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Hebei yanxi chemical co.,LTD.

Hebei yanxi chemical co. LTD. has expanded a compositive entity from initially only as a small manufacturer. The company dedicated to the development, production and marketing of chemicals. After many years of efforts, we have established stable

Ethylene

Cas:74-85-1

Min.Order:1 Metric Ton

FOB Price: $1.0 / 2.0

Type:Manufacturers

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Ethylene

Cas:74-85-1

Min.Order:1

Negotiable

Type:Other

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea Port:shanghai

ETHYLENE

Cas:74-85-1

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

Ethylene

Cas:74-85-1

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Changchun Artel lmport and Export trade company

Superiority We can customize and synthesize products that other suppliers may not be able to provide. Advantage cof, mof ligand manufacturer Product Detail

high purity 99.99% Ethylene CAS:74-85-1, C2H4

Cas:74-85-1

Min.Order:100 Kilogram

Negotiable

Type:Trading Company

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

Ethene

Cas:74-85-1

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

Ethylene

Cas:74-85-1

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality, moderate price & quick delivery. Appearance:Colourless gas Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:1kg/bag, 1kg/drum or 25kg/drum or as per your request. Application:A catalyst for pl

Ethylene

Cas:74-85-1

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Henan Tianfu Chemical Co., Ltd.

ETHYLENE Chemical Properties Melting point −169 °C(lit.) Boiling point −104 °C(lit.) density 0.00126 vapor density 0.97 (vs air) vapor pressure 35.04 atm ( 20 °C) refractive in

74-85-1 ETHYLENE

Cas:74-85-1

Min.Order:1 Metric Ton

FOB Price: $20.0

Type:Lab/Research institutions

inquiry

Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

Ethylene Manufacturer

Cas:74-85-1

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Dingyan Chem Co., Ltd

R & D enterprises have their own stock in stock Package:1kg Application:pharmaceutical intermediates

Ethene

Cas:74-85-1

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

Product Description Description & Specification Category Pharmaceutical Raw Materials, Fine Chemicals, Bulk drug Standard Medical standard

factory directly supply CAS 74-85-1 with competitive price

Cas:74-85-1

Min.Order:1 Kilogram

FOB Price: $112.0

Type:Trading Company

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

Ethylene

Cas:74-85-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hubei Langyou International Trading Co., Ltd

74-85-1 ETHYLENE Application:74-85-1 ETHYLENE

74-85-1 ETHYLENE

Cas:74-85-1

Min.Order:0

Negotiable

Type:Other

inquiry

Hunan Longxianng Runhui Trading Co.,Ltd

74-85-1 ETHYLENEAppearance:powder Storage:room tempurature Package:As required Application:medical Transportation:By express (Door to door) such as FEDEX, DHL, EMS for small amount. By air(airport to airport) or by sea LCL/FCL for large amount.

74-85-1 ETHYLENE

Cas:74-85-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Qingdao Sigma Chemical Co., Ltd.

Qingdao Sigma Chemical Ltd is is a global chemical industry manufacturers and suppliers of pharmaceuticals and intermediates, peptide,Nootropis etc API, food and feed additives, herbal extracts, agrochemicals and fine chemicals etc. Our Labo

High Quality ETHYLENE

Cas:74-85-1

Min.Order:1 Gram

FOB Price: $1.0

Type:Trading Company

inquiry

HENAN SUNLAKE ENTERPRISE CORPORATION

ETHYLENE Basic information Product Name: ETHYLENE Synonyms: ETHYLENE;Acetene;Athylen;bicarburettedhydrogen;Bicarburretted hydrogen;bicarburrettedhydrogen;C2H4;E

CAS:74-85-1 C2H4

Cas:74-85-1

Min.Order:500 Gram

Negotiable

Type:Trading Company

inquiry

HuBei Ipure Biotech CO.,ltd

HuBei ipure is a diversified product production and operation enterprise, with API, pharma intermediates, and other fine chemicals as well as R&D and pigments development and sales as one of the large enterprises, with more than 130 acres of pl

high purity 99.99% Ethylene CAS:74-85-1, C2H4

Cas:74-85-1

Min.Order:1 Gram

FOB Price: $1.0

Type:Trading Company

inquiry

Henan Fine Chemicals Co., Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & CommercialHenan Fine Chemicals Co., LTD. is a diversified technology - oriented integrated company, which mainly concentrates on fine chemicals. Our company is committed to becom

Ethene

Cas:74-85-1

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Chungking Joyinchem Co., Ltd.

Joyinchem have been committed to chemical supply for several years and have built good cooperation records with multinational chemical corporations and importers from all over the world. Our services include:-Spot goods-Contract manufacturing-Custom

Ethylene

Cas:74-85-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai AngewChem Co., Ltd.

Shanghai AngewChemCo., Ltd. is an innovative enterprise on fine chemicals and pharmaceuticals. Based on Shanghai R&D center and Hunan chemical manufacturing plant, we offer chemical research, process development, and large-scale production. Complete

Ethylene

Cas:74-85-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hebei mingxing biotech co.,ltd

Known for its best quality and competitve price, this chemicals we offered is widely appreciated by our customers. Prompt reaction, good quality and best service make us reliable and outstanding in this industry.Appearance:yellow to white solid or po

Ethene

Cas:74-85-1

Min.Order:0

Negotiable

Type:Other

inquiry

QINGDAO SUN TECH INDUSTRIES & TRADING CO., LTD

Liquid Ethylene Application:All kinds

Liquid Ethylene

Cas:74-85-1

Min.Order:0

Negotiable

Type:Other

inquiry

Hebei Minshang Biotechnology Co., Ltd

74-85-1 ETHYLENE Application:medical

74-85-1

Cas:74-85-1

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Nanjing Raymon Biotech Co., Ltd.

Ethylene Storage:Store in dry and cool condition Package:25kg or according to cutomer's demand Application:Chemical research/Pharmaceutical intermediates Transportation:By Sea,by Air,By courier like DHL or Fedx. Port:Shanghai/Shenzhen

Ethylene

Cas:74-85-1

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Shochem(Shanghai) Co., Ltd

good quality and best price Application:intermediates

Ethene

Cas:74-85-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Wuxi Morality Chemical Co., Ltd

Do best quality products, erect the morality model Application:Please email us, thanks

Ethylene

Cas:74-85-1

Min.Order:0

Negotiable

Type:Other

inquiry

Synova( Tianjin ) Chemical Technology Co,.Ltd

The company have effective management team, professional technical R & D personnel, the service spirit of customer oriented. We have long-term cooperation with famous domestic manufacturer, and excellent customer resources overseas. We are skilled in

ETHYLENE

Cas:74-85-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Skyrun Industrial Co.,Ltd

Purity, Prompt shipment, Price Application:surface active agent

CSR160805-22067

Cas:74-85-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Yanchu chemicals Co., Ltd

low price and good quality Application:It is an important raw material and intermediate used in Organic Synthesis, Pharmaceuticals, Agrochemicals and D

Ethylene

Cas:74-85-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

ethanol
64-17-5

ethanol

ethene
74-85-1

ethene

Conditions
ConditionsYield
With mesoporous silica MCM-4l/Al at 399.84℃; under 21.0021 - 94.5095 Torr; for 50h; Inert N2;100%
With H-USY zeolite at 299.84℃; under 760.051 Torr; for 1.5h; Catalytic behavior; Reagent/catalyst; Time; Temperature; Inert atmosphere; Flow reactor;100%
With water at 380℃; under 1500.15 Torr; Reagent/catalyst;99%
oxirane
75-21-8

oxirane

dipropylphosphinous iodide
81373-58-2

dipropylphosphinous iodide

A

ethene
74-85-1

ethene

B

2-iodoethyl dipropylphosphinate

2-iodoethyl dipropylphosphinate

Conditions
ConditionsYield
In dichloromethane for 1h; Yields of byproduct given;A n/a
B 100%
oxirane
75-21-8

oxirane

iodo-diphenyl-phosphine
20472-52-0

iodo-diphenyl-phosphine

A

ethene
74-85-1

ethene

B

2-iodoethyl diphenylphosphinate

2-iodoethyl diphenylphosphinate

Conditions
ConditionsYield
In dichloromethane for 1h; Yields of byproduct given;A n/a
B 100%
5-cyclopentylidene-2,2-dimethyl-1,3-dioxane-4,6-dione
3968-30-7

5-cyclopentylidene-2,2-dimethyl-1,3-dioxane-4,6-dione

A

butatriene
2873-50-9

butatriene

B

ethene
74-85-1

ethene

C

carbon dioxide
124-38-9

carbon dioxide

D

cyclohexa-1,3-diene
1165952-91-9

cyclohexa-1,3-diene

E

acetone
67-64-1

acetone

F

benzene
71-43-2

benzene

Conditions
ConditionsYield
With variation of temp. at 550℃; Product distribution;A 4%
B 11.9%
C 100%
D 39.2%
E 101.9 %
F 3.3%
diallyl sulphide
592-88-1

diallyl sulphide

A

2,5-dihydro-thiophene
1708-32-3

2,5-dihydro-thiophene

B

ethene
74-85-1

ethene

Conditions
ConditionsYield
With tungsten In octane; chlorobenzene at 80℃; for 1h;A 100%
B n/a
With chloroaryloxide neopentylidene complex of tungsten (1)A 90%
B n/a
(2,6-Ph2C6H3O)2W(Cl)=CHC(CH3)3*OEt2 In chlorobenzene at 80℃; for 3h;A 88%
B n/a
phenyl propionate
637-27-4

phenyl propionate

A

ethene
74-85-1

ethene

B

pentan-3-one
96-22-0

pentan-3-one

C

phenol
108-95-2

phenol

Conditions
ConditionsYield
With bis(1,5-cyclooctadiene)nickel (0); triphenylphosphine at 54℃; for 20h; Product distribution; Rate constant; Thermodynamic data; other solvents, reagents, reagents ratio, time, temperature; activation energy, ΔH<*>, ΔS<*>;A 100%
B n/a
C 100%
ethenyltrimethylsilane
754-05-2

ethenyltrimethylsilane

ethene
74-85-1

ethene

Conditions
ConditionsYield
With trifluoroacetic acid at 120℃;100%
Allyl ether
557-40-4

Allyl ether

A

2,5-dihydrofuran
1708-29-8

2,5-dihydrofuran

B

ethene
74-85-1

ethene

Conditions
ConditionsYield
With tungsten In octane; chlorobenzene at 80℃; for 2h;A 100%
B n/a
With Grubbs catalyst first generation In dichloromethane
3-allylsulfanyl-2-methyl-propene
83044-85-3

3-allylsulfanyl-2-methyl-propene

A

3-methyl-2,5-dihydro-thiophene
42855-50-5

3-methyl-2,5-dihydro-thiophene

B

ethene
74-85-1

ethene

Conditions
ConditionsYield
With tungsten In octane; chlorobenzene at 80℃; for 1h;A 100%
B n/a
2-phenylethanol
60-12-8

2-phenylethanol

ethenyltrimethylsilane
754-05-2

ethenyltrimethylsilane

A

ethene
74-85-1

ethene

B

trimethyl(phenethyloxy)silane
14629-58-4

trimethyl(phenethyloxy)silane

Conditions
ConditionsYield
hydrogenchloride; chlorobis(ethylene)rhodium(I) dimer In 1,4-dioxane; chloroform at 20℃; for 2h; Product distribution / selectivity;A n/a
B 100%
chlorobis(cyclooctene)rhodium(I) dimer In toluene at 70℃; for 3h; Product distribution / selectivity;A n/a
B 100%
hydrogenchloride; chlorobis(cyclooctene)rhodium(I) dimer In 1,4-dioxane; chloroform at 20℃; for 2h; Product distribution / selectivity;A n/a
B 96%
ethanol
64-17-5

ethanol

dimethylphenylvinylsilane
1125-26-4

dimethylphenylvinylsilane

A

ethene
74-85-1

ethene

B

dimethyl(ethoxy)phenylsilane
1825-58-7

dimethyl(ethoxy)phenylsilane

Conditions
ConditionsYield
hydrogenchloride; chlorobis(cyclooctene)rhodium(I) dimer In 1,4-dioxane; chloroform at 20℃; for 18h; Kinetics;A n/a
B 100%
isopropyl alcohol
67-63-0

isopropyl alcohol

dimethylphenylvinylsilane
1125-26-4

dimethylphenylvinylsilane

A

ethene
74-85-1

ethene

B

dimethyl(isopropoxy)phenylsilane
17988-21-5

dimethyl(isopropoxy)phenylsilane

Conditions
ConditionsYield
hydrogenchloride; chlorobis(cyclooctene)rhodium(I) dimer In 1,4-dioxane; chloroform at 20℃; for 24h; Kinetics;A n/a
B 100%
tris(1,10-phenanthroline)iron(III)
13479-49-7

tris(1,10-phenanthroline)iron(III)

cis-{(C2H5)2Co(2,2'-bipyridine)2}(ClO4)

cis-{(C2H5)2Co(2,2'-bipyridine)2}(ClO4)

A

ethane
74-84-0

ethane

B

ethene
74-85-1

ethene

C

n-butane
106-97-8

n-butane

Conditions
ConditionsYield
With oxygen In acetonitrile byproducts: {Co(2,2'-bipyridine)2}(2+); one-electron oxidn. of cis-Co complex by (Fe(phen)3(3+) in presence of O2 at 298 K; monitored by (1)H-NMR;A <1
B <1
C 100%
In acetonitrile byproducts: {Co(2,2'-bipyridine)2}(2+); one-electron oxidn. of cis-Co complex by (Fe(phen)3(3+) at 298 K; monitored by (1)H-NMR;A <1
B <1
C 98%
tris(2,2'-bipyridine)iron(III) ion
18661-69-3

tris(2,2'-bipyridine)iron(III) ion

cis-{(C2H5)2Co(2,2'-bipyridine)2}(ClO4)

cis-{(C2H5)2Co(2,2'-bipyridine)2}(ClO4)

A

ethane
74-84-0

ethane

B

ethene
74-85-1

ethene

C

n-butane
106-97-8

n-butane

Conditions
ConditionsYield
In acetonitrile byproducts: {Co(2,2'-bipyridine)2}(2+); one-electron oxidn. of cis-Co complex by (Fe(bpy)3(3+) at 298 K; monitored by (1)H-NMR;A <1
B <1
C 100%
diethylbis(triethylphosphine)platinum(II)
75847-39-1, 76189-28-1

diethylbis(triethylphosphine)platinum(II)

A

(ethylene)bis(triethylphosphine)platinum(0)
76136-93-1

(ethylene)bis(triethylphosphine)platinum(0)

B

ethene
74-85-1

ethene

Conditions
ConditionsYield
In cyclohexane Pt-complex evacuated to 0.1 torr, flushed with Ar, dry degassed cyclohexane added, cooled (liq. N2), evacuated (0.1 torr), sealed, warmed to room temp., heated at 118°C (oil bath) for 30 min;A 100%
B 0%
bis(1,5-cyclooctadiene)nickel (0)
1295-35-8

bis(1,5-cyclooctadiene)nickel (0)

tetrakis(triphenylphosphine)nickel(0)
15133-82-1

tetrakis(triphenylphosphine)nickel(0)

A

nickel(II) propionate

nickel(II) propionate

B

(triphenylphosphine)3(CO)nickelk
15376-83-7

(triphenylphosphine)3(CO)nickelk

C

ethene
74-85-1

ethene

D

phenol
108-95-2

phenol

Conditions
ConditionsYield
With triphenylphosphine In neat (no solvent) (N2 or Ar or vac.), EtCOOPh added to Ni(cod)2 and Ni(PPh3)4, mixture stirred at 54°C for 20 h; GLC;A 73%
B n/a
C 100%
D 91%
bis(1,5-cyclooctadiene)nickel (0)
1295-35-8

bis(1,5-cyclooctadiene)nickel (0)

phenyl propionate
637-27-4

phenyl propionate

A

(triphenylphosphine)3(CO)nickelk
15376-83-7

(triphenylphosphine)3(CO)nickelk

B

ethene
74-85-1

ethene

C

phenol
108-95-2

phenol

Conditions
ConditionsYield
With triphenylphosphine In neat (no solvent) Kinetics; byproducts: diethyl ketone, 1,3-cyclooctadiene, 1,4-cyclooctadiene; further byproducts: 1,5-cyclooctadiene, bicyclooctene-1, bicyclooctene-2, (N2 or Ar or vac.), EtCOOPh added to Ni(cod)2 and PPh3 (PPh3/Ni = 10), mixture stirred at 54°C for 21 h; gas chromy., volatile removed in vac., recrystd. from THF-hexane;A 80%
B 100%
C 100%
With triphenylphosphine In neat (no solvent) Kinetics; byproducts: diethyl ketone, 1,3-cyclooctadiene, 1,4-cyclooctadiene; further byproducts: 1,5-cyclooctadiene, bicyclooctene-1, bicyclooctene-2, (N2 or Ar or vac.), EtCOOPh added to Ni(cod)2 and PPh3 (PPh3/Ni = 4),mixture stirred at 54°C for 20 h; gas chromy., volatile removed in vac., recrystd. from THF-hexane;A 60%
B 100%
C 100%
With triphenylphosphine In neat (no solvent) Kinetics; byproducts: diethyl ketone, 1,3-cyclooctadiene, 1,4-cyclooctadiene; further byproducts: 1,5-cyclooctadiene, bicyclooctene-1, bicyclooctene-2, (N2 or Ar or vac.), EtCOOPh added to Ni(cod)2 and PPh3 (PPh3/Ni = 3),mixture stirred at 54°C for 20 h; gas chromy., volatile removed in vac., recrystd. from THF-hexane;A 60%
B 90%
C 90%
With triphenylphosphine In neat (no solvent) Kinetics; byproducts: diethyl ketone, 1,3-cyclooctadiene, 1,4-cyclooctadiene; further byproducts: 1,5-cyclooctadiene, bicyclooctene-1, bicyclooctene-2, (N2 or Ar or vac.), EtCOOPh added to Ni(cod)2 and PPh3 (PPh3/Ni = 2),mixture stirred at 54°C for 12 h; gas chromy., volatile removed in vac., recrystd. from THF-hexane;A 30%
B 60%
C 60%
With triphenylphosphine In neat (no solvent) Kinetics; byproducts: diethyl ketone, 1,3-cyclooctadiene, 1,4-cyclooctadiene; further byproducts: 1,5-cyclooctadiene, bicyclooctene-1, bicyclooctene-2, (N2 or Ar or vac.), EtCOOPh added to Ni(cod)2 and PPh3 (PPh3/Ni = 1),mixture stirred at 54°C for 12 h; gas chromy., volatile removed in vac., recrystd. from THF-hexane;A n/a
B 40%
C 50%
bis(1,5-cyclooctadiene)nickel (0)
1295-35-8

bis(1,5-cyclooctadiene)nickel (0)

phenyl propionate
637-27-4

phenyl propionate

Tri(p-tolyl)phosphine
1038-95-5

Tri(p-tolyl)phosphine

A

ethene
74-85-1

ethene

B

Ni(CO)(P(C6H4CH3)3)3
74887-07-3

Ni(CO)(P(C6H4CH3)3)3

C

phenol
108-95-2

phenol

Conditions
ConditionsYield
In further solvent(s) Kinetics; (N2 or Ar or vac.), EtCOOPh added to Ni(cod)2 and P(C6H4CH3)3 (P(Ph-CH3)3/Ni = 3) in acetophenone, mixture stirred at 65°C for 50 h;A 80%
B 85%
C 100%
N,N-Diallyltosylamide
50487-72-4

N,N-Diallyltosylamide

A

ethene
74-85-1

ethene

B

1-[(4-methylphenyl)sulfonyl]-2,5-dihydro-1H-pyrrole
16851-72-2

1-[(4-methylphenyl)sulfonyl]-2,5-dihydro-1H-pyrrole

Conditions
ConditionsYield
With Hoveyda-Grubbs catalyst second generation In dichloromethane at 40℃; for 1h; Concentration; Solvent; Temperature; Grubbs Olefin Metathesis; Flow reactor;A n/a
B 100%
With Hoveyda-Grubbs catalyst second generation In (2)H8-toluene at 29.84℃; Reagent/catalyst;
1,3-dithiolane-2-thione
822-38-8

1,3-dithiolane-2-thione

dimethyl acetylenedicarboxylate
762-42-5

dimethyl acetylenedicarboxylate

A

4,5-bis(methoxycarbonyl)-1,3-dithiole-2-thione
7396-41-0

4,5-bis(methoxycarbonyl)-1,3-dithiole-2-thione

B

ethene
74-85-1

ethene

Conditions
ConditionsYield
at 120 - 140℃;A 99.6%
B n/a
ethylene dibromide
106-93-4

ethylene dibromide

ethene
74-85-1

ethene

Conditions
ConditionsYield
With triethylamine In water at 20℃; for 2h; Inert atmosphere; Irradiation;99%
With vanadocene In hexane Product distribution; vanadocene monobromide, vanadocene monochloride; other temperature and reaction time.;62%
Electrolysis;
2,2-diphenyl-1,3-dithiolane
6317-10-8

2,2-diphenyl-1,3-dithiolane

A

benzophenone
119-61-9

benzophenone

B

ethene
74-85-1

ethene

Conditions
ConditionsYield
In chlorobenzene for 24h; Heating;A 99%
B n/a
7-Aza-bicyclo[2.2.1]hept-2-ene-1,2,3,4-tetracarboxylic acid diisopropyl ester dimethyl ester
85597-87-1

7-Aza-bicyclo[2.2.1]hept-2-ene-1,2,3,4-tetracarboxylic acid diisopropyl ester dimethyl ester

A

ethene
74-85-1

ethene

B

1H-Pyrrole-2,3,4,5-tetracarboxylic acid diisopropyl ester dimethyl ester
85597-95-1

1H-Pyrrole-2,3,4,5-tetracarboxylic acid diisopropyl ester dimethyl ester

Conditions
ConditionsYield
at 90 - 120℃; for 3h;A n/a
B 99%
ethanol
64-17-5

ethanol

A

diethyl ether
60-29-7

diethyl ether

B

ethene
74-85-1

ethene

Conditions
ConditionsYield
With alumina at 449.84℃; Catalytic behavior; Reagent/catalyst; Temperature; Inert atmosphere; Overall yield = 100 %;A 0.1%
B 98.9%
C2I2O2Rh(1-)*C8H20N(1+); tetraethylammonium iodide; hydrogen iodide In water at 110℃; Product distribution / selectivity; Inert atmosphere; Autoclave;A 10%
B 50%
1-methyl-3-(propyl-3-sulfonyl)imidazolium trifluoromethanesulfonate; CF3O3S(1-)*CHF3O3S*C7H13N2O3S(1+) at 240 - 260℃; for 4h; Product distribution / selectivity;A n/a
B 12%
methane
34557-54-5

methane

ethene
74-85-1

ethene

Conditions
ConditionsYield
under 760.051 Torr; Recess waveguide; Gas phase;98.53%
With hydrogen under 760.051 Torr; Product distribution / selectivity; Microwave irradiation;96.4%
Stage #1: methane
Stage #2: With alumina at 125℃; Reagent/catalyst; Temperature;
55%
ethane
74-84-0

ethane

ethene
74-85-1

ethene

Conditions
ConditionsYield
With oxygen; V-Mo-Nb-Te oxide98%
at 800℃; under 760.051 Torr; for 1h; Catalytic behavior; Gas phase; Flow reactor;84%
With disulfur; iron(II,III) oxide at 940℃; Reagent/catalyst; Temperature; Flow reactor;75.9%
methane
34557-54-5

methane

A

propene
187737-37-7

propene

B

ethene
74-85-1

ethene

Conditions
ConditionsYield
With iron sulfide at 800 - 900℃; other metal sulfides;A 2%
B 98%
With SAPO-34/HZSM-5 nanostructure In water at 370℃; for 20h; Reagent/catalyst; Inert atmosphere;
7-Aza-bicyclo[2.2.1]hept-2-ene-1,2,3,4-tetracarboxylic acid tetramethyl ester
85597-84-8

7-Aza-bicyclo[2.2.1]hept-2-ene-1,2,3,4-tetracarboxylic acid tetramethyl ester

A

ethene
74-85-1

ethene

B

tetramethyl 1H-pyrrole-2,3,4,5-tetracarboxylate
2703-15-3

tetramethyl 1H-pyrrole-2,3,4,5-tetracarboxylate

Conditions
ConditionsYield
at 90 - 120℃; for 3h;A n/a
B 98%
7-Aza-bicyclo[2.2.1]hept-2-ene-1,2,3,4-tetracarboxylic acid di-tert-butyl ester dimethyl ester
85597-90-6

7-Aza-bicyclo[2.2.1]hept-2-ene-1,2,3,4-tetracarboxylic acid di-tert-butyl ester dimethyl ester

A

ethene
74-85-1

ethene

B

1H-Pyrrole-2,3,4,5-tetracarboxylic acid di-tert-butyl ester dimethyl ester
85597-98-4

1H-Pyrrole-2,3,4,5-tetracarboxylic acid di-tert-butyl ester dimethyl ester

Conditions
ConditionsYield
at 90 - 120℃; for 3h;A n/a
B 98%
7-Aza-bicyclo[2.2.1]hept-2-ene-1,2,3,4-tetracarboxylic acid dicyclohexyl ester dimethyl ester
85597-92-8

7-Aza-bicyclo[2.2.1]hept-2-ene-1,2,3,4-tetracarboxylic acid dicyclohexyl ester dimethyl ester

A

ethene
74-85-1

ethene

B

1H-Pyrrole-2,3,4,5-tetracarboxylic acid dicyclohexyl ester dimethyl ester
85598-00-1

1H-Pyrrole-2,3,4,5-tetracarboxylic acid dicyclohexyl ester dimethyl ester

Conditions
ConditionsYield
at 90 - 120℃; for 3h;A n/a
B 98%
ethene
74-85-1

ethene

1-hexene
592-41-6

1-hexene

Conditions
ConditionsYield
With trimethylamine-N-oxide; [N(4-C6H4Br)3][B(C6F5)4]; triethylaluminum; [Cr(CO)4(2-C6H4(MeO))2PN(Me)P(2-C6H4(MeO))2] In toluene at 60℃; under 30002.4 Torr; for 1h;100%
In chlorobenzene at 45℃; under 36201.3 Torr; for 4h; Product distribution / selectivity;99%
In chlorobenzene at 60℃; under 36201.3 Torr; for 4h; Product distribution / selectivity;99%
ethene
74-85-1

ethene

ethane
74-84-0

ethane

Conditions
ConditionsYield
With hydrogen; [Ru2(μ-O2C-C6H4-CO2)2] at 20℃; for 5.4h; Kinetics; Product distribution; Further Variations:; Catalysts; reaction times;100%
With [1,1-(1,3-dimethylimidazol-2-ylidene)(PPh3)-3-(Py)-1,2-RhSB9H8]; hydrogen In dichloromethane-d2 under 3750.38 Torr; for 12h; Catalytic behavior; Time; Inert atmosphere;73%
With hydrogen; palladium25%
ethene
74-85-1

ethene

bis(2-chloroethyl)selenium dichloride
106471-36-7

bis(2-chloroethyl)selenium dichloride

Conditions
ConditionsYield
With selenium tetrachloride In benzene100%
With tetrachlorosilane; chloroform
With diselenium dichloride; benzene
ethene
74-85-1

ethene

acetaldehyde
75-07-0

acetaldehyde

Conditions
ConditionsYield
With bis(benzonitrile)palladium(II) dichloride; py.Co(N,N'-bis(alicylidene-o-phenylene)diamino).NO2 In tetrahydrofuran at 50℃; under 760 Torr; for 0.916667h;100%
With bis(benzonitrile)palladium(II) dichloride; py.Co(N,N'-bis(alicylidene-o-phenylene)diamino).NO2 In tetrahydrofuran at 50℃; under 760 Torr; for 0.916667h; Product distribution; influence of Pd/Co ratio, solvent, further olefins;100%
With aluminum(III) sulfate; water at 350 - 360℃;
styrene
292638-84-7

styrene

ethene
74-85-1

ethene

3-phenylbut-1-ene
934-10-1

3-phenylbut-1-ene

Conditions
ConditionsYield
With silver trifluoromethanesulfonate; triphenylphosphine; bi(allylnickel bromide) In dichloromethane at -55℃; under 760 Torr; for 2h;100%
With bi(allylnickel bromide); silver trifluoromethanesulfonate; triphenylphosphine In dichloromethane at -55℃; under 760 Torr; for 2h; Addition; Hydrovinylation;95%
With 2; diethylaluminium chloride; triphenylphosphine In dichloromethane; toluene under 7500.6 Torr; for 0.5h;90%
ethene
74-85-1

ethene

Bis(trifluoromethyl)disulfid
372-64-5

Bis(trifluoromethyl)disulfid

1,2-Bis-trifluormethyl-mercapto-ethan
674-64-6

1,2-Bis-trifluormethyl-mercapto-ethan

Conditions
ConditionsYield
Irradiation (UV/VIS); 44 h;100%
Irradiation (UV/VIS); 44 h;100%
Irradiation;
ethene
74-85-1

ethene

1,4-Dithia-7-azanorbornylium hexafluoroarsenate
106726-64-1

1,4-Dithia-7-azanorbornylium hexafluoroarsenate

Conditions
ConditionsYield
With dithionitronium hexafluoroarsenate In liquid sulphur dioxide Ambient temperature;100%
With dithionitronium hexafluoroarsenate In liquid sulphur dioxide for 1h; Ambient temperature;100%
ethene
74-85-1

ethene

carbon monoxide
201230-82-2

carbon monoxide

di-n-propylamine
142-84-7

di-n-propylamine

tri-n-propylamine
102-69-2

tri-n-propylamine

Conditions
ConditionsYield
di(rhodium)tetracarbonyl dichloride In ethanol at 115℃; under 37503 Torr; for 1.5h;100%
ethene
74-85-1

ethene

4-ethoxyphenylacetic acid chloride
10368-35-1

4-ethoxyphenylacetic acid chloride

6-ethoxy-3,4-dihydro-2(1H)-naphthalenone
69788-78-9

6-ethoxy-3,4-dihydro-2(1H)-naphthalenone

Conditions
ConditionsYield
With aluminium trichloride In dichloromethane for 4h; Ambient temperature;100%
ethene
74-85-1

ethene

polyethylene

polyethylene

Conditions
ConditionsYield
With triphenylphosphine; bis(1,5-cyclooctadiene)nickel (0) In toluene at 25℃; under 22502.3 Torr; for 70h;100%
With tetramethyldialuminoxane; N,N'-(1,1-Me2-ethylene)bis(salicylideneaminato)Zr(IV)Cl2*THF In toluene at 25℃; under 7500.6 Torr; for 24h; Polymerization;
Pd-2 at 22℃; under 4137.18 Torr; for 12h; Polymerization;
ethene
74-85-1

ethene

3-acetoxy-3-(4-methoxyphenyl)prop-1-yne
99520-55-5

3-acetoxy-3-(4-methoxyphenyl)prop-1-yne

acetic acid 1-(4-methoxy-phenyl)-2-methylene-but-3-enyl ester

acetic acid 1-(4-methoxy-phenyl)-2-methylene-but-3-enyl ester

Conditions
ConditionsYield
With RuCl2(P(C6H11)3)(1,3-dimesityl-4,5-dihydroimidazol-2-ylidene)(=CHC6H5) In toluene at 80℃; under 760 Torr; for 0.5h;100%
With tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride In toluene at 80℃; under 760.051 Torr; for 0.5h;100%
ethene
74-85-1

ethene

acetic acid 5-phenylpent-2-ynyl ester

acetic acid 5-phenylpent-2-ynyl ester

acetic acid 2-methylene-3-phenethylbut-3-enyl ester

acetic acid 2-methylene-3-phenethylbut-3-enyl ester

Conditions
ConditionsYield
With RuCl2(P(C6H11)3)(1,3-dimesityl-4,5-dihydroimidazol-2-ylidene)(=CHC6H5) In toluene at 80℃; under 760 Torr; for 0.5h;100%
With tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride In toluene at 80℃; under 760.051 Torr; for 2h;94%
ethene
74-85-1

ethene

(1S,4R,5S,6R)-5,6-Bis-prop-2-ynyloxy-bicyclo[2.2.1]hept-2-ene
441741-15-7

(1S,4R,5S,6R)-5,6-Bis-prop-2-ynyloxy-bicyclo[2.2.1]hept-2-ene

(4aS,4bR,8aS,9aR)-2,7-Divinyl-4a,4b,6,8a,9,9a-hexahydro-3H-4,5-dioxa-fluorene
441741-16-8

(4aS,4bR,8aS,9aR)-2,7-Divinyl-4a,4b,6,8a,9,9a-hexahydro-3H-4,5-dioxa-fluorene

Conditions
ConditionsYield
Grubbs catalyst first generation In dichloromethane at 20℃; for 4h;100%
Grubbs catalyst first generation In dichloromethane at 20℃; for 4h;53%
ethene
74-85-1

ethene

N-(cyclopentenylmethyl)-4-methyl-N-(prop-2-ynyl)benzenesulfonamide
477977-14-3

N-(cyclopentenylmethyl)-4-methyl-N-(prop-2-ynyl)benzenesulfonamide

2-(toluene-4-sulfonyl)-1,2,3,4,5,6-hexahydro-cyclohepta[c]pyrrole

2-(toluene-4-sulfonyl)-1,2,3,4,5,6-hexahydro-cyclohepta[c]pyrrole

Conditions
ConditionsYield
Cl2(PCy3)(N,N'-(Mes)2-imidazolidin-2-yl)Ru=CHC6H5 In dichloromethane under 760.051 Torr; for 26h; Heating;100%
ethene
74-85-1

ethene

8,8-dimethyl-4-phenyl-6,10-dioxa-spiro[4.5]deca-1,3-diene-1,2-dicarboxylic acid dimethyl ester
780755-05-7

8,8-dimethyl-4-phenyl-6,10-dioxa-spiro[4.5]deca-1,3-diene-1,2-dicarboxylic acid dimethyl ester

C22H26O6

C22H26O6

Conditions
ConditionsYield
In toluene at 100℃; for 192h; Diels-Alder reaction; ambient pressure;100%
ethene
74-85-1

ethene

Pentafluoroethyl iodide
354-64-3

Pentafluoroethyl iodide

1,1,1,2,2-pentafluoro-4-iodobutane
40723-80-6

1,1,1,2,2-pentafluoro-4-iodobutane

Conditions
ConditionsYield
With Vazo64100%
With triethyl phosphite71%
With hydrazine hydrate; copper (I) acetate In isopropyl alcohol at 30℃; under 22800 Torr; for 4h;69%
copper at 80℃; under 6000.6 - 7500.75 Torr; for 1.33333h; Product distribution / selectivity;
With VAZO 64 at 65 - 81℃; under 4897.34 - 8931.21 Torr; for 3h; Industry scale; Autoclave;97.3 %Chromat.
N-(1S)-[(2S)-2-((1R)-1-hydroxy-3-trimethylsilyl-2-propyn-1-yl)-4-pentenoyl]bornane-10,2-sultam

N-(1S)-[(2S)-2-((1R)-1-hydroxy-3-trimethylsilyl-2-propyn-1-yl)-4-pentenoyl]bornane-10,2-sultam

ethene
74-85-1

ethene

N-(1S)-[1-[(1S,2R)-2-hydroxy-3-(1-trimethylsilylethen-1-yl)-3-cyclopentenyl]carbonyl]bornane-10,2-sultam

N-(1S)-[1-[(1S,2R)-2-hydroxy-3-(1-trimethylsilylethen-1-yl)-3-cyclopentenyl]carbonyl]bornane-10,2-sultam

Conditions
ConditionsYield
tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride In toluene at 80℃;100%
N-(1S)-[(2R,3R)-6-benzyloxy-3-hydroxy-2-allyl-hex-4-ynoyl]bornane-10,2-sultam

N-(1S)-[(2R,3R)-6-benzyloxy-3-hydroxy-2-allyl-hex-4-ynoyl]bornane-10,2-sultam

ethene
74-85-1

ethene

N-(1S)-[1-[(1R,2R)-2-hydroxy-3-(3-(benzyloxy)prop-1-en-2-yl)-3-cyclopentenyl]carbonyl]bornane-10,2-sultam

N-(1S)-[1-[(1R,2R)-2-hydroxy-3-(3-(benzyloxy)prop-1-en-2-yl)-3-cyclopentenyl]carbonyl]bornane-10,2-sultam

Conditions
ConditionsYield
tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride In toluene at 80℃;100%
N-(1S)-[(2R,3R)-6-benzyloxy-3-triethylsilyloxy-2-propen-3-yl-hex-4-ynoyl]bornane-10,2-sultam

N-(1S)-[(2R,3R)-6-benzyloxy-3-triethylsilyloxy-2-propen-3-yl-hex-4-ynoyl]bornane-10,2-sultam

ethene
74-85-1

ethene

N-(1S)-[1-[(1R,2R)-2-triethylsilyloxy-3-(3-(benzyloxy)prop-1-en-2-yl)-3-cyclopentenyl]carbonyl]bornane-10,2-sultam

N-(1S)-[1-[(1R,2R)-2-triethylsilyloxy-3-(3-(benzyloxy)prop-1-en-2-yl)-3-cyclopentenyl]carbonyl]bornane-10,2-sultam

Conditions
ConditionsYield
tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride In toluene at 80℃;100%
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