73982-28-2Relevant articles and documents
Endohedral Functionalized Cage as a Tool to Create Frustrated Lewis Pairs
Yang, Jian,Chatelet, Bastien,Dufaud, Véronique,Hérault, Damien,Michaud-Chevallier, Sabine,Robert, Vincent,Dutasta, Jean-Pierre,Martinez, Alexandre
, p. 14212 - 14215 (2018/10/15)
A frustrated Lewis pair (FLP) system was obtained by confinement of the Lewis base partner, a Verkade's superbase, in a molecular cavity. Whereas the model superbase lacking cavity displayed no catalytic activity in Morita–Baylis–Hillman (MBH) reactions,
A convenient synthesis of 2,2-diphenyl-cyclohexanone and 6,6-diphenyl-2-cyclohexen-one
Bacque,Paris
, p. 2259 - 2272 (2007/10/02)
A short, convenient and large scale synthesis of 2,2-diphenyl-cyclohexanone and 6,6-diphenyl-2-cyclohexen-one using respectively the regioselective hydrogenolysis of 1,3-diketone (3) and the radical reduction of 3-bromo-2-enone (4) is reported.