70561-76-1

Basic information

• Product Name: (±)-allosedamine
• Synonyms: (±)-allosedamine
• CAS NO: 70561-76-1
• Molecular Weight: 219.327
• Mol File: 70561-76-1.mol
• Article Data: 13

Chemical Properties

• CAS DataBase Reference: (±)-allosedamine(CAS DataBase Reference)
• NIST Chemistry Reference: (±)-allosedamine(70561-76-1)
• EPA Substance Registry System: (±)-allosedamine(70561-76-1)

Safety Data

• Hazardous Substances Data: 70561-76-1(Hazardous Substances Data)

Upstream product

• 101113-68-2 (+/-)-sedaminone 
• 1941-84-0 sodium pentanolate 
• 497-88-1 sedamine 
• 98-88-4 benzoyl chloride 
• 54441-66-6 tert-butyl benzoylacetate 
• 57147-18-9 1-methyl-2-ethoxy-6-piperidone 
• 110-94-1 1,5-pentanedioic acid 
• 25077-25-2 N-methyladipinimide 
• 70546-85-9 2-phenyl-3,3a,4,5,6,7-hexahydro-2H-isoxazolo<2,3-a>pyridine 
• 100-42-5 styrene 
• 4801-58-5 N-hydroxypiperidine 
• 2294-74-8 1-phenyl-2-pyridin-2-yl-ethanol 
• 100-52-7 benzaldehyde 
• 73853-37-9 1-phenyl-2-(piperidin-2-yl)ethan-1-ol 

Downstream Products

• 101113-68-2 (+/-)-sedaminone 
• 497-89-2 2-[1-methyl-(2S)-piperidin-2-yl]-1-phenyl-(1R)-ethan-1-ol 
• 67008-23-5 (2R)-2-((2R)-2-hydroxy-2-phenylethyl)-1-methylpiperidine 
• 497-88-1 (-)-sedamine 

Relevant articles and documents

(±)-Sedamine and (±)-allosedamine by redution of n-methyl-2-phenacylidenepiperidine

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A rapid access to (±)-sedamine and some original N -benzyl unsaturated analogues

Reduction of N-alkyl-2-(2-hydroxy-2-phenylethyl)pyridinium salts using excess of sodium triacetoxyborohydride afforded exclusively the corresponding tetrahydropyridine derivative bearing a piperidine ring with a double bond in the 3,4-position. Furthermore, under these conditions, syn-1,3-amino alcohols were obtained in good yield and diastereoselectivity. Georg Thieme Verlag Stuttgart · New York.

Expeditious syntheses of (±)-allo-sedamine and (±)-allo- lobeline via a combination of aza-Sakurai-Hosomi and hydroformylation reactions

The expeditious preparation of allo-sedamine and allo-lobeline via 1,3-diastereoselective aza-Sakurai-Hosomi reaction followed by hydroformylation is reported. Georg Thieme Verlag Stuttgart.