982-45-6Relevant articles and documents
Iron-mediated cross dehydrogenative coupling (CDC) of terminal alkynes with benzylic ethers and alkanes
Xiang, Shi-Kai,Zhang, Bo,Zhang, Li-He,Cui, Yuxin,Jiao, Ning
experimental part, p. 50 - 54 (2012/03/12)
Iron-mediated sp-sp3 C-C bond formation through the cross dehydrogenative coupling (CDC) of terminal alkynes with benzylic ethers or alkanes has been developed. The inexpensive iron salt is used as the catalyst to make this transformation envir
Sp-sp3 C-C bond formation via Fe(OTf)3/TfOH cocatalyzed coupling reaction of terminal alkynes with benzylic alcohols
Xiang, Shi-Kai,Zhang, Li-He,Jiao, Ning
supporting information; experimental part, p. 6487 - 6489 (2010/03/04)
An Fe(OTf)3/TfOH cocatalyzed sp-sp3 C-C bond formation through the coupling of benzylic alcohols with terminal alkynes in the absence of base has been developed. H2O is the sole by-product.