81585-72-0Relevant articles and documents
A comparison of reactivity of (EtO)2P(O)CH2I with related non-phosphorus-containing iodides in the radical iodine atom transfer addition
Balczewski, Piotr,Bialas, Tomasz,Szadowiak, Aldona
, p. 186 - 188 (2003)
Based on competitive reactions and 1H NMR measurements, it was found that (EtO)2P(O)CH2I is at least 2-3 orders of magnitude less reactive than other non-phosphorus iodides of the EWG-CH2I type (EWG = NC COOMe,
Imidazolium-Based Ionic Network as a Robust Heterogeneous Catalyst in Synthesis of Phenacyl Derivatives
Kakesh,Sayyahi,Badri,Tahanpesar
, p. 1218 - 1220 (2019/07/16)
A new imidazolium-based poly(ionic liquid) has been synthesized and used as a robust heterogeneous catalyst for the preparation of phenacyl derivatives by an SN2 reaction of different phenacyl bromides with a broad range of nucleophiles. The products are obtained in high yields under mild conditions. The catalyst can be recycled efficiently.
Mild and General Synthesis of Pyrrolo[2,1-a]isoquinolines and Related Polyheterocyclic Frameworks from Pyrrole Precursors Derived from a Mechanochemical Multicomponent Reaction
Leonardi, Marco,Villacampa, Mercedes,Menéndez, J. Carlos
, p. 2570 - 2578 (2017/03/14)
The combination of a three-component, solvent-free pyrrole synthesis performed under mechanochemical conditions with a TMSOTf-catalyzed oxonium-mediated cyclization gave general access to pyrrolo[2,1-a]isoquinoline derivatives under very mild conditions.