83638-29-3Relevant articles and documents
Iron-catalysed, hydride-mediated reductive cross-coupling of vinyl halides and Grignard reagents
Le Bailly, Bryden A. F.,Greenhalgh, Mark D.,Thomas, Stephen P.
, p. 1580 - 1582 (2012)
An iron-catalysed, hydride-mediated reductive cross-coupling reaction has been developed for the preparation of alkanes. Using a bench-stable iron(ii) pre-catalyst, reductive cross-coupling of vinyl iodides, bromides and chlorides with aryl- and alkyl Grignard reagents successfully gave the products of formal sp3-sp3 cross-coupling reactions.