-
Name
2,2',6,6'-tetramethyl-N-nitrosopiperidine
- EINECS
- CAS No. 6130-93-4
- Article Data3
- CAS DataBase
- Density 1g/cm3
- Solubility
- Melting Point
- Formula C9H18 N2 O
- Boiling Point 246.1°C at 760 mmHg
- Molecular Weight 170.255
- Flash Point 102.6°C
- Transport Information
- Appearance
- Safety Poison by ingestion and intravenous routes. Questionable carcinogen with experimental tumorigenic data. When heated to decomposition it emits toxic fumes of NOx. See also NITROSO COMPOUNDS.
- Risk Codes
-
Molecular Structure
- Hazard Symbols
- Synonyms 1-Nitroso-2,2,6,6-tetramethylpiperidine;2,2,6,6-Tetramethyl-N-nitrosopiperidine; 2,2,6,6-Tetramethylnitrosopiperidine;N-Nitroso-2,2,6,6-tetramethylpiperidine
- PSA 98.13000
- LogP 2.95150
2,2,6,6-Tetramethylnitrosopiperidine Chemical Properties
IUPAC Name: 2,2,6,6-Tetramethyl-1-nitrosopiperidine
Molecular Formula: C9H18N2O
Density: 1 g/cm3
Boiling Point: 246.1 °C at 760 mmHg
Flash Point: 102.6 °C
Molecular Weight: 170.29g/mol
Properties: golden-yellow liquid.
Freely Rotating Bonds: 1
Polar Surface Area: 32.67 Å2
Index of Refraction: 1.499
Molar Refractivity: 49.65 cm3
Molar Volume: 168.9 cm3
Polarizability: 19.68 ×10-24 cm3
Surface Tension: 33.4 dyne/cm
Enthalpy of Vaporization: 46.36 kJ/mol
Vapour Pressure: 0.0434 mmHg at 25°C
The Cas Register Number of 2,2,6,6-Tetramethylnitrosopiperidine is 6130-93-4.The chemical synonyms of 2,2,6,6-Tetramethylnitrosopiperidine (CAS NO.6130-93-4) are 2,2,6,6-tetramethyl-1-nitrosopiperidine ; Piperidine, 2,2,6,6-tetramethyl-1-nitroso- ; 1-Nitroso-2,2,6,6-tetramethylpiperidine ; 2,2,6,6-Tetramethyl-1-nitroso-piperidine ; 2,2,6,6-Tetramethylnitrosopiperidine ; 2,2',6,6'-Tetramethyl-N-nitrosopiperidine ; 5-20-04-00252 (Beilstein Handbook Reference) [Beilstein] ; 6130-93-4 [RN] ; Piperidine, 1-nitroso-2,2,6,6-tetramethyl- .The molecular structure of 2,2,6,6-Tetramethylnitrosopiperidine (CAS NO.6130-93-4) is
.
2,2,6,6-Tetramethylnitrosopiperidine Uses
It can be used in organic synthesis.
2,2,6,6-Tetramethylnitrosopiperidine Production
Bromination of 2,2,6,6-tetramethyl-4-oximinopiperidine by N-bromosuccinimide and subsequent oxidation yields 2,2,6,6-Tetramethylnitrosopiperidine (CAS NO.6130-93-4) .
The reaction of 2,2,6,6-tetramethyl-4-nitropiperidine with iodine gives2,2,6,6-Tetramethylnitrosopiperidine (CAS NO.6130-93-4) .
Oxidation of 2,2,6,6-tetramethyl-4-bromo- and 2,2,6,6-tetramethyl-4-iodo-4-nitropiperidines by perbenzoic acid yields the corresponding nitroxyl radicals .
2,2,6,6-Tetramethylnitrosopiperidine Toxicity Data With Reference
| 1. | orl-mus LD50:300 mg/kg | NATUAS Nature. 184 (1959),1707. | ||
| 2. | ivn-mus LD50:25 mg/kg | NATUAS Nature. 184 (1959),1707. |
2,2,6,6-Tetramethylnitrosopiperidine Safety Profile
Poison by ingestion and intravenous routes. Questionable carcinogen with experimental tumorigenic data. When heated to decomposition it emits toxic fumes of NOx. See also NITROSO COMPOUNDS.
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