853955-61-0

Basic information

• Product Name: Benzenemethanol, 2-[dimethyl(1E)-1-octenylsilyl]-
• CAS NO: 853955-61-0
• Molecular Formula: C17H28OSi
• Molecular Weight: 276.494
• Mol File: 853955-61-0.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Benzenemethanol, 2-[dimethyl(1E)-1-octenylsilyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenemethanol, 2-[dimethyl(1E)-1-octenylsilyl]-(853955-61-0)
• EPA Substance Registry System: Benzenemethanol, 2-[dimethyl(1E)-1-octenylsilyl]-(853955-61-0)

Safety Data

• Hazardous Substances Data: 853955-61-0(Hazardous Substances Data)

Upstream product

• 853955-59-6 dimethyl-[2-(2-acetoxymethyl)phenyl]-silane 
• 629-05-0 n-octyne 
• 321903-29-1 1,1-dimethyl-1,3-dihydrobenzo[c][1,2]oxasilole 
• 18982-54-2 o-bromobenzyl alcohol 
• 17100-66-2 2-(tetrahydropyranyloxy)methylbromobenzene 
• 853955-58-5 dimethyl(2-(((tetrahydro-2H-pyran-2-yl)oxy)methyl)phenyl)silane 

Downstream Products

• 853955-59-6 dimethyl-[2-(2-acetoxymethyl)phenyl]-silane 
• 853955-65-4 [2-(hydroxymethyl)phenyl]dimethyl(propen-2-yl)silane 
• 853955-68-7 [2-(hydroxymethyl)phenyl]-dimethyl-(2-methyl-1-propenyl)-silane 
• 853955-66-5 (2-(hydroxymethyl)phenyl)-dimethyl(1-phenylethenyl)-silane 
• 926321-10-0 (E)-5-tert-butyldimethylsiloxy-1-pentenyl[2-(hydroxymethyl)phenyl]dimethylsilane 
• 913621-65-5 [2-(hydroxymethyl)phenyl]dimethyl(vinyl)silane 
• 321903-29-1 1,1-dimethyl-1,3-dihydrobenzo[c][1,2]oxasilole 
• 1031869-24-5 C₁₇H₂₄ 
• 1024756-99-7 (E)-N-[1-phenyl-2-nonen-1-yl]-4-nitrobenzenesulfonamide 
• 81953-05-1 (E)-5-dodecen-2-one 
• 64955-00-6 (E)-3-(1-octen-1-yl)cyclopentanone 
• 106470-35-3 (E)-1-methoxy-4-(non-2-en-1-yl)benzene 
• 75473-94-8 (E)-(non-2-en-1-yl)benzene 
• 73062-38-1 (E,E)-1-phenyl-undecadiene 

Relevant articles and documents

Silicon-Based Cross-Coupling Reagent and Production Method of Organic Compound Using the Same

In one embodiment of the present invention, a silicon-based cross-coupling reagent is disclosed which is a highly stable tetraorganosilicon compound allowing for a cross-coupling reaction under mild reaction conditions without using fluoride ions, transition metal promoter, or strong bases, and the residue of the silicon reagent can be recovered and reused. The silicon-based cross-coupling reagent is a silicon compound in which an o-hydroxymethylphenyl group is connected to a silicon atom for intramolecular activation.

Alkenyl- and aryl[2-(hydroxymethyl)phenyl]dimethylsilanes: An entry to tetraorganosilicon reagents for the silicon-based cross-coupling reaction

Alkenyl- and aryl[2-(hydroxymethyl)phenyl]dimethylsilanes, highly stable tetraorganosilicon reagents, are found to react with aryl and alkenyl iodides in the presence of a palladium catalyst and K2CO3 as a base, significantly milder conditions compared with those ever reported for the silicon-based cross-coupling reactions. The reaction tolerates a wide range of functional groups, including silyl protectors, and allows a gram-scale synthesis to recover and reuse the silicon residue. Copyright