4,4'-Dimethoxybiphenyl

The 4,4'-Dimethoxybiphenyl is an organic compound with the formula C₁₄H₁₄O₂. The systematic name of this chemical is 4,4'-dimethoxybiphenyl. With the CAS registry number 2132-80-1, it is also named as 1,1'-Biphenyl, 4,4'-dimethoxy-. The product's category is Biphenyl & Diphenyl ether.

Physical properties about 4,4'-Dimethoxybiphenyl are: (1)ACD/LogP: 3.61; (2)ACD/LogD (pH 5.5): 3.61; (3)ACD/LogD (pH 7.4): 3.61; (4)ACD/BCF (pH 5.5): 324.25; (5)ACD/BCF (pH 7.4): 324.25; (6)ACD/KOC (pH 5.5): 2182.2; (7)ACD/KOC (pH 7.4): 2182.2; (8)#H bond acceptors: 2; (9)#Freely Rotating Bonds: 3; (10)Polar Surface Area: 18.46 Å²; (11)Index of Refraction: 1.546; (12)Molar Refractivity: 64.2 cm³; (13)Molar Volume: 202.7 cm³; (14)Polarizability: 25.45×10-²⁴cm³; (15)Surface Tension: 35.2 dyne/cm; (16)Density: 1.056 g/cm³; (17)Flash Point: 137.4 °C; (18)Enthalpy of Vaporization: 55.87 kJ/mol; (19)Boiling Point: 338.4 °C at 760 mmHg; (20)Vapour Pressure: 0.000193 mmHg at 25°C.

Preparation: this chemical can be prepared by 1-bromo-4-methoxy-benzene. This reaction will need reagent nickel powder and solvent dimethylformamide. The reaction time is 20 hours with reaction temperature of 140 °C. The yield is about 68%.

Uses of 4,4'-Dimethoxybiphenyl: it can be used to produce 1-methoxy-4-(1,4,4-trimethoxy-cyclohexa-2,5-dienyl)-benzene. It will need reagent potassium hydroxide with reaction time of 8 hours. The yield is about 86%.

You can still convert the following datas into molecular structure:
(1)SMILES: O(c2ccc(c1ccc(OC)cc1)cc2)C
(2)InChI: InChI=1/C14H14O2/c1-15-13-7-3-11(4-8-13)12-5-9-14(16-2)10-6-12/h3-10H,1-2H3
(3)InChIKey: UIMPAOAAAYDUKQ-UHFFFAOYAB
(4)Std. InChI: InChI=1S/C14H14O2/c1-15-13-7-3-11(4-8-13)12-5-9-14(16-2)10-6-12/h3-10H,1-2H3
(5)Std. InChIKey: UIMPAOAAAYDUKQ-UHFFFAOYSA-N