6605-39-6

Basic information

• Product Name: cyclohexyl 2,3,4,6-tetra-O-acetyl-α-D-glucopyranoside
• CAS NO: 6605-39-6
• Molecular Weight: 430.452
• Mol File: 6605-39-6.mol
• Article Data: 14

Chemical Properties

• CAS DataBase Reference: cyclohexyl 2,3,4,6-tetra-O-acetyl-α-D-glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: cyclohexyl 2,3,4,6-tetra-O-acetyl-α-D-glucopyranoside(6605-39-6)
• EPA Substance Registry System: cyclohexyl 2,3,4,6-tetra-O-acetyl-α-D-glucopyranoside(6605-39-6)

Safety Data

• Hazardous Substances Data: 6605-39-6(Hazardous Substances Data)

Upstream product

• 1152-39-2 p-methylphenyl 1-thio-β-D-glucopyranoside 
• 108-93-0 cyclohexanol 
• 604-69-3 β-D-glucose pentaacetate 
• 108-24-7 acetic anhydride 
• 29781-93-9 cyclohexylglucoside 
• 1464-44-4 phenyl-β-D-glucopyranoside 
• 13871-89-1 trimethylsilyl cyclohexyl ether 
• 572-09-8 2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide 
• 604-68-2 α-D-glucopyranose peracetylate 
• 13035-49-9 2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl iodide 
• 19879-84-6 tetraacetyl thioglucose 
• 35927-64-1 2-bromoethyl 1-deoxy-1-thio-2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside 
• 6605-39-6 cyclohexyl 2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside 
• 100432-86-8 1-deoxy-1-[(R/S)-(phenyl)sulfinyl]-2,3,4,6-tetra-O-acetyl-β-D-glucopyranose 

Downstream Products

• 6605-39-6 cyclohexyl 2,3,4,6-tetra-O-acetyl-α-D-glucopyranoside 
• 25320-98-3 cyclohexyl glucoside 
• 5284-99-1 cyclohexyl glucoside 

Relevant articles and documents

AuCl3-AgOTf promoted O-glycosylation using anomeric sulfoxides as glycosyl donors at room temperature

Activation of sulfoxide as glycosyl donors using AuCl3/AgOTf reagent system has been described. Under optimal reaction conditions, both armed and disarmed glycosyl sulfoxide donors were found to react with a range of primary, secondary, and tertiary alcohol acceptors, and sugar derived glycosyl acceptors to afford the corresponding glycosides in moderate to good yields with predictable selectivity. The reactions are quick (20–60 min), facile at room temperature and the reactions conditions tolerate acid sensitive groups.

Polyvinyl trisulfonate ethylamine based solid acid catalyst for the efficient glycosylation of sugars under solvent free conditions

Heterogeneous Bronsted solid acid catalysts have the potential to decrease the environmental impact related to chemical production. Herein, we have synthesized polyvinyl bound trisulfonate ethylamine chloride (PV-THEAC) and polyvinyl bound disulfonate ethylamine (PV-DSEA) as Bronsted solid acid catalysts which exhibited effective catalytic activity for acid catalyzed glycosylation reactions with sugar derivatives. In particular, 0.3 equiv. of the PV-THEAC catalyst was found to be the most efficient and a reusable catalyst for glycosylation reactions. A high density of the trisulfonic group (-OSO3H) contributed to the excellent catalytic activity during glycosylation. Moreover, glycosylation reactions with d-mannose, d-xylose and d-glucose have been studied with alcohol. Remarkable acceleration of the glycosylation reaction using a glycosyltrichloroacetimidate donor was obtained with the selective production of β-glycoside.

Efficient glycosylation of unprotected sugars using sulfamic acid: A mild eco-friendly catalyst

Sulfamic acid, a mild and environmentally benign catalyst has been successfully used in the Fischer glycosylation of unprotected sugars for the preparation alkyl glycosides. A diverse range of aliphatic alcohols have been used to prepare a series of alkyl glycosides in good to excellent yield.