Diisopropyl peroxydicarbonate supplier

Name
Peroxydicarbonic acid,C,C'-bis(1-methylethyl) ester
EINECS 203-317-4
CAS No. 105-64-6
Density 1.138 g/cm³
Solubility 30.5mg/L at 20℃
Melting Point 12 ºC
Formula C8H14 O6
Boiling Point 208 °C at 760 mmHg
Molecular Weight 206.196
Flash Point 79.1 °C
Transport Information UN 2133/2134
Appearance Colorless, crystalline solid.
Safety Moderately toxic by ingestion and skin contact. A severe eye irritant. Very dangerous fire hazard. Dangerously unstable above 10°C. An impact- and heat-sensitive explosive. Solutions may spontaneously explode (the hazard increases with concentration). Storage in sealed containers may be dangerous. Explodes on contact with amines or potassium iodide. May explode on contact with organic matter. When heated to decomposition it emits acrid smoke and fumes. See also PEROXIDES, ORGANIC.
Risk Codes R36/37/38
Molecular Structure
Hazard Symbols Spontaneous decomposition at room temperature releases flammable and corrosive products; dangerous fire hazard; explodes on heating. Store in open containers at low temperature with adequate ventilation.
Synonyms Peroxydicarbonicacid, bis(1-methylethyl) ester (9CI); Peroxydicarbonic acid, diisopropyl ester(6CI,8CI); Bisisopropyl peroxydicarbonate; Di-iso-propyl peroxydicarbonate;Diisopropyl percarbonate; Diisopropyl perdicarbonate; Diisopropylperoxydicarbonate; Diisopropyl peroxydiformate; IPP; Isopropylperoxydicarbonate; Luperox IPP; Perkadox IPP; Peroyl IPP
PSA 71.06000
LogP 2.02460

Synthetic route

: 108-23-6
isopropyl chloroformate

: 105-64-6
diisopropyl peroxydicarbonate

Conditions

Conditions	Yield
With sodium hydroxide; dihydrogen peroxide	99%
With sodium hydroxide; dihydrogen peroxide In water at 15℃; Product distribution / selectivity;	94%
With dihydrogen peroxide; potassium hydroxide In water at 5 - 50℃; for 0.0766667h; Flow reactor;	74.7%
With sodium peroxide
With sodium hydroxide; dihydrogen peroxide

: 2564-83-2, 45842-10-2
2,2,6,6-Tetramethyl-1-piperidinyloxy free radical

: 105-64-6
diisopropyl peroxydicarbonate

: 105-06-6
1,4-Divinylbenzene

: 262616-04-6
2-(isopropyloxycarbonyloxy)-1-(2',2',6',6'-tetramethyl-1'-piperidinyloxy)-1-(4'-vinylphenyl)ethane

Conditions

Conditions	Yield
at 55℃; for 5h;	76.1%

...Expand

: 132969-46-1
4-acetoxy-2,2,6,6-tetramethylpiperidine-1-oxyl

: 105-64-6
diisopropyl peroxydicarbonate

: 105-06-6
1,4-Divinylbenzene

: 2-(isopropyloxycarbonyloxy)-1-(4'-acetoxy-2',2',6',6'-tetramethyl-1'-piperidinyloxy)-1-(4'-vinylphenyl)ethane

Conditions

Conditions	Yield
at 0 - 55℃; for 5h;	73%

...Expand

: 2564-83-2, 45842-10-2
2,2,6,6-Tetramethyl-1-piperidinyloxy free radical

: 105-64-6
diisopropyl peroxydicarbonate

: 108-57-6
1,3-divinylbenzene

: 2-(isopropyloxycarbonyloxy)-1-(2',2',6',6'-tetramethyl-1'-piperidinyloxy)-1-(3'-vinylphenyl)ethane

Conditions

Conditions	Yield
	70.5%

...Expand

: 3225-26-1
4-(benzyloxycarbonyl)-2,2,6,6-tetramethylpiperidine-1-oxyl

: 105-64-6
diisopropyl peroxydicarbonate

: 105-06-6
1,4-Divinylbenzene

: 2-(isopropyloxycarbonyloxy)-1-(4'-benzoyloxy-2',2',6',6'-tetramethyl-1'-piperidinyloxy)-1-(4'-vinylphenyl)ethane

Conditions

Conditions	Yield
at 0 - 55℃; for 5h;	62.1%

...Expand

: 105-64-6
diisopropyl peroxydicarbonate

: 142505-38-2
N-(4-chlorophenylmethylene)-2-methylthiobenzenamine

A: 6265-91-4
2-(4-chlorophenyl)benzothiazole

B: 104-88-1
4-chlorobenzaldehyde

C: 142505-43-9
(2-aminophenyl)thiomethyl isopropyl carbonate

Conditions

Conditions	Yield
In benzene at 60℃; for 5h;	A 36% B 48% C 54%

...Expand

: 105-64-6
diisopropyl peroxydicarbonate

: 105-06-6
1,4-Divinylbenzene

: 2406-25-9, 44871-19-4
di-tert-butyl nitroxide

: 2-(isopropyloxycarbonyloxy)-1-(di-t-butylnitroxy)-1-(4'-vinylphenyl)ethane

Conditions

Conditions	Yield
at 0 - 55℃; for 5h;	53.2%

...Expand

: 105-64-6
diisopropyl peroxydicarbonate

: 19860-20-9
benzylidene-(2-methylsulfanyl-phenyl)-amine

A: 883-93-2
2-Phenylbenzothiazole

B: 100-52-7
benzaldehyde

C: 142505-43-9
(2-aminophenyl)thiomethyl isopropyl carbonate

Conditions

Conditions	Yield
In benzene at 60℃; for 5h;	A 17% B 35% C 53%

...Expand

: 105-64-6
diisopropyl peroxydicarbonate

: 142505-40-6
N-(3-nitrophenylmethylene)-2-methylthiobenzenamine

A: 22868-33-3
2-(3-nitrophenyl)benzothiazole

B: 99-61-6
3-nitro-benzaldehyde

C: 142505-43-9
(2-aminophenyl)thiomethyl isopropyl carbonate

D: 142505-44-0
<(2-(3-nitrophenyl)methylenamino)phenyl>thiomethyl isopropyl carbonate

Conditions

Conditions	Yield
With 2,6-di-tert-butylphenol In benzene at 60℃; for 5h;	A 3% B 13% C 10% D 50%

...Expand

: 105-64-6
diisopropyl peroxydicarbonate

: 783-08-4
[4-(benzylideneamino)phenyl]methanol

A: 128220-34-8
methyl 6-methoxy-2-phenylquinoline-4-carboxylate

B: 85221-16-5
carbamic acid, (4-methoxyphenyl)-, 1-methylethyl ester

Conditions

Conditions	Yield
With acrylic acid methyl ester In benzene at 60℃; for 4h;	A 49% B 14%

...Expand

: 105-64-6
diisopropyl peroxydicarbonate

: 142505-39-3
N-(4-methoxyphenylmethylene)-2-methylthiobenzenamine

A: 6265-92-5
2-(4-methoxy-phenyl)-benzothiazole

B: 123-11-5
4-methoxy-benzaldehyde

C: 142505-43-9
(2-aminophenyl)thiomethyl isopropyl carbonate

Conditions

Conditions	Yield
In benzene at 60℃; for 5h;	A 28% B 48% C 39%

...Expand

: 105-64-6
diisopropyl peroxydicarbonate

: 123534-01-0
N-(phenylmethylene)-5-amino-2-methoxypyridine

: 1972-28-7
diethylazodicarboxylate

A: 4114-28-7
diethyl hydrazodicarboxylate

B: (6-Methoxy-pyridin-3-yl)-carbamic acid isopropyl ester

C: 7-Methoxy-3-phenyl-pyrido[3,2-e][1,2,4]triazine-1,2-dicarboxylic acid diethyl ester

Conditions

Conditions	Yield
In benzene at 60℃;	A n/a B n/a C 47%

...Expand

: 105-64-6
diisopropyl peroxydicarbonate

: 142505-41-7
N-(2-thienylmethylene)-2-methylthiobenzenamine

A: 98-03-3
thiophene-2-carbaldehyde

B: 34243-38-4
2-thiophen-2-yl-benzothiazole

C: 142505-43-9
(2-aminophenyl)thiomethyl isopropyl carbonate

Conditions

Conditions	Yield
In benzene at 60℃; for 5h;	A 40% B 13% C 45%

...Expand

: 45985-24-8, 2226-96-2
TEMPOL

: 105-64-6
diisopropyl peroxydicarbonate

: 105-06-6
1,4-Divinylbenzene

: 262616-12-6
2-(isopropyloxycarbonyloxy)-1-(4'-hydroxy-2',2',6',6'-tetramethyl-1'-piperidinyloxy)-1-(4'-vinylphenyl)ethane

Conditions

Conditions	Yield
at 0 - 55℃; for 5h;	41%

...Expand

: 105-64-6
diisopropyl peroxydicarbonate

: 783-08-4
[4-(benzylideneamino)phenyl]methanol

A: 85221-16-5
carbamic acid, (4-methoxyphenyl)-, 1-methylethyl ester

B: Benzoyl-(4-methoxy-phenyl)-carbamic acid isopropyl ester

C: 6-Methoxy-2,3,4-triphenyl-quinoline

Conditions

Conditions	Yield
With (E)-1,2-diphenyl-ethene In benzene at 60℃; for 4h;	A 15% B 40% C 20%

...Expand

: 105-64-6
diisopropyl peroxydicarbonate

: 142505-40-6
N-(3-nitrophenylmethylene)-2-methylthiobenzenamine

A: 22868-33-3
2-(3-nitrophenyl)benzothiazole

B: 99-61-6
3-nitro-benzaldehyde

C: 142505-43-9
(2-aminophenyl)thiomethyl isopropyl carbonate

Conditions

Conditions	Yield
In benzene at 60℃; for 5h;	A 38% B 40% C 35%

...Expand

: 105-64-6
diisopropyl peroxydicarbonate

: 1750-36-3, 33993-35-0, 538-51-2, 137431-97-1, 137432-04-3
(E)-N-benzylidenebenzenamine

A: 122-42-9
carbamic acid, phenyl-, 1-methylethyl ester

B: 57464-22-9
2-phenyl-quinoline-3,4-dicarbonitrile

Conditions

Conditions	Yield
With 1,2-Dicyanoethylene In benzene at 60℃; for 4h;	A 20% B 38%

...Expand

: 105-64-6
diisopropyl peroxydicarbonate

: 142505-42-8
N-(3-phenyl-2-propenylidene)-2-methylthiobenzenamine

A: 1483-30-3, 59066-61-4, 104505-71-7
2-styrylbenzothiazole

B: 142505-43-9
(2-aminophenyl)thiomethyl isopropyl carbonate

C: 104-55-2
3-phenyl-propenal

Conditions

Conditions	Yield
In benzene at 60℃; for 5h;	A 24% B 30% C 36%

...Expand

: 105-64-6
diisopropyl peroxydicarbonate

: 4-{[1-(4-Methoxy-phenyl)-meth-(E)-ylidene]-amino}-benzoic acid ethyl ester

: 1972-28-7
diethylazodicarboxylate

A: 4114-28-7
diethyl hydrazodicarboxylate

B: 4-Isopropoxycarbonylamino-benzoic acid ethyl ester

C: 3-(4-Methoxy-phenyl)-benzo[1,2,4]triazine-1,2,7-tricarboxylic acid triethyl ester

Conditions

Conditions	Yield
In benzene at 60℃;	A n/a B n/a C 36%

...Expand

: 105-64-6
diisopropyl peroxydicarbonate

: 4425-82-5
9-methylene-fluorene

polymer, Mn 1070 by SEC with oligostyrene as standard, Mn 1560 by SEC with oligo(dibenzofulvene) as standard; monomer(s): dibenzofulvene; 2,9-dimethyl-3,5,6,8-tetraoxadeca-4,7-dione: polymer, Mn 1070 by SEC with oligostyrene as standard, Mn 1560 by SEC with oligo(dibenzofulvene) as standard; monomer(s): dibenzofulvene; 2,9-dimethyl-3,5,6,8-tetraoxadeca-4,7-dione

Conditions

Conditions	Yield
In toluene at 40℃; for 24h;	33%

: 105-64-6
diisopropyl peroxydicarbonate

: N-(4-chlorophenylmethylene)-N'-methyl-N'-phenylbenzen-1,2-diamine

A: 2622-73-3
1-phenyl-2-(4-chlorophenyl)-1H-benzo[d]imidazole

B: 3-(4-chlorophenyl)-1-phenyl-1H-quinoxalin-2-one

C: 3-phenylbenzimidazolin-2-one-1-carboxylic acid 2-propyl ester

Conditions

Conditions	Yield
In benzene at 60℃; for 18h;	A 16% B 28% C 11%

...Expand

: 105-64-6
diisopropyl peroxydicarbonate

: 780-21-2
N-(4-chlorobenzylidene)aniline

A: 2239-92-1
Isopropyl N-4-chlorophenylcarbamate

B: methyl 6-chloro-2-phenylquinoline-4-carboxylate

Conditions

Conditions	Yield
With acrylic acid methyl ester In benzene at 60℃; for 4h;	A 27% B 16%

...Expand

: 105-64-6
diisopropyl peroxydicarbonate

: 138469-40-6
N-benzylidene-4-acetylaniline

A: 67648-20-8
isopropyl (4-acetylphenyl)carbamate

B: 6-Acetyl-2-phenyl-quinoline-4-carbonitrile

Conditions

Conditions	Yield
With acrylonitrile In benzene at 60℃; for 4h;	A 23% B 27%

...Expand

: 105-64-6
diisopropyl peroxydicarbonate

: N-(4-chlorophenylmethylene)-2-<4-(triphenylmethoxy)phenoxy>benzeneamine

A: 76-84-6
triphenylmethyl alcohol

B: 1141-35-1
2-(4-chlorophenyl)benzoxazole

C: 13594-78-0
triphenylmethyl iso-propyl ether

D: 2-propyl 4-(triphenylmethoxy)phenyl carbonate

Conditions

Conditions	Yield
In benzene at 60℃; for 24h; Further byproducts given;	A 23% B 23% C 6% D 6%

...Expand

: 105-64-6
diisopropyl peroxydicarbonate

: N-(4-chlorophenylmethylene)-2-<4-(triphenylmethoxy)phenoxy>benzeneamine

A: 76-84-6
triphenylmethyl alcohol

B: 1141-35-1
2-(4-chlorophenyl)benzoxazole

C: 13594-78-0
triphenylmethyl iso-propyl ether

D: 2-propyl 4-(triphenylmethoxy)phenyl carbonate

E: 11-(4-chlorophenyl)-2-(triphenylmethoxy)dibenz<1,4>oxazepine

Conditions

Conditions	Yield
In benzene at 60℃; for 24h; Product distribution; Mechanism;	A 23% B 23% C 6% D 6% E 3%

...Expand

: 105-64-6
diisopropyl peroxydicarbonate

: N-(4-methoxyphenylmethylene)-N'-methyl-N'-phenylbenzen-1,2-diamine

A: 3-phenylbenzimidazolin-2-one-1-carboxylic acid 2-propyl ester

B: 3-(4-methoxyphenyl)-1-phenyl-1H-quinoxalin-2-one

C: 2620-84-0
2-(4-methoxyphenyl)-1-phenyl-1H-benzo[d]imidazole

Conditions

Conditions	Yield
In benzene at 60℃; for 18h;	A 18% B 21% C 13%

...Expand

: 105-64-6
diisopropyl peroxydicarbonate

: 536-74-3
phenylacetylene

: (4-Methoxy-phenyl)-[2-methyl-2-phenyl-prop-(E)-ylidene]-amine

A: 65757-61-1
(1-isopropoxyethyl)benzene

B: 98-85-1, 13323-81-4
1-Phenylethanol

C: (Z)-3-(4-methoxyphenyl)-3-phenyl-2-propenenitrile

D: 1,1-Dimethyl-4-phenyl-1H-naphthalen-2-one

E: 7-Methoxy-2-(1-methyl-1-phenyl-ethyl)-4-phenyl-quinoline

F: 6-Methoxy-2-(1-methyl-1-phenyl-ethyl)-4-phenyl-quinoline

Conditions

Conditions	Yield
In benzene at 60℃; Product distribution; Mechanism; same produts were determined by GC;	A n/a B n/a C 21% D n/a E n/a F n/a

...Expand

: 105-64-6
diisopropyl peroxydicarbonate

: 1750-36-3, 33993-35-0, 538-51-2, 137431-97-1, 137432-04-3
(E)-N-benzylidenebenzenamine

A: 5892-72-8
Benzoyl-phenyl-carbamic acid isopropyl ester

B: 128220-30-4
2-phenyl-4-(trimethylsilyl)quinoline

Conditions

Conditions	Yield
With ethenyltrimethylsilane In benzene at 60℃; for 4h;	A 20% B 7%

...Expand

: 105-64-6
diisopropyl peroxydicarbonate

: N-(phenylmethylene)-N'-methyl-N'-phenylbenzen-1,2-diamine

A: 2622-67-5
1,2-diphenyl-1H-benzoimidazole

B: 3-phenylbenzimidazolin-2-one-1-carboxylic acid 2-propyl ester

C: 16194-28-8
1,3-diphenyl-1H-quinoxalin-2-one

Conditions

Conditions	Yield
In benzene at 60℃; for 30h;	A 20% B 14% C 14%

...Expand

: 105-64-6
diisopropyl peroxydicarbonate

: N-(4-methoxyphenylmethylene)-2-phenoxybenzeneamine

A: 611-94-9
4-Methoxybenzophenone

B: 123-11-5
4-methoxy-benzaldehyde

C: 124293-56-7
11-(4-methoxyphenyl)dibenz<1,4>oxazepine

D: 2-propyl N-(2-phenoxyphenyl)carbamate

Conditions

Conditions	Yield
In benzene at 60℃; for 6h; imine:reagent=1:4; Yield given. Further byproducts given;	A 18% B n/a C 17% D n/a

...Expand

Diisopropyl peroxydicarbonate Chemical Properties

Chemical Name: Diisopropyl peroxydicarbonate
IUPAC NAME: Propan-2-yl propan-2-yloxycarbonyloxy carbonate
CAS No.: 105-64-6
EINECS: 203-317-4
RTECS Class: Primary Irritant
Molecular Formula: C₈H₁₄O₆
Molecular Weight: 206.19 g/mol
Melting Point: 12°C
Density: 1.138 g/cm³
Flash Point: 79.1 °C
Boiling Point: 208 °C at 760 mmHg
Sensitive: Heat sensitive.
Following is the structure of Diisopropyl perdicarbonate (105-64-6):

The chemical synonymous of Diisopropyl perdicarbonate (105-64-6) are Diisopropyl peroxydicarbonate ; Bisisopropyl peroxydicarbonate ; Isopropyl peroxydicarbonate ; Isopropyl peroxycarbonate ; Peroxydicarbonic acid, diisopropyl ester ; Isopropylpercarbonate ; Diisopropylperoxydicarbonat ; Diisopropyl peroxydiformate

Diisopropyl peroxydicarbonate Toxicity Data With Reference

1.	eye-rbt 500 mg SEV	IHFCAY Industrial Hygiene Foundation of America, Chemical and Toxicological Series, Bulletin. 6 (1967),1.
2.	orl-rat LD50:2140 mg/kg	IHFCAY Industrial Hygiene Foundation of America, Chemical and Toxicological Series, Bulletin. 6 (1967),1.
3.	skn-rbt LD50:2025 mg/kg	BSPII* SPI Bulletin. (Society of the Plastics Industry, 250 Park Ave., New York, NY 10017) 1/75-19B .

Diisopropyl peroxydicarbonate Consensus Reports

Reported in EPA TSCA Inventory.

Diisopropyl peroxydicarbonate Safety Profile

Moderately toxic by ingestion and skin contact. A severe eye irritant. Very dangerous fire hazard. Dangerously unstable above 10°C. An impact- and heat-sensitive explosive. Solutions may spontaneously explode (the hazard increases with concentration). Storage in sealed containers may be dangerous. Explodes on contact with amines or potassium iodide. May explode on contact with organic matter. When heated to decomposition it emits acrid smoke and fumes. See also PEROXIDES, ORGANIC.
Attention:
1. Storage: Keep in a cool, dry, dark location in a tightly sealed container or cylinder. Keep away from incompatible materials, ignition sources and untrained individuals. Secure and label area. Protect containers/cylinders from physical damage.
2. Handling: All chemicals should be considered hazardous. Avoid direct physical contact. Use appropriate, approved safety equipment. Untrained individuals should not handle this chemical or its container. Handling should occur in a chemical fume hood.

Product Name

Peroxydicarbonic acid,C,C'-bis(1-methylethyl) ester

Synthetic route

Diisopropyl peroxydicarbonate Chemical Properties

Diisopropyl peroxydicarbonate Toxicity Data With Reference

Diisopropyl peroxydicarbonate Consensus Reports

Diisopropyl peroxydicarbonate Safety Profile

Related Products

Hot Products