952594-53-5Relevant articles and documents
Cycloisomerization of γ- and δ-acetylenic acids catalyzed by gold(I) chloride
Marchal, Estelle,Uriac, Philippe,Legouin, Béatrice,Toupet, Lo?c,Weghe, Pierre van de
, p. 9979 - 9990 (2008/02/13)
We have developed a gold(I)-catalyzed intramolecular cyclization of γ- and δ-alkyne acids in mild conditions yielding various alkylidene lactones. Whereas a slight electronic effect of the R group was observed on the regioselectivity, bulky substituents o