6721-33-1Relevant articles and documents
Two novel organic-inorganic hybrid compounds with straight and zigzag chain alignments of Cu(II) centers: Synthesis, crystal structure, spectroscopy, thermal analysis and magnetism
Nenwa, Justin,Djomo, Edith D.,Nfor, Emmanuel N.,Djonwouo, Patrick L.,Mbarki, Mohammed,Fokwa, Boniface P.T.
, p. 26 - 33 (2015/07/15)
Abstract Two hybrid salts, viz. bis(guanidinium) bis(oxalato)cuprate(II) (1) and bis(2-aminopyridinium) bis(oxalato)cuprate(II) trihydrate (2) have been synthesized and characterized by elemental and thermal analyses, IR spectroscopy, single-crystal X-ray diffraction and SQUID magnetometry. Compounds 1 and 2 crystallize in the monoclinic P21/c and triclinic P1ˉ space groups, respectively. In both structures, the four-coordinated Cu(II) ion in [Cu(C2O4)2]2- unit weakly interacts with two axial O-atoms of neighboring units to build a prolate CuO6 octahedron, with regular axial Cu-O bonds of 2.825 ? in 1, whereas in 2 two different Cu-O bonds (2.814 ? and 2.701 ?) are found. In 1, stacking of [Cu(C2O4)2]2- units across internal symmetry-related O-atoms results in equidistantly spaced monomers, thus forming straight Cu(II) chains with regular spacing of Cu?Cu = 3.582 ?. By contrast, in 2, stacking of the [Cu(C2O4)2]2- entities occurs via external symmetry-related O-atoms, yielding zigzag Cu(II) chains with shorter intra-dimer spacing of [Cu?Cu]intra = 3.430 ? and longer inter-dimer spacing of [Cu?Cu]inter = 4.961 ?. The anhydrated compound 1 is stable up to 250 °C, whereas the hydrated compound 2 shows a significant weight loss of solvent water molecules at about 70°C, followed by the decomposition of the network. The magnetic measurements in the 2-300 K temperature range revealed weak antiferromagnetic coupling in the two hybrid salts.
PROCESS FOR PRODUCING METHIONINE
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Page/Page column 2, (2008/12/07)
A process for producing methionine by hydrolysis of 5-(β-methylmercaptoethyl)hydantoin in the presence of an alkali, in which the concentration of hydrogen sulfide is 5 ppm or less in a solution used for hydrolysis comprising 5-(β-methylmercaptoethyl)hydantoin and the alkali, whereby methionine can be stably produced for a long period of time.
ENZYMATIC DECOMPOSITION OF CARBAMIDE WITH IMMOBILIZED UREASE
Berezina, N. P.,Kononenko, N. A.,Ivina, O. P.,Vitul'skaya, N. V.,Shamolina, I. A.
, p. 372 - 375 (2007/10/02)
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