853955-68-7

Basic information

• Product Name: Benzenemethanol, 2-[dimethyl(2-methyl-1-propenyl)silyl]-
• CAS NO: 853955-68-7
• Molecular Formula: C13H20OSi
• Molecular Weight: 220.387
• Mol File: 853955-68-7.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Benzenemethanol, 2-[dimethyl(2-methyl-1-propenyl)silyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenemethanol, 2-[dimethyl(2-methyl-1-propenyl)silyl]-(853955-68-7)
• EPA Substance Registry System: Benzenemethanol, 2-[dimethyl(2-methyl-1-propenyl)silyl]-(853955-68-7)

Safety Data

• Hazardous Substances Data: 853955-68-7(Hazardous Substances Data)

Upstream product

• 18982-54-2 o-bromobenzyl alcohol 
• 853955-61-0 (E)-[2-(hydroxymethyl)phenyl]-dimethyl-(1-octenyl)-silane 
• 853955-58-5 dimethyl(2-(((tetrahydro-2H-pyran-2-yl)oxy)methyl)phenyl)silane 
• 853955-59-6 dimethyl-[2-(2-acetoxymethyl)phenyl]-silane 
• 38614-36-7 2-methylpropen-1-ylmagnesium bromide 
• 321903-29-1 1,1-dimethyl-1,3-dihydrobenzo[c][1,2]oxasilole 
• 17100-66-2 2-(tetrahydropyranyloxy)methylbromobenzene 

Downstream Products

• 1024757-07-0 N-(3-methyl-1-phenyl-2-buten-1-yl)-4-nitrobenzenesulfonamide 
• 1024757-11-6 N-[1-(4-methoxyphenyl)-3-methyl-2-buten-1-yl]-4-nitrobenzenesulfonamide 
• 1024757-09-2 N-[1-(4-chlorophenyl)-3-methyl-2-buten-1-yl]-4-nitrobenzenesulfonamide 
• 29843-69-4 3-(2-Methyl-1-propen-1-yl)cyclohexan-1-one 
• 77837-66-2 1-(4-carboethoxyphenyl)-2-methyl-1-propene 

Relevant articles and documents

Silicon-Based Cross-Coupling Reagent and Production Method of Organic Compound Using the Same

In one embodiment of the present invention, a silicon-based cross-coupling reagent is disclosed which is a highly stable tetraorganosilicon compound allowing for a cross-coupling reaction under mild reaction conditions without using fluoride ions, transition metal promoter, or strong bases, and the residue of the silicon reagent can be recovered and reused. The silicon-based cross-coupling reagent is a silicon compound in which an o-hydroxymethylphenyl group is connected to a silicon atom for intramolecular activation.

Alkenyl- and aryl[2-(hydroxymethyl)phenyl]dimethylsilanes: An entry to tetraorganosilicon reagents for the silicon-based cross-coupling reaction

Alkenyl- and aryl[2-(hydroxymethyl)phenyl]dimethylsilanes, highly stable tetraorganosilicon reagents, are found to react with aryl and alkenyl iodides in the presence of a palladium catalyst and K2CO3 as a base, significantly milder conditions compared with those ever reported for the silicon-based cross-coupling reactions. The reaction tolerates a wide range of functional groups, including silyl protectors, and allows a gram-scale synthesis to recover and reuse the silicon residue. Copyright