6939-75-9Relevant articles and documents
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Sah,Lei,Fang
, p. 4727 (1933)
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Discriminating non-ylidic carbon-sulfur bond cleavages of sulfonium ylides for alkylation and arylation reactions
Cai, Lei,Chen, Qi,Fang, Jing,Li, Ting,Liao, Zhiwen,Ma, Xiang,Meng, Lingkui,Sun, Jiuchang,Wan, Qian,Zeng, Jing
, (2021/07/25)
A sulfonium ylide participated alkylation and arylation under transition-metal free conditions is described. The disparate reaction pattern allowed the separate activation of non-ylidic S-alkyl and S-aryl bond. Under acidic conditions, sulfonium ylides serve as alkyl cation precursors which facilitate the alkylations. While under alkaline conditions, cleavage of non-ylidic S-aryl bond produces O-arylated compounds efficiently. The robustness of the protocols were established by the excellent compatibility of wide variety of substrates including carbohydrates.
Acidic ion functionalized N-doped hollow carbon for esterification of levulinic acid
Zhang, Qifang,Jiang, Pingping,Nie, Zhixin,Zhang, Pingbo
, p. 1588 - 1593 (2020/02/06)
Acidic ion functionalized N-doped hollow carbon (NHC-[C4N][SO3CF3]) has been successfully synthesized by quaternization of N-doped hollow carbon (NHC) with 1,4-butanesultone, followed by ion exchange with trifluoromethanesulfonic acid. The catalyst was characterized by Fourier transform infrared (FT-IR), scanning electron microscopy (SEM), acid-base titration techniques and other methods. A hollow spherical catalyst with regular morphology, high acid density (2.72 mmol g-1) and good stability was obtained. Various characterizations showed that NHC-[C4N][SO3CF3] possesses abundant nanopores (3.41 nm), large Brunauer-Emmett-Teller (BET) surface area (154 m2 g-1) and strong and controllable Br?nsted acid sites. The as-prepared NHC-[C4N][SO3CF3] was then used for the acid-catalyzed esterification of levulinic acid with ethanol. At the optimum conditions, the highest conversion of levulinic acid reached 94.17% and high conversion was maintained after recycling four times. Further investigation of the catalytic activity in the esterification of different aliphatic and aromatic alcohols with levulinate was carried out, showing good results.