65987-12-4

Basic information

• Product Name: 1-O-allyl-4,6-O-benzylidene-α-D-glucopyranoside
• Synonyms: 1-O-allyl-4,6-O-benzylidene-α-D-glucopyranoside
• CAS NO: 65987-12-4
• Molecular Weight: 308.331
• Mol File: 65987-12-4.mol
• Article Data: 27

Chemical Properties

• CAS DataBase Reference: 1-O-allyl-4,6-O-benzylidene-α-D-glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: 1-O-allyl-4,6-O-benzylidene-α-D-glucopyranoside(65987-12-4)
• EPA Substance Registry System: 1-O-allyl-4,6-O-benzylidene-α-D-glucopyranoside(65987-12-4)

Safety Data

• Hazardous Substances Data: 65987-12-4(Hazardous Substances Data)

Upstream product

• 100-52-7 benzaldehyde 
• 7464-56-4 1-O-allyl-α-D-glucopyranoside 
• 1125-88-8 benzaldehyde dimethyl acetal 
• 48149-74-2 allyl D-glucopyranoside 
• 84276-56-2 allyl 4,6-O-benzylidene-β-D-glucopyranoside 
• 30688-66-5 4,6-O-benzylidene-D-glucopyranose 
• 107-18-6 allyl alcohol 
• 3006-41-5 4,6-O-benzylidene-α,β-D-galactopyranose 
• 106-95-6 allyl bromide 
• 2595-07-5 allyl β-D-glucopyranoside 
• 492-61-5 β-D-glucose 
• 572-09-8 2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide 
• 10343-15-4 Acetic acid (2R,3R,4S,5R,6R)-3,5-diacetoxy-2-acetoxymethyl-6-allyloxy-tetrahydro-pyran-4-yl ester 
• 604-69-3 β-D-glucose pentaacetate 

Downstream Products

• 155896-88-1 Allyl 2-O-Benzoyl-4,6-O-benzylidene-α-D-glucopyranoside 
• 87326-31-6 1-O-allyl-2,3-di-O-benzyl-4,6-O-benzylidene-α-D-glucopyranoside 
• 223124-25-2 allyl 4,6-O-benzylidene-2,3-di-O-methyl-α-D-glucopyranoside 
• 540474-09-7 allyl 2-O-benzoyl-4,6-O-benzylidene-β-D-glucopyranoside 
• 137172-47-5 allyl 3-O-benzyl-(R)-4,6-O-benzylidene-β-D-glucopyranoside 
• 161277-33-4 allyl 2-O-benzyl-(R)-4,6-O-benzylidene-β-D-gluco-pyranoside 
• 145773-08-6 allyl 2,3-di-O-benzyl-4,6-O-benzylidene-β-D-glucopyranoside 
• 99541-24-9 O-(2,3-di-O-benzyl-β-D-glucopyranosyl)-(1->4)-3-O-acetyl-1,6-anhydro-2-azido-2-deoxy-β-D-glucopyranose 
• 99541-26-1 O-(methyl 2,3-di-O-benzyl-β-D-glucopyranosyluronate)-(1->4)-3-O-acetyl-1,6-anhydro-2-azido-2-deoxy-β-D-glucopyranose 
• 400865-12-5 allyl (2-O-benzoyl-4,6-O-benzylidene-3-O-chloroacetyl-β-D-glucopyranosyl)-(1->4)-2,3,6-tri-O-benzoyl-β-D-glucopyranoside 

Relevant articles and documents

The compound or its salt, and radiation sensitizer

In combination with the novel pharmaceutical compound [a] tumors to radiation. (I) represented by the following formula [a] compound or a salt thereof. In the formula (I), R1 C is1 - C26 The aliphatic hydrocarbon group. Fi

Preparation method of fondaparinux sodium disaccharide intermediate

The invention discloses a preparation method of fondaparinux sodium disaccharide intermediate. 1-O-substituent sulfonyl-2,3-bis-O-benzyl-4,6-O-benzylidene-beta-D-glucopyranose directly reacts with 1,6-dehydrated-2-deoxy-2-azido-3-O-acetyl-beta-D-glucopyranose to prepare the fondaparinux sodium disaccharide intermediate as shown in a formula I; and meanwhile, the fondaparinux sodium intermediate asshown in the formula I can be used as a raw material to synthesize fondaparinux sodium intermediate as shown in a formula IV. The preparation method is simple and small in steps, the yield is high, the atomic utilization rate is high, the three wastes are small, and the preparation method is suitable for industrial large-scale production. Please see the description for the formula.

Stereoselective dihydroxylation reaction of alkenyl β- D -hexopyranosides: A methodology for the synthesis of glycosylglycerol derivatives and 1-O-Acyl-3-O-β- D -glycosyl-sn-glycerol analogues

A variety of new glycosylglycerol derivatives have been prepared by stereoselective dihydroxylation of a range of alkenyl β-D-hexopyanosides under Donohoe's conditions. We have studied the relationship between the diastereoisomeric excess and the structural features of the precursor (sugar and alkenyl moieties). The stereochemical yields demonstrated that the presence of a hydrogen-bond donor group (OH, NHAc) at the 2-position of the sugar moiety is required to obtain high levels of stereofacial discrimination. New 1-O-acyl-3-O-β-D-glycosyl-sn-glycerol analogues were obtained by functionalisation of the primary hydroxy group with a fatty acid. Preliminary cytotoxic activity assays of both glycosylglycerol and glycoglycerolipid analogues are also presented. An efficient asymmetric dihydroxylation reaction of alkenyl β-D-hexopyranoside derivatives is described. New glycosylglycerol and glycoglycerolipid analogues have been synthesised by this methodology. Preliminary cytotoxic activity assays are presented. Copyright