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Titanium chloride(TiCl2)

1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

Product name

Titanium(II) chloride

2. HAZARDS IDENTIFICATION

Classification of the substance or mixture

According to Regulation (EC) No1272/2008

Pyrophoric liquids (Category 1)

Skin corrosion (Category 1B)

Serious eye damage (Category 1)

According to European Directive 67/548/EEC as amended.

Reacts violently with water, liberating extremely flammable gases. Spontaneously flammable in air. Causes

burns.

Label elements

Pictogram

Signal word

Hazard statement(s)

H250

H314

EUH014

Precautionary statement(s)

P222

P231

P280

P305 + P351 + P338

P310

P422

Hazard symbol(s)

R-phrase(s)

R14/15

R17

R34

S-phrase(s)

S16

S24

S26

S36/37/39

S45

Danger

Catches fire spontaneously if exposed to air.

Causes severe skin burns and eye damage.

Reacts violently with water.

Do not allow contact with air.

Handle under inert gas.

Wear protective gloves/ protective clothing/ eye protection/ face protection.

IF IN EYES: Rinse cautiously with water for several minutes. Remove

contact lenses, if present and easy to do. Continue rinsing.

Immediately call a POISON CENTER or doctor/ physician.

Store contents under inert gas.

Highly flammable

Corrosive

Reacts violently with water, liberating extremely flammable gases.

Spontaneously flammable in air.

Causes burns.

Keep away from sources of ignition - No smoking.

Avoid contact with skin.

In case of contact with eyes, rinse immediately with plenty of water and

seek medical advice.

Wear suitable protective clothing, gloves and eye/face protection.

In case of accident or if you feel unwell, seek medical advice immediately

(show the label where possible).

Other hazards - none

3. COMPOSITION/INFORMATION ON INGREDIENTS

Formula

Molecular Weight

Cl2Ti

118,77 g/mol

CAS-No.

EC-No.

Classification

Concentration

Titanium dichloride

10049-06-6

233-164-9

Pyr. Liq. 1; Skin Corr. 1B; Eye

Dam. 1; H250, H314,

EUH014

F, C, R14/15 - R17 - R34

For the full text of the H-Statements mentioned in this Section, see Section 16.

4. FIRST AID MEASURES

General advice

Consult a physician. Show this safety data sheet to the doctor in attendance.

If inhaled

If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.

In case of skin contact

Take off contaminated clothing and shoes immediately. Wash off with soap and plenty of water. Consult a

physician.

In case of eye contact

Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.

If swallowed

Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water.

Consult a physician.

5. FIRE-FIGHTING MEASURES

Suitable extinguishing media

Carbon dioxide (CO2) Dry powder

Extinguishing media which shall not be used for safety reasons

Water

Special protective equipment for fire-fighters

Wear self contained breathing apparatus for fire fighting if necessary.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions

Use personal protective equipment. Avoid breathing vapors, mist or gas. Ensure adequate ventilation.

Evacuate personnel to safe areas.

Environmental precautions

Prevent further leakage or spillage if safe to do so. Do not let product enter drains.

Methods and materials for containment and cleaning up

Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet-brushing and place

in container for disposal according to local regulations (see section 13). Do not flush with water.

7. HANDLING AND STORAGE

Precautions for safe handling

Avoid inhalation of vapour or mist.

Keep away from sources of ignition - No smoking.

Conditions for safe storage

Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully

resealed and kept upright to prevent leakage. Store in cool place.

Never allow product to get in contact with water during storage.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Personal protective equipment

Respiratory protection

Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with

multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to

engineering controls. If the respirator is the sole means of protection, use a full-face supplied air

respirator. Use respirators and components tested and approved under appropriate government

standards such as NIOSH (US) or CEN (EU).

Hand protection

Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without

touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves

after use in accordance with applicable laws and good laboratory practices. Wash and dry hands.

Protective gloves against thermal risks

The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the

standard EN 374 derived from it.

Eye protection

Tightly fitting safety goggles. Faceshield (8-inch minimum). Use equipment for eye protection tested and

approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

Skin and body protection

Complete suit protecting against chemicals, Flame retardant antistatic protective clothing, The type of

protective equipment must be selected according to the concentration and amount of the dangerous

substance at the specific workplace.

Hygiene measures

Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at

the end of workday.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance

Form

Colour

Safety data

Melting point

Boiling point

Flash point

Ignition temperature

Lower explosion limit

Upper explosion limit

Water solubility

powder

black

no data available

not applicable

no data available

10. STABILITY AND REACTIVITY

Chemical stability

Stable under recommended storage conditions.

Possibility of hazardous reactions

Reacts violently with water.

Conditions to avoid

Exposure to moisture.

Materials to avoid

Strong oxidizing agentsWater, Strong oxidizing agents

Hazardous decomposition products

Hazardous decomposition products formed under fire conditions. - Hydrogen chloride gas, Titanium/titanium

oxides

11. TOXICOLOGICAL INFORMATION

Acute toxicity

no data available

Skin corrosion/irritation

no data available

Serious eye damage/eye irritation

no data available

Respiratory or skin sensitization

no data available

Germ cell mutagenicity

no data available

Carcinogenicity

IARC: No component of this product present at levels greater than or equal to 0.1% is identified as

probable, possible or confirmed human carcinogen by IARC.

Reproductive toxicity

no data available

Specific target organ toxicity - single exposure

no data available

Specific target organ toxicity - repeated exposure

no data available

Aspiration hazard

no data available

Potential health effects

Inhalation

Ingestion

Skin

Eyes

May be harmful if inhaled. Material is extremely destructive to the tissue of the

mucous membranes and upper respiratory tract.

May be harmful if swallowed. Causes burns.

May be harmful if absorbed through skin. Causes skin burns.

Causes eye burns.

Signs and Symptoms of Exposure

Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and

skin., spasm, inflammation and edema of the larynx, spasm, inflammation and edema of the bronchi,

pneumonitis, pulmonary edema, burning sensation, Cough, wheezing, laryngitis, Shortness of breath,

Headache, Nausea

Additional Information

RTECS: Not available

12. ECOLOGICAL INFORMATION

Toxicity

no data available

Persistence and degradability

no data available

Bioaccumulative potential

no data available

Mobility in soil

no data available

PBT and vPvB assessment

no data available

Other adverse effects

no data available

13. DISPOSAL CONSIDERATIONS

Product

Burn in a chemical incinerator equipped with an afterburner and scrubber but exert extra care in igniting as

this material is highly flammable. Offer surplus and non-recyclable solutions to a licensed disposal company.

Contact a licensed professional waste disposal service to dispose of this material.

Contaminated packaging

Dispose of as unused product.

14. TRANSPORT INFORMATION

ADR/RID

UN-Number: 3200 Class: 4.2

Packing group: I

Proper shipping name: PYROPHORIC SOLID, INORGANIC, N.O.S. (Titanium dichloride)

IMDG

UN-Number: 3200 Class: 4.2

Packing group: I EMS-No: F-G, S-M

Proper shipping name: PYROPHORIC SOLID, INORGANIC, N.O.S. (Titanium dichloride)

Marine pollutant: No

IATA

UN-Number: 3200 Class: 4.2

Proper shipping name: Pyrophoric solid, inorganic, n.o.s. (Titanium dichloride)

IATA Passenger: Not permitted for transport

IATA Cargo: Not permitted for transport

15. REGULATORY INFORMATION

This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.

16. OTHER INFORMATION

Text of H-code(s) and R-phrase(s) mentioned in Section 3

EUH014

Eye Dam.

H250

H314

Pyr. Liq.

Skin Corr.

R14/15

R17

R34

Reacts violently with water.

Serious eye damage

Catches fire spontaneously if exposed to air.

Causes severe skin burns and eye damage.

Pyrophoric liquids

Skin corrosion

Corrosive

Highly flammable

Reacts violently with water, liberating extremely flammable gases.

Spontaneously flammable in air.

Causes burns.

Further information

The above information is believed to be correct but does not purport to be all inclusive and
shall be used only as a guide. The information this document is based on the resent state
of our knowledge and is applicable to the product with regard to appropriate safety precautions.
It does not represent any guarantee of the properties of the product. Lookchem shall not be
held liable for any damage resulting from handling or from contact with the above product.
See reverse side of invoice or packing slip for additional terms and conditions of sale.

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