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Cyproconazole

1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

Product name

Cyproconazole

2. HAZARDS IDENTIFICATION

Classification of the substance or mixture

According to Regulation (EC) No1272/2008

Reproductive toxicity (Category 2)

Acute toxicity, Oral (Category 4)

Acute aquatic toxicity (Category 1)

Chronic aquatic toxicity (Category 1)

According to European Directive 67/548/EEC as amended.

Possible risk of harm to the unborn child. Harmful if swallowed. Very toxic to aquatic organisms, may cause

long-term adverse effects in the aquatic environment.

Label elements

Pictogram

Signal word

Hazard statement(s)

H302

H410

H361d

Precautionary statement(s)

P273

P281

P501

Hazard symbol(s)

R-phrase(s)

R22

R50/53

R63

S-phrase(s)

S36/37

S60

S61

Warning

Harmful if swallowed.

Very toxic to aquatic life with long lasting effects.

Suspected of damaging the unborn child.

Avoid release to the environment.

Use personal protective equipment as required.

Dispose of contents/container to an approved waste disposal plant.

Harmful

Dangerous for the environment

Harmful if swallowed.

Very toxic to aquatic organisms, may cause long-term adverse effects in

the aquatic environment.

Possible risk of harm to the unborn child.

Wear suitable protective clothing and gloves.

This material and its container must be disposed of as hazardous waste.

Avoid release to the environment. Refer to special instructions/ Safety data

sheets.

Other hazards - none

3. COMPOSITION/INFORMATION ON INGREDIENTS

Formula

Molecular Weight

C15H18ClN3O

291,8 g/mol

CAS-No.

EC-No.

Classification

Concentration

Cyproconazole

94361-06-5

Repr. 2; Acute Tox. 4;

Aquatic Acute 1; Aquatic

Chronic 1; H302, H410,

H361d

Xn, N, Repr.Cat.3, R22 -

R50/53 - R63

For the full text of the H-Statements mentioned in this Section, see Section 16.

4. FIRST AID MEASURES

General advice

Consult a physician. Show this safety data sheet to the doctor in attendance.

If inhaled

If breathed in, move person into fresh air. If not breathing give artificial respiration Consult a physician.

In case of skin contact

Wash off with soap and plenty of water. Consult a physician.

In case of eye contact

Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.

If swallowed

Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

5. FIRE-FIGHTING MEASURES

Suitable extinguishing media

Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

Special protective equipment for fire-fighters

Wear self contained breathing apparatus for fire fighting if necessary.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions

Use personal protective equipment. Avoid dust formation. Avoid breathing dust. Ensure adequate ventilation.

Environmental precautions

Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the

environment must be avoided.

Methods and materials for containment and cleaning up

Pick up and arrange disposal without creating dust. Keep in suitable, closed containers for disposal.

7. HANDLING AND STORAGE

Precautions for safe handling

Avoid formation of dust and aerosols.

Provide appropriate exhaust ventilation at places where dust is formed. Normal measures for preventive fire

protection.

Conditions for safe storage

Store in cool place. Keep container tightly closed in a dry and well-ventilated place.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Personal protective equipment

Respiratory protection

Where risk assessment shows air-purifying respirators are appropriate use a full-face particle respirator

type N100 (US) or type P3 (EN 143) respirator cartridges as a backup to engineering controls. If the

respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and

components tested and approved under appropriate government standards such as NIOSH (US) or CEN

(EU).

Hand protection

The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the

standard EN 374 derived from it.

Handle with gloves.

Eye protection

Safety glasses with side-shields conforming to EN166

Skin and body protection

Choose body protection according to the amount and concentration of the dangerous substance at the

work place.

Hygiene measures

Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at

the end of workday.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance

Form

Colour

Safety data

Melting point

Boiling point

Flash point

Ignition temperature

Lower explosion limit

Upper explosion limit

Water solubility

Partition coefficient:

crystalline

beige

no data available

104 - 106 °C

no data available

> 100,00 °C

no data available

log Pow: 2,9

n-octanol/water

10. STABILITY AND REACTIVITY

Chemical stability

Stable under recommended storage conditions.

Conditions to avoid

no data available

Materials to avoid

Strong oxidizing agents

Hazardous decomposition products

Hazardous decomposition products formed under fire conditions. - Carbon oxides, nitrogen oxides (NOx),

Hydrogen chloride gas

11. TOXICOLOGICAL INFORMATION

Acute toxicity

LD50 Oral - rat - 1.020 mg/kg

LC50 Inhalation - rat - 4 h - > 5.650 mg/m3

LD50 Dermal - rat - > 2.000 mg/kg

Skin corrosion/irritation

Serious eye damage/eye irritation

Eyes - rabbit - Mild eye irritation

Respiratory or skin sensitization

no data available

Germ cell mutagenicity

no data available

Carcinogenicity

IARC: No component of this product present at levels greater than or equal to 0.1% is identified as

probable, possible or confirmed human carcinogen by IARC.

Reproductive toxicity

Suspected human reproductive toxicant

Reproductive toxicity - rabbit - Oral

Effects on Fertility: Post-implantation mortality (e.g., dead and/or resorbed implants per total number of

implants).

Reproductive toxicity - rat - Oral

Maternal Effects: Other effects. Effects on Embryo or Fetus: Fetal death. Specific Developmental

Abnormalities: Craniofacial (including nose and tongue).

Reproductive toxicity - rat - Oral

Effects on Fertility: Post-implantation mortality (e.g., dead and/or resorbed implants per total number of

implants). Effects on Fertility: Litter size (e.g.; # fetuses per litter; measured before birth). Effects on Embryo or

Fetus: Fetotoxicity (except death, e.g., stunted fetus).

Specific target organ toxicity - single exposure

no data available

Specific target organ toxicity - repeated exposure

no data available

Aspiration hazard

no data available

Potential health effects

Inhalation

Ingestion

Skin

Eyes

May be harmful if inhaled. May cause respiratory tract irritation.

Harmful if swallowed.

May be harmful if absorbed through skin. May cause skin irritation.

May cause eye irritation.

Additional Information

RTECS: XZ4803250

12. ECOLOGICAL INFORMATION

Toxicity

Toxicity to fish

Toxicity to daphnia

LC50 - Oncorhynchus mykiss (rainbow trout) - 19 mg/l - 96,0 h

EC50 - Daphnia magna (Water flea) - 26 mg/l - 48 h

and other aquatic

invertebrates.

Persistence and degradability

no data available

Bioaccumulative potential

no data available

Mobility in soil

no data available

PBT and vPvB assessment

no data available

Other adverse effects

Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

13. DISPOSAL CONSIDERATIONS

Product

Observe all federal, state, and local environmental regulations. Contact a licensed professional waste

disposal service to dispose of this material. Dissolve or mix the material with a combustible solvent and burn

in a chemical incinerator equipped with an afterburner and scrubber.

Contaminated packaging

Dispose of as unused product.

14. TRANSPORT INFORMATION

ADR/RID

UN-Number: 3077 Class: 9

Packing group: III

Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Cyproconazole)

IMDG

UN-Number: 3077 Class: 9

Packing group: III EMS-No: F-A, S-F

Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Cyproconazole)

Marine pollutant: No

IATA

UN-Number: 3077 Class: 9

Packing group: III

Proper shipping name: Environmentally hazardous substance, solid, n.o.s. (Cyproconazole)

15. REGULATORY INFORMATION

This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.

16. OTHER INFORMATION

Text of H-code(s) and R-phrase(s) mentioned in Section 3

Acute Tox.

Aquatic Acute

Aquatic Chronic

H302

H361d

H410

Repr.

R22

R50/53

R63

Repr.Cat.3

Acute toxicity

Acute aquatic toxicity

Chronic aquatic toxicity

Harmful if swallowed.

Suspected of damaging the unborn child.

Very toxic to aquatic life with long lasting effects.

Reproductive toxicity

Dangerous for the environment

Harmful

Harmful if swallowed.

Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic

environment.

Possible risk of harm to the unborn child.

Toxic to Reproduction Category 3

Further information

The above information is believed to be correct but does not purport to be all inclusive and
shall be used only as a guide. The information this document is based on the resent state
of our knowledge and is applicable to the product with regard to appropriate safety precautions.
It does not represent any guarantee of the properties of the product. Lookchem shall not be
held liable for any damage resulting from handling or from contact with the above product.
See reverse side of invoice or packing slip for additional terms and conditions of sale.

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