3-O-benzyl-1,2-5,6-O-diisopropylidene-α-D-glucofuranose
O3-benzyl-D-glucose
Conditions | Yield |
---|---|
With sulfuric acid | |
With sulfuric acid | |
With hydrogenchloride | |
(acid hydrolysis); |
O3-benzyl-D-glucose
Conditions | Yield |
---|---|
With sulfuric acid |
benzyl chloride
O3-benzyl-D-glucose
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: potassium hydroxide 2: aqueous methanol. HCl View Scheme |
benzyl bromide
O3-benzyl-D-glucose
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 2: aqueous methanol. H2SO4 View Scheme |
methanol
O3-benzyl-D-glucose
methyl-(O3-benzyl-O2,O4,O6-trimethyl-ξ-D-glucopyranoside)
Conditions | Yield |
---|---|
With hydrogenchloride Behandeln mit Methyljodid unter Zusatz von Silberoxid; |
Conditions | Yield |
---|---|
With hydrogenchloride |
O3-benzyl-D-glucose
O2-Benzyl-arabinose
Conditions | Yield |
---|---|
With sodium periodate Behandeln des Reaktionsprodukts mit einem Kationen-Austauscher in H2O bei 100grad; O2-benzyl-D-arabinose; | |
With sodium periodate Behandeln des Reaktionsprodukts mit wss. NaOH; O2-benzyl-D-arabinose; |
O3-benzyl-D-glucose
O3-benzyl-D-glucose
acetic anhydride
1,2,4,6-tetra-O-acetyl-3-O-benzyl-β-D-glucopyranose
Conditions | Yield |
---|---|
With pyridine |
Conditions | Yield |
---|---|
With pyridine |
O3-benzyl-D-glucose
trityl chloride
O1,O2,O4-Triacetyl-O3-benzyl-O6-trityl-ξ-D-glucopyranose
Conditions | Yield |
---|---|
With pyridine Behandeln mit Acetanhydrid und Pyridin; |
O3-benzyl-D-glucose
benzoyl chloride
1,2,4,6-tetra-O-benzoyl-3-O-benzyl-β-D-glucopyranoside
Conditions | Yield |
---|---|
With pyridine |
O3-benzyl-D-glucose
phenylhydrazine
O3-benzyl-D-arabino-[2]hexosulose-bis-phenylhydrazone
4-phenylazobenzoyl chloride
O3-benzyl-D-glucose
Conditions | Yield |
---|---|
With pyridine |
O3-benzyl-D-glucose
methyl iodide
methyl-(O3-benzyl-O2,O4,O6-trimethyl-ξ-D-glucopyranoside)
Conditions | Yield |
---|---|
With silver(l) oxide |
O3-benzyl-D-glucose
2-deoxy-D-ribonic acid
Conditions | Yield |
---|---|
With sodium hydroxide; dihydrogen peroxide |
O3-benzyl-D-glucose
3-deoxyglucosone
Conditions | Yield |
---|---|
With sodium hydroxide |
O3-benzyl-D-glucose
A
D-arabino-3-deoxy-hexonic acid
Conditions | Yield |
---|---|
at 25℃; Rate constant; |
The D-Glucose,3-O-(phenylmethyl)-, with the CAS registry number 10230-17-8, is also known as 3-O-Benzyl-D-glucose. It belongs to the product category of Sugars, Carbohydrates & Glucosides. This chemical's molecular formula is C13H18O6 and molecular weight is 270.28. What's more, its systematic name is 3-O-benzyl-β-D-glucopyranose. It should be sealed and stored in a cool and dry place.
Physical properties of D-Glucose,3-O-(phenylmethyl)- are: (1)ACD/LogP: 0.36; (2)# of Rule of 5 Violations: 0; (3)ACD/BCF (pH 5.5): 1; (4)ACD/BCF (pH 7.4): 1; (5)ACD/KOC (pH 5.5): 8; (6)ACD/KOC (pH 7.4): 8; (7)#H bond acceptors: 6; (8)#H bond donors: 4; (9)#Freely Rotating Bonds: 8; (10)Polar Surface Area: 99.38 Å2; (11)Index of Refraction: 1.612; (12)Molar Refractivity: 66.634 cm3; (13)Molar Volume: 191.781 cm3; (14)Polarizability: 26.416×10-24cm3; (15)Surface Tension: 69.209 dyne/cm; (16)Density: 1.409 g/cm3; (17)Flash Point: 252.191 °C; (18)Enthalpy of Vaporization: 80.095 kJ/mol; (19)Boiling Point: 493.386 °C at 760 mmHg.
You can still convert the following datas into molecular structure:
(1)SMILES: O([C@H]1[C@H](O)[C@H](O[C@@H](O)[C@@H]1O)CO)Cc2ccccc2
(2)InChI: InChI=1S/C13H18O6/c14-6-9-10(15)12(11(16)13(17)19-9)18-7-8-4-2-1-3-5-8/h1-5,9-17H,6-7H2/t9-,10-,11-,12+,13-/m1/s1
(3)InChIKey: FYEFQDXXKFUMOJ-NJMOYASZSA-N
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