87413-32-9

Basic information

• Product Name: (cyclohex-2-enylsulfonyl)benzene
• Synonyms: (cyclohex-2-enylsulfonyl)benzene
• CAS NO: 87413-32-9
• Molecular Weight: 222.308
• Mol File: 87413-32-9.mol
• Article Data: 18

Chemical Properties

• CAS DataBase Reference: (cyclohex-2-enylsulfonyl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: (cyclohex-2-enylsulfonyl)benzene(87413-32-9)
• EPA Substance Registry System: (cyclohex-2-enylsulfonyl)benzene(87413-32-9)

Safety Data

• Hazardous Substances Data: 87413-32-9(Hazardous Substances Data)

Upstream product

• 2562-37-0 1-nitrocyclohexene 
• 873-55-2 sodium benzenesulfonate 
• 25932-11-0 benzenesulfinic acid sodium dihydrate 
• 64-17-5 ethanol 
• 57981-18-7 N-cyclohex-2-enyl-4-methyl-benzenesulfonamide 
• 618-41-7 Benzenesulfinic acid 
• 822-67-3 Cyclohex-2-enol 
• 882-33-7 diphenyldisulfane 
• 4972-29-6 benzenesulphinyl chloride 
• 931-59-9 benzenesulfenyl chloride 
• 1521-51-3 rac-3-bromocyclohexene 
• 108-98-5 thiophenol 
• 76644-52-5 rac-3-acetoxycyclohexene 
• 58329-99-0 cyclohex-2-enyl methyl carbonate 

Downstream Products

• 1489-56-1 1-methyl-1,3-cyclohexadiene 
• 76345-95-4 1-n-butyl-1,3-cyclohexadiene 
• 6947-57-5 cyclohexyl phenyl sulfone 
• 1346696-92-1 (1-(pent-2-ynyl)cyclohex-2-enylsulfonyl)benzene 
• 1346696-94-3 (1-(3-phenylprop-2-ynyl)cyclohex-2-enylsulfonyl)benzene 
• 1346696-90-9 (1-(prop-2-ynyl)cyclohex-2-enylsulfonyl)benzene 
• 1050425-73-4 (2-cyclohexan-1,3-dienyl-ethoxymethyl)-benzene 
• 1050425-71-2 [2-(1-benzenesulfonyl-cyclohex-2-enyl)-ethoxymethyl]-benzene 
• 146606-25-9 1-<3-(phenylsulfonyl)cyclohexen-3-yl>-propan-2-yl tetrahydropyran-2-yl ether 
• 146606-21-5 1-(1,3-cyclohexadienyl)-propan-2-yl vinylsulfonate 
• 146606-27-1 1-(1,3-cyclohexadienyl)-propan-2-yl 
• 193824-95-2 tert-butyl(2-(cyclohexa-1,3-dien-1-yl)ethoxy)dimethylsilane 

Relevant articles and documents

Base-Mediated Radical Borylation of Alkyl Sulfones

A practical and direct method was developed for the production of versatile alkyl boronate esters via transition metal-free borylation of primary and secondary alkyl sulfones. The key to the success of the strategy is the use of bis(neopentyl glycolato) diboron (B2neop2), with a stoichiometric amount of base as a promoter. The practicality and industrial potential of this protocol are highlighted by its wide functional group tolerance, the late-stage modification of complex compounds, no need for further transesterification, and operational simplicity. Radical clock, radical trap experiments, and EPR studies were conducted which show that the borylation process involves radical intermediates.

An expeditious entry to benzylic and allylic sulfones through byproduct-catalyzed reaction of alcohols with sulfinyl chlorides

(Chemical Equation Presented) In the absence of external catalysts and additives, a broad range of benzylic and allylic alcohols react with various sulfinyl chlorides to afford structurally diversified benzylic and allylic sulfones in moderate to excellen

π-Allylic sulfonylation in water with amphiphilic resin-supported palladium-phosphine complexes

π-Allylic substitution of allyl esters with sodium arylsul-finate was performed with an amphiphilic polystyrene-poly(ethylene glycol) (PS-PEG) resin-supported phosphine-palladium complex in water as a single reaction medium under heterogeneous conditions to give allyl sulfones in good to high yields. Catalytic asymmetric allylic substitution of cycloalkenyl esters also took place in water using a PS-PEG resin-supported chiral imidazo-indolephosphine- palladium complex to give cycloalkenyl sulfones with up to 81% ee.