monoclinic, space group Cc, with a = 10.166(2), b = 10.345(2), c = 26.650(5) ?, β = 91.91(3)°, V = 2801.1(10) ?3, Z = 8, Dc = 1.447 g/cm3, λ = 0.71073 ?, μ(MoKα) = 0.454 mm-1, F (000) = 1264. The final refinement gave R = 0.0652, wR(F2) = 0.1582 for 4,578 observed reflections with I > 2σ (I). X-Ray diffraction analysis reveals that the asymmetric unit of the title compound consists of two independent molecules. Each independent molecule adopts an E configuration about the central C=N functional bond. The dihedral angles between the two benzene rings are 2.3(2) and 0.5(2)°, respectively in two independent molecules. The molecules are linked through C- H···Cl hydrogen bonds interactions.
Phototriggered cytotoxic properties of tricarbonyl manganese(I) complexes bearing α-diimine ligands towards HepG2
Mansour, Ahmed M.,Radacki, Krzysztof,Khaled, Rabaa M.,Soliman, Marwa H.,Abdel-Ghani, Nour T.
, p. 135 - 147 (2021/03/06)
Reaction between bromo tricarbonyl manganese(I) and N,N′-bis(phenyl)-1,4-diaza-1,3-butadiene ligands, bearing different electron-donating and electron-withdrawing groups R?=?OCH3, Cl, and NO2 in the ortho- and para-positions on the p
Synthesis and biological evaluation of novel cYY analogues targeting Mycobacterium tuberculosis CYP121A1
Kishk, Safaa M.,McLean, Kirsty J.,Sood, Sakshi,Helal, Mohamed A.,Gomaa, Mohamed S.,Salama, Ismail,Mostafa, Samia M.,de Carvalho, Luiz Pedro S.,Munro, Andrew W.,Simons, Claire
supporting information, p. 1546 - 1561 (2019/03/05)
The rise in multidrug resistant (MDR) cases of tuberculosis (TB) has led to the need for the development of TB drugs with different mechanisms of action. The genome sequence of Mycobacterium tuberculosis (Mtb) revealed twenty different genes coding for cy
Nano tetraimine Pd(0) complex as an efficient catalyst for phosphine-free Suzuki reaction in water and copper-free Sonogashira reaction under aerobic conditions
Mandegani, Zeinab,Asadi, Mozaffar,Asadi, Zahra
, p. 657 - 663 (2016/07/19)
A nano tetraimine Pd(0) complex catalyst was successfully used as an efficient heterogeneous catalyst for the phosphine-free palladium-catalysed Suzuki coupling reaction in water at 80 °C. This nano tetraimine Pd(0) complex was also used for copper-free Sonogashira reaction in dimethylformamide at 100 °C. The catalyst was easily recovered from the reaction mixture by centrifugation and reused for at least six cycles without any significant loss in its catalytic activity. Analysis of the reaction mixture using inductively coupled plasma analysis showed that leaching of palladium from the catalyst was negligible. The reactions can be performed efficiently for aryl iodides, bromides and also chlorides.