Phosphorus oxychloride
|
1.
1.1
IDENTIFICATION
OF
THE
SUBSTANCE/MIXTURE
AND
OF
THE
COMPANY/UNDERTAKING
Product
identifiers
Product
name
Product
Number
Brand
Index-No.
CAS-No.
:
:
:
:
:
Phosphorus(V)
oxychloride
201170
Anonymous
015-009-00-5
10025-87-3
1.2
Relevant
identified
uses
of
the
substance
or
mixture
and
uses
advised
against
Identified
uses
:
Laboratory
chemicals,
Manufacture
of
substances 2.
2.1
2.2
HAZARDS
IDENTIFICATION
Classification
of
the
substance
or
mixture
Classification
according
to
Regulation
(EC)
No
1272/2008
[EU-GHS/CLP]
Acute
toxicity,
Inhalation
(Category
2)
Specific
target
organ
toxicity
-
repeated
exposure
(Category
1)
Acute
toxicity,
Oral
(Category
4)
Skin
corrosion
(Category
1A)
Classification
according
to
EU
Directives
67/548/EEC
or
1999/45/EC
Reacts
violently
with
water.
Toxic:
danger
of
serious
damage
to
health
by
prolonged
exposure
through
inhalation.
Very
toxic
by
inhalation.
Causes
severe
burns.
Harmful
if
swallowed.
Contact
with
water
liberates
toxic
gas.
Label
elements
Labelling
according
Regulation
(EC)
No
1272/2008
[CLP]
Pictogram
Signal
word
Hazard
statement(s)
H302
H314
H330
H372
Danger
Harmful
if
swallowed.
Causes
severe
skin
burns
and
eye
damage.
Fatal
if
inhaled.
Causes
damage
to
organs
through
prolonged
or
repeated
exposure.
Precautionary
statement(s)
P260
P280
P284
P305
+
P351
+
P338
P310
Do
not
breathe
dust/
fume/
gas/
mist/
vapours/
spray.
Wear
protective
gloves/
protective
clothing/
eye
protection/
face
protection.
Wear
respiratory
protection.
IF
IN
EYES:
Rinse
cautiously
with
water
for
several
minutes.
Remove
contact
lenses,
if
present
and
easy
to
do.
Continue
rinsing.
Immediately
call
a
POISON
CENTER
or
doctor/
physician.
Supplemental
Hazard
information
(EU)
EUH014
EUH029
Reacts
violently
with
water.
Contact
with
water
liberates
toxic
gas.
According
to
European
Directive
67/548/EEC
as
amended.
Hazard
symbol(s)
R-phrase(s)
R14
R22
R26
R35
R48/23
R29
S-phrase(s)
S
7/8
S26
S36/37/39
S45
Reacts
violently
with
water.
Harmful
if
swallowed.
Very
toxic
by
inhalation.
Causes
severe
burns.
Toxic:
danger
of
serious
damage
to
health
by
prolonged
exposure
through
inhalation.
Contact
with
water
liberates
toxic
gas.
Keep
container
tightly
closed
and
dry.
In
case
of
contact
with
eyes,
rinse
immediately
with
plenty
of
water
and
seek
medical
advice.
Wear
suitable
protective
clothing,
gloves
and
eye/face
protection.
In
case
of
accident
or
if
you
feel
unwell,
seek
medical
advice
immediately
(show
the
label
where
possible).
2.3
3.
3.1
Other
hazards
Reacts
violently
with
water.,
Lachrymator.
COMPOSITION/INFORMATION
ON
INGREDIENTS
Substances
Synonyms
Formula
Molecular
Weight
Component
Phosphoryl
trichloride
:
:
:
Phosphorus(V)
oxide
chloride
Phosphoryl
chloride
Cl3OP
153,33
g/mol
Concentration
CAS-No.
EC-No.
Index-No.
10025-87-3
233-046-7
015-009-00-5
-
4.
4.1
FIRST
AID
MEASURES
Description
of
first
aid
measures
General
advice
Consult
a
physician.
Show
this
safety
data
sheet
to
the
doctor
in
attendance.
If
inhaled
If
breathed
in,
move
person
into
fresh
air.
If
not
breathing,
give
artificial
respiration.
Consult
a
physician.
In
case
of
skin
contact
Take
off
contaminated
clothing
and
shoes
immediately.
Wash
off
with
soap
and
plenty
of
water.
Take
victim
immediately
to
hospital.
Consult
a
physician.
In
case
of
eye
contact
Rinse
thoroughly
with
plenty
of
water
for
at
least
15
minutes
and
consult
a
physician.
If
swallowed
Do
NOT
induce
vomiting.
Never
give
anything
by
mouth
to
an
unconscious
person.
Rinse
mouth
with
water.
Consult
a
physician.
4.2
4.3
5.
5.1
5.2
5.3
5.4
6.
6.1
6.2
6.3
6.4
7.
7.1
7.2
7.3
Most
important
symptoms
and
effects,
both
acute
and
delayed
Redness,
corneal
injury,
Cough,
Shortness
of
breath,
Dizziness,
Headache,
chest
pain,
Nausea,
Vomiting,
Kidney
injury
may
occur.,
Abdominal
pain
Indication
of
any
immediate
medical
attention
and
special
treatment
needed
no
data
available
FIREFIGHTING
MEASURES
Extinguishing
media
Suitable
extinguishing
media
Use
extinguishing
measures
that
are
appropriate
to
local
circumstances
and
the
surrounding
environment.
Dry
powder
Special
hazards
arising
from
the
substance
or
mixture
Oxides
of
phosphorus,
Hydrogen
chloride
gas
Advice
for
firefighters
Wear
self
contained
breathing
apparatus
for
fire
fighting
if
necessary.
Further
information
Water
hydrolyzes
material
liberating
acidic
gas
which
in
contact
with
metal
surfaces
can
generate
flammable
and/or
explosive
hydrogen
gas.The
product
itself
does
not
burn.
ACCIDENTAL
RELEASE
MEASURES
Personal
precautions,
protective
equipment
and
emergency
procedures
Wear
respiratory
protection.
Avoid
breathing
vapors,
mist
or
gas.
Ensure
adequate
ventilation.
Evacuate
personnel
to
safe
areas.
Environmental
precautions
Prevent
further
leakage
or
spillage
if
safe
to
do
so.
Do
not
let
product
enter
drains.
Methods
and
materials
for
containment
and
cleaning
up
Soak
up
with
inert
absorbent
material
and
dispose
of
as
hazardous
waste.
Do
not
flush
with
water.
Keep
in
suitable,
closed
containers
for
disposal.
Reference
to
other
sections
For
disposal
see
section
13.
HANDLING
AND
STORAGE
Precautions
for
safe
handling
Avoid
contact
with
skin
and
eyes.
Avoid
inhalation
of
vapour
or
mist.
Conditions
for
safe
storage,
including
any
incompatibilities
Store
under
inert
gas.
Store
in
cool
place.
Keep
container
tightly
closed
in
a
dry
and
well-ventilated
place.
Containers
which
are
opened
must
be
carefully
resealed
and
kept
upright
to
prevent
leakage.
Keep
away
from
water.Never
allow
product
to
get
in
contact
with
water
during
storage.
Specific
end
uses
no
data
available
8.
8.1
8.2
9.
9.1
EXPOSURE
CONTROLS/PERSONAL
PROTECTION
Control
parameters
Components
with
workplace
control
parameters
Exposure
controls
Appropriate
engineering
controls
Avoid
contact
with
skin,
eyes
and
clothing.
Wash
hands
before
breaks
and
immediately
after
handling
the
product.
Personal
protective
equipment
Eye/face
protection
Tightly
fitting
safety
goggles.
Faceshield
(8-inch
minimum).
Use
equipment
for
eye
protection
tested
and
approved
under
appropriate
government
standards
such
as
NIOSH
(US)
or
EN
166(EU).
Skin
protection
Handle
with
gloves.
Gloves
must
be
inspected
prior
to
use.
Use
proper
glove
removal
technique
(without
touching
glove's
outer
surface)
to
avoid
skin
contact
with
this
product.
Dispose
of
contaminated
gloves
after
use
in
accordance
with
applicable
laws
and
good
laboratory
practices.
Wash
and
dry
hands.
The
selected
protective
gloves
have
to
satisfy
the
specifications
of
EU
Directive
89/686/EEC
and
the
standard
EN
374
derived
from
it.
Splash
protection
Material:
Nitrile
rubber
Minimum
layer
thickness:
0,4
mm
Break
through
time:
>
30
min
Material
tested:Camatril?
(Anonymous
Z677442,
Size
M)
data
source:
KCL
GmbH,
D-36124
Eichenzell,
phone
+49
(0)6659
873000,
e-mail
sales@kcl.de,
test
method:
EN374
If
used
in
solution,
or
mixed
with
other
substances,
and
under
conditions
which
differ
from
EN
374,
contact
the
supplier
of
the
CE
approved
gloves.
This
recommendation
is
advisory
only
and
must
be
evaluated
by
an
Industrial
Hygienist
familiar
with
the
specific
situation
of
anticipated
use
by
our
customers.
It
should
not
be
construed
as
offering
an
approval
for
any
specific
use
scenario.
Body
Protection
Complete
suit
protecting
against
chemicals,
Flame
retardant
protective
clothing,
The
type
of
protective
equipment
must
be
selected
according
to
the
concentration
and
amount
of
the
dangerous
substance
at
the
specific
workplace.
Respiratory
protection
Where
risk
assessment
shows
air-purifying
respirators
are
appropriate
use
a
full-face
respirator
with
multi-purpose
combination
(US)
or
type
ABEK
(EN
14387)
respirator
cartridges
as
a
backup
to
engineering
controls.
If
the
respirator
is
the
sole
means
of
protection,
use
a
full-face
supplied
air
respirator.
Use
respirators
and
components
tested
and
approved
under
appropriate
government
standards
such
as
NIOSH
(US)
or
CEN
(EU).
PHYSICAL
AND
CHEMICAL
PROPERTIES
Information
on
basic
physical
and
chemical
properties
a)
b)
c)
d)
e)
f)
Appearance
Odour
Odour
Threshold
pH
Melting
point/freezing
point
Initial
boiling
point
and
Form:
liquid
no
data
available
no
data
available
1
at
20
°C
Melting
point/range:
1,25
°C
-
lit.
105,8
°C
-
lit.
boiling
range
g)
h)
Flash
point
Evaporation
rate
no
data
available
no
data
available
i)
Flammability
(solid,
gas)
no
data
available
j)
k)
l)
Upper/lower
flammability
or
explosive
limits
Vapour
pressure
Vapour
density
no
data
available
37
hPa
at
20
°C
139
hPa
at
50
°C
5,29
-
(Air
=
1.0)
m)
Relative
density
1,645
g/cm3
at
25
°C
n)
o)
p)
q)
r)
s)
t)
Water
solubility
Partition
coefficient:
n-
octanol/water
Autoignition
temperature
Decomposition
temperature
Viscosity
Explosive
properties
Oxidizing
properties
no
data
available
no
data
available
no
data
available
no
data
available
no
data
available
no
data
available
no
data
available
9.2
10.
10.1
10.2
10.3
10.4
10.5
10.6
11.
11.1
Other
safety
information
no
data
available
STABILITY
AND
REACTIVITY
Reactivity
no
data
available
Chemical
stability
no
data
available
Possibility
of
hazardous
reactions
Reacts
violently
with
water.
Conditions
to
avoid
Exposure
to
moisture.
Incompatible
materials
Strong
bases,
Alcohols,
Amines,
Phenol,
Metals,
Strong
oxidizing
agents,
Reacts
violently
with
water.,
Acetone
reacts
violently
with
phosphorous
oxychloride.
Hazardous
decomposition
products
Other
decomposition
products
-
no
data
available
TOXICOLOGICAL
INFORMATION
Information
on
toxicological
effects
Acute
toxicity
LD50
Oral
-
rat
-
36
mg/kg
Remarks:
Gastrointestinal:Other
changes.
Liver:Other
changes.
Nutritional
and
Gross
Metabolic:Weight
loss
or
decreased
weight
gain.
LC50
Inhalation
-
rat
-
4
h
-
32
ppm
LC50
Inhalation
-
rat
-
4
h
-
0,197
mg/l
Skin
corrosion/irritation
no
data
available
Serious
eye
damage/eye
irritation
no
data
available
Respiratory
or
skin
sensitization
no
data
available
Germ
cell
mutagenicity
no
data
available
Carcinogenicity
IARC:
No
component
of
this
product
present
at
levels
greater
than
or
equal
to
0.1%
is
identified
as
probable,
possible
or
confirmed
human
carcinogen
by
IARC.
Reproductive
toxicity
no
data
available
Specific
target
organ
toxicity
-
single
exposure
no
data
available
Specific
target
organ
toxicity
-
repeated
exposure
Inhalation
-
Causes
damage
to
organs
through
prolonged
or
repeated
exposure.
Aspiration
hazard
no
data
available
Potential
health
effects
Inhalation
Ingestion
Skin
Eyes
May
be
fatal
if
inhaled.
Material
is
extremely
destructive
to
the
tissue
of
the
mucous
membranes
and
upper
respiratory
tract.
May
be
fatal
if
swallowed.
Causes
burns.
Toxic
if
absorbed
through
skin.
Causes
skin
burns.
Causes
eye
burns.
Signs
and
Symptoms
of
Exposure
Redness,
corneal
injury,
Cough,
Shortness
of
breath,
Dizziness,
Headache,
chest
pain,
Nausea,
Vomiting,
Kidney
injury
may
occur.,
Abdominal
pain
Additional
Information
RTECS:
TH4897000
12.
12.1
12.2
12.3
12.4
12.5
12.6
13.
13.1
ECOLOGICAL
INFORMATION
Toxicity
no
data
available
Persistence
and
degradability
no
data
available
Bioaccumulative
potential
no
data
available
Mobility
in
soil
no
data
available
Results
of
PBT
and
vPvB
assessment
no
data
available
Other
adverse
effects
May
be
harmful
to
aquatic
organisms
due
to
the
shift
of
the
pH.
DISPOSAL
CONSIDERATIONS
Waste
treatment
methods
Product
Offer
surplus
and
non-recyclable
solutions
to
a
licensed
disposal
company.
Contaminated
packaging
Dispose
of
as
unused
product.
14.
14.1
TRANSPORT
INFORMATION
UN
number
14.2
ADR/RID:
1810
UN
proper
shipping
name
IMDG:
1810
IATA:
1810
ADR/RID:
IMDG:
IATA:
PHOSPHORUS
OXYCHLORIDE
PHOSPHORUS
OXYCHLORIDE
Phosphorus
oxychloride
Passenger
Aircraft:
Not
permitted
for
transport
Cargo
Aircraft:
Not
permitted
for
transport
14.3
Transport
hazard
class(es)
14.4
14.5
14.6
15.
ADR/RID:
6.1
(8)
Packaging
group
ADR/RID:
I
Environmental
hazards
ADR/RID:
no
Special
precautions
for
user
no
data
available
REGULATORY
INFORMATION
IMDG:
6.1
(8)
IMDG:
I
IMDG
Marine
pollutant:
no
IATA:
6.1
(8)
IATA:
-
IATA:
no
This
safety
datasheet
complies
with
the
requirements
of
Regulation
(EC)
No.
1907/2006.
15.1
15.2
16.
Safety,
health
and
environmental
regulations/legislation
specific
for
the
substance
or
mixture
no
data
available
Chemical
Safety
Assessment
no
data
available
OTHER
INFORMATION
Further
information
The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information this document is based on the resent state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. Lookchem shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. |
Related Product
Recommended suppliers
Hunan Russell Chemicals Technology Co.,Ltd
China (Mainland) Assessed Supplier
Phosphorus oxychloride 10025-87-3
- Assay：98%
- Appearance：solid or liquid
- Package：Foil bag; Drum; Plastic bottle
- Storage:in sealed air resistant place
- Transportation：by sea or air
- Application:Pharma;Industry;Agricultural
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