87117-61-1Relevant articles and documents
Synthesis of Monodisperse Perfluoroalkyl-Oxyethylene Surfactants with Methoxy Capping: Surfactants of High Chemical Inertness
Selve, Claude,Achilefu, Samuel
, p. 911 - 912 (2007/10/02)
Monodisperse fluoroalkyl non-ionic surfactants with a methoxy group capping the hydrophilic head, and having a high chemical inertness and surface properties typical of perfluorinated non-ionic surfactants, have been synthesized.
Neutral Ligands with Surfactant-Type Structure - Synthesis, Complexation, and Ion Transfer
Weber, Edwin
, p. 770 - 801 (2007/10/02)
New lipophilic neutral ligands which combine crown ether and podand characteristics with structural features of surfactants (cf. formulas 1-12, 16-26) were synthesized.Their complexation behaviour was studied, their solid-to-liquid and liquid-to-liquid phase transfer properties as well as their efficiency in ion transport across a liquid model membrane.Crystalline stoichiometric complexes of the cycles 2a-4a and of 3e with NaSCN, Ba(SCN)2, and BaI2 can be isolated.Among the noncyclic representatives a crystalline complex is obtained only from 11 with BaI2.The ligand 8d behaves in aqueous solution as a typical surfactant showing micelle formation and cloud point.
