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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch

Rhodium trichloride Manufacturer/High quality/Best price/In stock

Cas:10049-07-7

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

High efficiency 99% Rhodium Trichloride 10049-07-7 Manufacturer

Cas:10049-07-7

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

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Leader Biochemical Group

About Product Technical Details Rhodium(III) Chloride Chemical Properties Melting point 450 °C Boiling point 717 °C (730

China Largest factory Manufacturer Supply Rhodium(III) Chloride CAS 10049-07-7

Cas:10049-07-7

Min.Order:1 Kilogram

FOB Price: $1.0 / 3.0

Type:Lab/Research institutions

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Wholesale price CAS 10049-07-7 with best price

Cas:10049-07-7

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Hubei Langyou International Trading Co., Ltd

1. Guaranteed purity; 2. Large quantity in stock; 3. Largest manufacturer; 4. Best service after shipment with email; 5. High quality & competitive price; Appearance:White Crystalline Powder Storage:Store in sealed conta

high quality 10049-07-7 Rhodium trichloride with best price

Cas:10049-07-7

Min.Order:10 Gram

Negotiable

Type:Other

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Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Rhodium chloride(RhCl3)

Cas:10049-07-7

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Guangdong Juda Chemical Industrial Co.,Limited

We provide tailor-made photoinitiator solutions for different performances by custom synthesisi.blends or other technical supports low-odor uv formulations non-yellowing uv formulations benzene-free uv formulations polymeric uv formul

Rhodium trichlorideCAS:10049-07-7

Cas:10049-07-7

Min.Order:100 Kilogram

Negotiable

Type:Trading Company

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Hebei Nengqian Chemical Import and Export Co., LTD

Our Advantage Rich Experience Our products are sold all over Europe,North&South America, Sino-East, Asia and pacific area as well as Africa,we establish long term. Quality service Company cooperates with research institutes. We strictly con

Rhodium trichloride CAS:10049-07-7

Cas:10049-07-7

Min.Order:1 Kilogram

FOB Price: $1.0 / 10.0

Type:Trading Company

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Rhodium chloride(RhCl3)

Cas:10049-07-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

High purity Rhodium Chloride 10049-07-7

Cas:10049-07-7

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Rhodium chloride(RhCl3)

Cas:10049-07-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providing h

Factory Supply rhodium trichloride

Cas:10049-07-7

Min.Order:0

Negotiable

Type:Other

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SHANGHAI SYSTEAM BIOCHEM CO., LTD

We are one of a few suppliers that can offer custom synthesis service of this product We are specialized in custom synthesis, chemical/pharmaceutical/ pesticides outsourcing and contract research. We are committed to prov

High purity Rhodium Chloride 10049-07-7

Cas:10049-07-7

Min.Order:100 Gram

FOB Price: $100.0 / 2000.0

Type:Lab/Research institutions

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Shanghai Minstar Chemical Co., Ltd

Product Name: Rhodium trichloride CAS: 10049-07-7 MF: Cl3Rh MW: 209.26 EINECS: 233-165-4 Mol File: 10049-07-7.mol Rhodium trichloride Structure Rhodium trichloride Chemical Properties Melting point 450 °C Boiling point

Rhodium trichloride

Cas:10049-07-7

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

High purity Rhodium Chloride 10049-07-7

Cas:10049-07-7

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

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Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

High purity Rhodium Chloride 10049-07-7

Cas:10049-07-7

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

High purity Rhodium Chloride 10049-07-7

Cas:10049-07-7

Min.Order:1 Metric Ton

FOB Price: $1.5

Type:Trading Company

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Bluecrystal chem-union

We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp

High purity Rhodium Chloride 10049-07-7

Cas:10049-07-7

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Trading Company

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Hebei Mojin Biotechnology Co.,Ltd

1, High quality with competitive price:2, Fast and safe delivery3.Excellent pre-sales and after-sales service4. Well-trained and professional technologist and sales with rich experience in the field for 5-10 yearsAppearance:see detailed specification

Rhodium chloride(RhCl3)

Cas:10049-07-7

Min.Order:0

Negotiable

Type:Trading Company

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Hunan chemfish Pharmaceutical co.,Ltd

Hunan chemfish Pharmaceutical co.,Ltd.located in Lugu High-tech industral park ,Hunan province . with its own R&D center and more than 10000㎡manufacture plant . Chemfish owns 40 reactors from 1000L to 8000L. With complete auxiliary equipment as:

Rhodium trichloride

Cas:10049-07-7

Min.Order:1 Gram

Negotiable

Type:Manufacturers

inquiry

GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

Rhodium trichloride

Cas:10049-07-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

rhodium trichloride

Cas:10049-07-7

Min.Order:0

Negotiable

Type:Other

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Enke Pharma-tech Co.,Ltd. (Cangzhou, China )

Cangzhou Enke Pharma Tech Co.,ltd. is located in Cangzhou City, Hebei province ,where is a famous petroleum chemical industry city in China. Enke Pharma a high-tech enterprise ,and we are dedicated to developing and manufacturing new api, intermediat

Rhodium trichloride

Cas:10049-07-7

Min.Order:1 Kilogram

FOB Price: $777.0 / 888.0

Type:Lab/Research institutions

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Shanghai Acmec Biochemical Technology Co., Ltd.

Acmec is a leading manufacturer and supplier of biochemical reagents and life science products. We have over 40,000 items in stock (real-time inventory) and offer discounted prices to registered members of the online store ( www.acmec.com.cn ) Appea

Acmec Rhodium chloride 1g

Cas:10049-07-7

Min.Order:1 bottle

Negotiable

Type:Lab/Research institutions

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Xi`an Eastling Biotech Co., Ltd.

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:Foil bag; Drum; Plastic bottle Application:Pharma;Industry;Agricultural Transportation:by sea or air Port:Beijing or Guangzhou

Rhodium trichloride

Cas:10049-07-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Xian Changyue Biological Technology Co., Ltd.

best seller Application:API

Rhodium trichloride

Cas:10049-07-7

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Henan Tianfu Chemical Co., Ltd.

Good quantity Storage:R.T. Package:as per buyers Application:Reagent Transportation:by air/sea

Rhodium(III) chloride, anhydrous

Cas:10049-07-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

RhodiuM(III) chloride

Cas:10049-07-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Hangzhou Ocean Chemical Co., Ltd.

Ocean inorganic department is a professional supplier and exporter engaging in inorganic chemical materials and metal organic compounds. Over the past years, our company is committed to improving the product quality and developing new products, in or

Rhodium Chloride anhydrous

Cas:10049-07-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Qingdao Beluga Import and Export Co., LTD

We are a trading company aiming at providing high-quality services to customers. Established for many years, with good reputation in the industry Storage:Sealed and preserved Application:Fine chemical intermediates, used as the main raw material for

High purity Rhodium Chloride 10049-07-7

Cas:10049-07-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Synthetic route

chlorine
7782-50-5

chlorine

rhodium(III)chloride
10049-07-7

rhodium(III)chloride

Conditions
ConditionsYield
In neat (no solvent) finely divided metallic Rh is heated in dry Cl2 at to 540 °C ;;100%
In neat (no solvent) Kinetics; exposing Rh to flowing Cl2 (0.05-0.80 atm) at 300-1150°C;
In neat (no solvent) rhodium black is heated at 800 °C in dry Cl2 and cooled slowly inflowing Cl2;;
rhodium(III) chloride trihydrate

rhodium(III) chloride trihydrate

rhodium(III)chloride
10049-07-7

rhodium(III)chloride

Conditions
ConditionsYield
In solid in air or in Ar atmosphere; TG and DTA monitoring, X-ray diffraction anal.;
phosphorus trichloride
7719-12-2, 52843-90-0

phosphorus trichloride

rhodium(III)chloride
10049-07-7

rhodium(III)chloride

Conditions
ConditionsYield
In neat (no solvent) heating;;
In not given heating;
In neat (no solvent) heating;;
phosphorus pentachloride
10026-13-8, 874483-75-7

phosphorus pentachloride

rhodium(III)chloride
10049-07-7

rhodium(III)chloride

Conditions
ConditionsYield
In neat (no solvent) heating with Rh;;
In not given heating;
di(rhodium)tetracarbonyl dichloride

di(rhodium)tetracarbonyl dichloride

rhodium(III)chloride
10049-07-7

rhodium(III)chloride

Conditions
ConditionsYield
With hydrogenchloride; dihydrogen peroxide In propan-1-ol Kinetics; byproducts: CO, CO2, H2O; oxidation of {Rh(CO)2Cl}2 with H2O2 in propanol contg. HCl is investigated, intermediate discussed; reaction monitored by UV/VIS spectroscopy;
With hydrogenchloride; dihydrogen peroxide In methanol Kinetics; byproducts: CO, CO2, H2O; oxidation of {Rh(CO)2Cl}2 with H2O2 in methanol contg. HCl is investigated, intermediate discussed; reaction monitored by UV/VIS spectroscopy;
With hydrogenchloride; dihydrogen peroxide In ethanol Kinetics; byproducts: CO, CO2, H2O; oxidation of {Rh(CO)2Cl}2 with H2O2 in ethanol contg. HCl is investigated, intermediate discussed; reaction monitored by UV/VIS spectroscopy;
chlorine
7782-50-5

chlorine

sodium chloride
7647-14-5

sodium chloride

rhodium(III)chloride
10049-07-7

rhodium(III)chloride

Conditions
ConditionsYield
In neat (no solvent) mixt. of Rh and NaCl in Cl2 stream (red heat);;
chlorine
7782-50-5

chlorine

A

Rh2Cl5

Rh2Cl5

B

rhodium(III)chloride
10049-07-7

rhodium(III)chloride

Conditions
ConditionsYield
In neat (no solvent) heating finely divided Rh in a Cl2-stream;;
tripotassium hexachlororhodate(III) monohydrate

tripotassium hexachlororhodate(III) monohydrate

A

potassium chloride

potassium chloride

B

rhodium(III)chloride
10049-07-7

rhodium(III)chloride

Conditions
ConditionsYield
With hydrogenchloride In neat (no solvent) Kinetics; heating in dry HCl-stream; loss of water proceeds slowly at 360 °C, rapidly at 440 °C to form insol. RhCl3;; KCl is leached by water;;
tripotassium hexachlororhodate(III) monohydrate

tripotassium hexachlororhodate(III) monohydrate

rhodium(III)chloride
10049-07-7

rhodium(III)chloride

Conditions
ConditionsYield
With chlorine In neat (no solvent) Kinetics; dried K3(RhCl6)*H2O (105-110 °C); heating to 440 °C in a dry Cl2-stream;; washing with water;;
rhodium(VI) oxide hydrate

rhodium(VI) oxide hydrate

rhodium(III)chloride
10049-07-7

rhodium(III)chloride

Conditions
ConditionsYield
In hydrogenchloride byproducts: Cl2;
In hydrogenchloride byproducts: Cl2;
RhSn3

RhSn3

chlorine
7782-50-5

chlorine

rhodium(III)chloride
10049-07-7

rhodium(III)chloride

Conditions
ConditionsYield
In neat (no solvent) heating RhSn3 to 440 °C in a rapid stream of dry Cl2; air and moisture must be excluded;; Sn contents corresponding to RhSn(<3) causes formation of mixtures of RhCl3 and Rh;;
rhodium trichloride hydrate

rhodium trichloride hydrate

rhodium(III)chloride
10049-07-7

rhodium(III)chloride

Conditions
ConditionsYield
With air In neat (no solvent) heating RhCl3.aq in air;;
heating nerly until the glowing heat;;
heating nerly until the glowing heat;;
rhodium trichloride hydrate

rhodium trichloride hydrate

A

hydrogenchloride
7647-01-0

hydrogenchloride

B

rhodium(III) oxide

rhodium(III) oxide

C

rhodium(III)chloride
10049-07-7

rhodium(III)chloride

Conditions
ConditionsYield
With air In neat (no solvent) heating; decomposition;;A n/a
B n/a
C 0%
rhodium trichloride hydrate

rhodium trichloride hydrate

chlorine
7782-50-5

chlorine

rhodium(III)chloride
10049-07-7

rhodium(III)chloride

Conditions
ConditionsYield
In neat (no solvent) heating to 175-180 °C in a stream of dry HCl-gas, then to 440 °C in a Cl2-stream, cooling in CO2-stream;;
hydrogenchloride
7647-01-0

hydrogenchloride

rhodium(III) oxide

rhodium(III) oxide

rhodium(III)chloride
10049-07-7

rhodium(III)chloride

Conditions
ConditionsYield
In hydrogenchloride prepn. by dissolving Rh2O3 in the least amt. of hot concd. HCl;
hydrogenchloride
7647-01-0

hydrogenchloride

tetra[μ-acetato-bis(methanol)]dirhodium

tetra[μ-acetato-bis(methanol)]dirhodium

A

rhodium(III)chloride
10049-07-7

rhodium(III)chloride

sodium hexachlororhodate(III)

sodium hexachlororhodate(III)

rhodium(III)chloride
10049-07-7

rhodium(III)chloride

Conditions
ConditionsYield
With alkali In hydrogenchloride addn. of alkali to Na3(RhCl6)-soln. and dissolving ppt. in HCl;;
sodium hexachlororhodate(III) dodecahydrate

sodium hexachlororhodate(III) dodecahydrate

A

rhodium(III)chloride
10049-07-7

rhodium(III)chloride

B

sodium chloride
7647-14-5

sodium chloride

Conditions
ConditionsYield
With hydrogenchloride In neat (no solvent) Kinetics; heating slowly in a stream of dry HCl; dehydration proceeds slowly at 350 °C, rapidly at 440 °C to form insol. RhCl3; by-product NaCl is leached by water;;
sodium hexachlororhodate(III) dodecahydrate

sodium hexachlororhodate(III) dodecahydrate

rhodium(III)chloride
10049-07-7

rhodium(III)chloride

Conditions
ConditionsYield
With hydrogenchloride; sulfuric acid In not given reacting with concd. H2SO4 leads to rhodium(III) oxide chlorides that were treated with gaseous HCl to yield RhCl3*2/3H2O; heating to 360 °C with HCl gas;;
With chlorine In neat (no solvent) Kinetics; Na3(RhCl6)*12H2O is dried at 105-110 °C and then heated to 440 °C in a stream of dry Cl2;; washing with water;;
With HCl; H2SO4 In not given reacting with concd. H2SO4 leads to rhodium(III) oxide chlorides that were treated with gaseous HCl to yield RhCl3*2/3H2O; heating to 360 °C with HCl gas;;
chloropentaamminerhodium(III) chloride

chloropentaamminerhodium(III) chloride

rhodium(III)chloride
10049-07-7

rhodium(III)chloride

Conditions
ConditionsYield
With chlorine calcination in dry Cl2;;
With chlorine In neat (no solvent) calcination in a dry Cl2-stream;;
With Cl2
tris(ammonium) hexachlororhodate(III)

tris(ammonium) hexachlororhodate(III)

rhodium(III)chloride
10049-07-7

rhodium(III)chloride

Conditions
ConditionsYield
With chlorine In neat (no solvent) heating to 440 °C in a stream of dry Cl2;; product does not contain impurities;;
With nitrogen In neat (no solvent) calcination in a dry N2-stream;; product does not contain impurities;;
Rh(amodiaquine-4-(7-chloro-4-quinolyl)amino-2-diethylaminomethylphenol)Cl3

Rh(amodiaquine-4-(7-chloro-4-quinolyl)amino-2-diethylaminomethylphenol)Cl3

rhodium(III)chloride
10049-07-7

rhodium(III)chloride

Conditions
ConditionsYield
In neat (no solvent) static air atmosphere, 260°C; thermogravimetry;
ammonium chlororhodate(III) * 1(1 1/2) H20

ammonium chlororhodate(III) * 1(1 1/2) H20

A

chloropentaamminerhodium(III) chloride

chloropentaamminerhodium(III) chloride

B

rhodium(III)chloride
10049-07-7

rhodium(III)chloride

Conditions
ConditionsYield
In neat (no solvent) 440°C;;
In neat (no solvent) 440°C;;
rhodium(IV) oxide dihydrate

rhodium(IV) oxide dihydrate

rhodium(III)chloride
10049-07-7

rhodium(III)chloride

Conditions
ConditionsYield
In hydrogenchloride byproducts: Cl2;
ammonium chloride

ammonium chloride

rhodium(III)chloride
10049-07-7

rhodium(III)chloride

sodium nitrite
7632-00-0

sodium nitrite

rhodium(III) ammonium sodium hexanitrite

rhodium(III) ammonium sodium hexanitrite

Conditions
ConditionsYield
With sodium carbonate In hydrogenchloride aq. HCl soln. of RhCl3 partly neutralized by sodium carbonate; to soln. added soln. of NaNO2 and mixt. heated on water bath for 1 h; NH4Cl addedto soln.; ppt. sepd., washed with NH4Cl and min. amt. cold water; dried in air; detn. by XRD;99%
rhodium(III)chloride
10049-07-7

rhodium(III)chloride

tricyclohexylphosphine
2622-14-2

tricyclohexylphosphine

HRhCl2(tricyclohexylphosphine)2
70897-33-5, 63736-69-6

HRhCl2(tricyclohexylphosphine)2

Conditions
ConditionsYield
In water; isopropyl alcohol bubbled N2 through a stirred soln. of RhCl3; added tricyclohexylphosphine; refluxed for 18 h under stirring; filtered; washed with ethanol; dried in vacuo;99%
3-(2-thiazolylazo)-2,6-diaminopyridine
22409-45-6

3-(2-thiazolylazo)-2,6-diaminopyridine

rhodium(III)chloride
10049-07-7

rhodium(III)chloride

[Rh(3-(2-thiazolylazo)-2,6-diaminopyridine(+2H))](5+)

[Rh(3-(2-thiazolylazo)-2,6-diaminopyridine(+2H))](5+)

Conditions
ConditionsYield
With sodium sulfate In water Kinetics; placing of soln. of 3-(2-thiazolylazo)-2,6-diaminopyridine) and RhCl3 ationic strength I = 1.50 (0.497 M Na2SO4) into tube; addn. of water, pla cing of tube on boiling water bath, heating for 50-60 min, cooling in a wessel with water (10°C); monitoring by UV;99%
(C2H5OOC(CH2)3OC6H4)4C20H10N4

(C2H5OOC(CH2)3OC6H4)4C20H10N4

rhodium(III)chloride
10049-07-7

rhodium(III)chloride

(C2H5OOC(CH2)3OC6H4)4C20H8N4RhCl
1351286-94-6

(C2H5OOC(CH2)3OC6H4)4C20H8N4RhCl

Conditions
ConditionsYield
In benzonitrile (N2), porphyrin refluxed in benzonitrile for 5 min, treated with 2 equiv. of RhCl3, refluxed for 3 h; cooled, dried (vac.) with heating,treated with CH2Cl2, washed (aq.NaCl),org. layer dried (Na2SO4), filtered, concd., chromy.(silica gel - CH2Cl 2/EtOH 100:1), elem. anal.;98%
rhodium(III)chloride
10049-07-7

rhodium(III)chloride

potassium iodide
7681-11-0

potassium iodide

triethylenediaminerhodiumiodide*ethylenediamine*methanol

triethylenediaminerhodiumiodide*ethylenediamine*methanol

Conditions
ConditionsYield
With ethylenediamine In methanol; water RhCl3 and KI are warmed in mixt. of ethylendiamine and water, after cooling methanol is added; washing (methanol), drying (vac.); elem. anal.;96%
chromonethiobarbituric acid
263146-62-9

chromonethiobarbituric acid

water
7732-18-5

water

rhodium(III)chloride
10049-07-7

rhodium(III)chloride

[Rh(C15H9N2O6S)(H2O)4](2+)*2Cl(1-)*5H2O=[Rh(C15H9N2O6S)(H2O)4]Cl2*5H2O

[Rh(C15H9N2O6S)(H2O)4](2+)*2Cl(1-)*5H2O=[Rh(C15H9N2O6S)(H2O)4]Cl2*5H2O

Conditions
ConditionsYield
With ammonium hydroxide In 1,4-dioxane; water byproducts: HCl; the complex was prepd. by mixing a hot aq. soln. of the metal chloride (4 mmol) with hot dioxane soln. of the ligand (4 mmol); the react. mixt. was then refluxed; aq. ammonia soln. (1:10) was slowly added with stirring (pH 5.0-5.5); the ppt. was filtered, washed with hot dioxane and diethyl ether and dried over anhyd. CaCl2; elem. anal.;92%
glyoxalbis(N-phenyl)osazone
1534-21-0, 29841-71-2

glyoxalbis(N-phenyl)osazone

rhodium(III)chloride
10049-07-7

rhodium(III)chloride

triphenylphosphine
603-35-0

triphenylphosphine

trans-Rh(glyoxalbis(N-phenyl)osazone)(PPh3)Cl2
1264746-52-2

trans-Rh(glyoxalbis(N-phenyl)osazone)(PPh3)Cl2

Conditions
ConditionsYield
In ethanol (Ar); to soln. of osazone in EtOH, RhCl3 and PPh3 were added, refluxed for 40 min; solid was separated, soln. was cooled at 20°C, filtered, residue was dried in air and collected, elem. anal.;92%
pyridine
110-86-1

pyridine

hydrogenchloride
7647-01-0

hydrogenchloride

rhodium(III)chloride
10049-07-7

rhodium(III)chloride

{Rhpy4Cl2}Cl*6H2O

{Rhpy4Cl2}Cl*6H2O

Conditions
ConditionsYield
In water pyridine was added to aq. soln. of RhCl3 and heated (water bath) for two hours;; cooling; pptn.; addn. of concd. HCl soln. yields further pptn.; washing (first: concd. HCl soln./H2O / second: H2O); recrystn. (little boiling water); drying (100 °C);;90%
In water byproducts: {Rh py3 Cl3}; pyridine was added to aq. soln. of RhCl3 and heated (water bath) for two hours; pptn. of (Rhpy3Cl3) when heating;; cooling; pptn.; addn. of concd. HCl soln. yields further pptn.; washing (first: concd. HCl soln./H2O / second: H2O); recrystn. (little boiling water); drying (100 °C);;90%
In water byproducts: {Rh py3 Cl3}; pyridine was added to aq. soln. of RhCl3 and heated (water bath) for two hours; pptn. of (Rhpy3Cl3) when heating;; cooling; pptn.; addn. of concd. HCl soln. yields further pptn.; washing (first: concd. HCl soln./H2O / second: H2O); recrystn. (little boiling water); drying (100 °C);;90%
2,3,5,6-tetrakis(2-pyridyl)pyrazine
25005-97-4

2,3,5,6-tetrakis(2-pyridyl)pyrazine

rhodium(III)chloride
10049-07-7

rhodium(III)chloride

(RhCl3)2(2,3,5,6-tetrakis(2-pyridyl)pyrazine)*0.5CH3OH

(RhCl3)2(2,3,5,6-tetrakis(2-pyridyl)pyrazine)*0.5CH3OH

Conditions
ConditionsYield
With methanol In methanol mixing of RhCl3 and tppz (2:1 mole ratio) in methanol, refluxing in an open-top condenser, pptn. (after 1 h), further refluxing (24 h), cooling to room temp.; filtration, washing (boiling anhyd. methanol or ethanol), drying (vac.); elem. anal.;89%
ethene
74-85-1

ethene

rhodium(III)chloride
10049-07-7

rhodium(III)chloride

bis(ethylene)rhodium(I) chloride dimer

bis(ethylene)rhodium(I) chloride dimer

Conditions
ConditionsYield
In not given bubbling of ethylene through RhCl3 soln. for 22 h;86%
pyridine-4-carboxylic acid
55-22-1

pyridine-4-carboxylic acid

rhodium(III)chloride
10049-07-7

rhodium(III)chloride

trans-[Rh(isonicotinic acid)3(isonicotonic acid(-H))Cl2]
1268626-58-9

trans-[Rh(isonicotinic acid)3(isonicotonic acid(-H))Cl2]

Conditions
ConditionsYield
With NaOH In hydrogenchloride; ethanol EtOH soln. of ligand added to aq. HCl soln. of RhCl3, mixt. refluxed with vigorous stirirng; cooled, pH 4.5 (NaOH), ppt. filtered off, washed (hot water, acetone), dried in air, elem. anal.;85%
hydrogenchloride
7647-01-0

hydrogenchloride

3-Methylpyridine
108-99-6

3-Methylpyridine

hydrazine hydrochloride
2644-70-4

hydrazine hydrochloride

water
7732-18-5

water

rhodium(III)chloride
10049-07-7

rhodium(III)chloride

trans-dichlorotetrakis(β-picoline)rhodium(III) chloride dihydrate

trans-dichlorotetrakis(β-picoline)rhodium(III) chloride dihydrate

Conditions
ConditionsYield
In hydrogenchloride small amt. of hydrazine hydrochloride added to soln. of Rh salt in 0.5 MHCl, heated on water bath, β-picoline added to hot soln. under sti rring, cooled, mixed with equal vol. of concd. HCl; ppt. filtered off, washed with ice water, dried in air; elem. anal.;85%
rhodium(III)chloride
10049-07-7

rhodium(III)chloride

tris(1-methylethyl)phosphine
6476-36-4

tris(1-methylethyl)phosphine

(((CH3)2CH)3P)2Rh(H)Cl2
36656-55-0, 139163-38-5, 139238-78-1

(((CH3)2CH)3P)2Rh(H)Cl2

Conditions
ConditionsYield
In water; isopropyl alcohol bubbled N2 through a stirred soln. of RhCl3 for 1 h; added triisopropylphosphine; refluxed for 33 h under stirring; filtered; washed with acetone; dried in vacuo;82%
ethyleneimine
151-56-4

ethyleneimine

rhodium(III)chloride
10049-07-7

rhodium(III)chloride

3(ClCH2CH2NH3)(1+)*{RhCl6}(3-)=(ClCH2CH2NH3)3{RhCl6}

3(ClCH2CH2NH3)(1+)*{RhCl6}(3-)=(ClCH2CH2NH3)3{RhCl6}

Conditions
ConditionsYield
With hydrogenchloride In hydrogenchloride aziridine dissolved in conc. HCl (cooling), addn. of saturated RhCl3 soln. in conc. HCl (molar ratio aziridine:RhCl3 3:1); solvent evapd. on a water bath, crystn., cooled, filtered, residue washed with acetone and ether, dried in vac. (P2O5); elem. anal.;80%
2,3,5,6-tetrakis(2-pyridyl)pyrazine
25005-97-4

2,3,5,6-tetrakis(2-pyridyl)pyrazine

rhodium(III)chloride
10049-07-7

rhodium(III)chloride

(RhCl3)(2,3,5,6-tetrakis(2-pyridyl)pyrazine)
125859-05-4

(RhCl3)(2,3,5,6-tetrakis(2-pyridyl)pyrazine)

Conditions
ConditionsYield
In ethanol mixing of RhCl3 and tppz (1:2 mole ratio) in ethanol, refluxing in an open-top condenser, pptn. (after 1 h), further refluxing (24 h), cooling to room temp.; filtration, washing (boiling anhyd. methanol or ethanol), drying (vac.); elem. anal.;80%
ammonium tetrafluroborate
13826-83-0

ammonium tetrafluroborate

rhodium(III)chloride
10049-07-7

rhodium(III)chloride

5-oxa-2,8-dithia[9](2,9)-1,10-phenanthrolinophane
350014-32-3

5-oxa-2,8-dithia[9](2,9)-1,10-phenanthrolinophane

[Rh(5-oxa-2,8-dithia[9](2,9)-1,10-phenanthrolinophane)Cl2]BF4
350014-40-3

[Rh(5-oxa-2,8-dithia[9](2,9)-1,10-phenanthrolinophane)Cl2]BF4

Conditions
ConditionsYield
In water; acetonitrile mixt. of ligand and RhCl3 in MeCN/H2O refluxed under N2 for 5 h, a largeexcess of NH4BF4 added; pptd. by concn. (vac.), recrystd. by slow diffusion of Et2O vapor into an MeCN soln.;80%

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