864443-52-7

Basic information

• Product Name: (+/-)-S-methyl-S-phenyl-N-[2-(trifluoromethoxy)benzenesulfonyl]sulfoximine
• Synonyms: (+/-)-S-methyl-S-phenyl-N-[2-(trifluoromethoxy)benzenesulfonyl]sulfoximine
• CAS NO: 864443-52-7
• Molecular Weight: 379.381
• Mol File: 864443-52-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (+/-)-S-methyl-S-phenyl-N-[2-(trifluoromethoxy)benzenesulfonyl]sulfoximine(CAS DataBase Reference)
• NIST Chemistry Reference: (+/-)-S-methyl-S-phenyl-N-[2-(trifluoromethoxy)benzenesulfonyl]sulfoximine(864443-52-7)
• EPA Substance Registry System: (+/-)-S-methyl-S-phenyl-N-[2-(trifluoromethoxy)benzenesulfonyl]sulfoximine(864443-52-7)

Safety Data

• Hazardous Substances Data: 864443-52-7(Hazardous Substances Data)

Upstream product

• 4381-25-3 S-methyl-S-phenylsulfoximine 
• 103008-51-1 2-(trifluoromethoxy)benzenesulfonyl chloride 

Downstream Products

• 864443-60-7 (+/-)-S-carboxymethyl-S-phenyl-N-[2-(trifluoromethoxy)benzenesulfonyl]sulfoximine 
• 864443-68-5 (+/-)-S-phenyl-S-(3-phenyl-2-propenyloxycarboxymethyl)-N-[2-(trifluoromethoxy)benzenesulfonyl]sulfoximine 

Relevant articles and documents

Asymmetric decarboxylative claisen rearrangement reactions of sulfoximine-substituted allylic tosylacetic esters

Allylic acetate esters containing a variety of N-arylsulfonyl sulfoximines on the acetyl residue have been prepared and submitted to the decarboxylative Claisen rearrangement reaction. Rearranged products were isolated in generally good yields, and diastereoselectivities up to 82:18 have been obtained. The N-(2,4,6-triisopropylphenylsulfonyl)-S-phenyl sulfoximine moiety gave the best selectivity. The stereochemistry of the major isomer was established by X-ray crystallography. A model to explain the stereochemical course of the rearrangement is proposed.