Magnesium, iodomethyl- supplier

Name
METHYLMAGNESIUM IODIDE
EINECS 213-031-1
CAS No. 917-64-6
Article Data59
CAS DataBase
Density g/cm³
Solubility
Melting Point
Formula CH3 I Mg
Boiling Point °Cat760mmHg
Molecular Weight 166.244
Flash Point °C
Transport Information
Appearance
Safety Toxic. Explosive reaction with thiophosphoryl chloride or vanadium trichloride. A Grignard reagent. When heated to decomposition it emits toxic fumes of I⁻. See also IODIDES and MAGNESIUM COMPOUNDS.
Risk Codes 12-14/15-22-34-66-67
Molecular Structure
Hazard Symbols
Synonyms Methylmagnesiumiodide (6CI);Iodomethylmagnesium;methylmagnesium iodine;
PSA 0.00000
LogP 1.46950

Synthetic route

: 74-88-4
methyl iodide

: 917-64-6
methyl magnesium iodide

Conditions

Conditions	Yield
With magnesium In diethyl ether at 25℃; under 5171.62 Torr; Inert atmosphere; Flow reactor;	94%
With magnesium In diethyl ether
With magnesium In solid matrix at -258.2℃;

: 142-68-7
TETRAHYDROPYRANE

: 917-64-6
methyl magnesium iodide

Conditions

Conditions	Yield
Katalytischer Einfluss;

: 60-29-7
diethyl ether

: 74-88-4
methyl iodide

magnesium: magnesium

: 917-64-6
methyl magnesium iodide

...Expand

: 74-88-4
methyl iodide

magnesium: magnesium

: 917-64-6
methyl magnesium iodide

Conditions

Conditions	Yield
With diethyl ether

: 4363-93-3
quinoline-4-carboxaldehyde

: 917-64-6
methyl magnesium iodide

: 55908-34-4
1-Quinolin-4-yl-ethanol

Conditions

Conditions	Yield
In tetrahydrofuran; diethyl ether at -78 - 20℃; Nitrogen atmosphere;	100%
With diethyl ether

: 917-64-6
methyl magnesium iodide

: 7044-91-9
9,10-diformylanthracene

: 101789-38-2
9,10-bis(1-hydroxymethyl)anthracene

Conditions

Conditions	Yield
In tetrahydrofuran; diethyl ether at 40℃; for 8h;	100%
In tetrahydrofuran; diethyl ether at 20℃; for 18h;	100%

: 917-64-6
methyl magnesium iodide

: 5392-10-9
2-bromo-4,5-dimethoxybenzaldehyde

: 5293-52-7
6-bromo-3,4-dimethoxy-α-methylbenzyl alcohol

Conditions

Conditions	Yield
In tetrahydrofuran at 20℃; for 0.5h;	100%
In tetrahydrofuran; diethyl ether for 1h; Heating;	100%
In diethyl ether at 0 - 20℃; for 3h; Inert atmosphere;	90%
In diethyl ether at 20℃; for 0.5h;

: 917-64-6
methyl magnesium iodide

: 93860-79-8
7β-acetyl-4aβ-methyl-1aα-decahydrocyclopropanaphthalene

: 71962-31-7
(+)-7β-(1-hydroxy-1-methylethyl)-4aB-methyl-1aα-decahydrocyclopropanaphthalene

Conditions

Conditions	Yield
In diethyl ether for 2h; Ambient temperature;	100%

: 917-64-6
methyl magnesium iodide

: 24306-23-8
methyl 4-(4-methylphenyl)butanoate

: 22184-00-5
2-(methyl-5-(4-methylphenyl))-2-pentanol

Conditions

Conditions	Yield
In diethyl ether for 24h; Ambient temperature;	100%

: 917-64-6
methyl magnesium iodide

: 61203-53-0
2-iodo-4,5-dimethoxybenzaldehyde

: 4-iodo-5-(1-hydroxyethyl)veratrole

Conditions

Conditions	Yield
In tetrahydrofuran; diethyl ether for 1h; Heating;	100%

: 917-64-6
methyl magnesium iodide

: 3558-68-7
2,6-diphenylpyrylium perchlorate

: 55696-71-4
4-methyl-2,6-diphenyl-4H-pyran

Conditions

Conditions	Yield
With copper(l) iodide In diethyl ether at -15 - -10℃;	100%
In diethyl ether for 2h; Ambient temperature;	94%
In diethyl ether at 20℃; Inert atmosphere;	790 mg

: 917-64-6
methyl magnesium iodide

: 81805-47-2
6,9-dimethylnaphtho<1,8-bc>pyran-3(2H)-one

: 107686-35-1
3,6,9-trimethyl-2,3-dihydronaphtho<1,8-bc>pyran-3-ol

Conditions

Conditions	Yield
In diethyl ether for 1h; Ambient temperature;	100%
Yield given;

: 917-64-6
methyl magnesium iodide

: 86253-84-1
methyl 2-(2,6-dimethoxy-4-pentylphenyl)-3-methoxy-4-methylbenzoate

: 86253-85-2
6'-(1-hydroxy-1-methylethyl)-2,2',6-trimethoxy-3'-methyl-4-pentylbiphenyl

Conditions

Conditions	Yield
In tetrahydrofuran; diethyl ether for 1.16667h; Heating;	100%

: 917-64-6
methyl magnesium iodide

: 68781-89-5, 123930-74-5, 129569-63-7, 146727-49-3
exo-4,5-epoxy-endo-tricyclo[5.2.1.02,6]dec-8-en-3-one

: 135441-20-2
endo-4,5-epoxy-exo-5-methyl-endo-tricyclo<5.2.1.02,6>dec-8-en-exo-3-ol

Conditions

Conditions	Yield
In tetrahydrofuran at 0℃; for 72h;	100%

: 917-64-6
methyl magnesium iodide

: 139592-64-6
methyl 2-(2-bromophenyl)pent-4-enoate

: 139592-68-0
3-(o-bromophenyl)-2-methylhex-5-en-2-ol

Conditions

Conditions	Yield
In diethyl ether for 2h; Heating;	100%

: 917-64-6
methyl magnesium iodide

: 101472-25-7
(2R,4S)-4-Methyl-tricyclo[11.2.2.25,8]nonadeca-1(16),5(19),6,8(18),13(17),14-hexaene-2-carbaldehyde

: 101472-33-7
cis-1-(1-hydroxyethyl)-3-methyl<3.4>paracyclophane

Conditions

Conditions	Yield
In diethyl ether	100%

: 917-64-6
methyl magnesium iodide

: 145513-97-9
(S)-(+)-2-phenyl-N-(trifluoroacetyl)glycine methyl ester

: 145439-97-0
(S)-2,2,2-trifluoro-N-[2-hydroxy-2-methyl-1-phenylpropyl]acetamide

Conditions

Conditions	Yield
Stage #1: methyl magnesium iodide; (S)-(+)-2-phenyl-N-(trifluoroacetyl)glycine methyl ester In diethyl ether at 20℃; for 16h; Stage #2: With water; ammonium chloride In diethyl ether	100%
at 23℃; for 2.5h;	90%

: 917-64-6
methyl magnesium iodide

: 345976-80-9, 84021-69-2, 84048-79-3
9-(2-acetyl-1-naphthyl)fluorene

: 148648-28-6
9-<2-(1-hydroxy-1-methylethyl)-1-naphthyl>fluorene

Conditions

Conditions	Yield
In diethyl ether for 1.5h;	100%

: 917-64-6
methyl magnesium iodide

: 95512-49-5
1-acetyl-9,9-bis(methylthio)fluorene

: 65223-17-8
9,9-bis(methylthio)-α,α-dimethyl-1-fluorenemethanol

Conditions

Conditions	Yield
	100%

: 917-64-6
methyl magnesium iodide

: 4445-36-7
6H-benzo[c]thiochromen-6-one

: 87221-18-9
6-methyl-6H-dibenzo-thiopyran-6-ol

Conditions

Conditions	Yield
In tetrahydrofuran for 0.5h; Heating;	100%

: 917-64-6
methyl magnesium iodide

: 171-74-4
Spiroindole>

: 97961-94-9
2'-methylspiro

Conditions

Conditions	Yield
With copper(I) chloride In toluene at 120℃; for 2h;	100%

: 917-64-6
methyl magnesium iodide

: 167367-79-5
2-[(E)-3-(tert-Butyl-dimethyl-silanyloxy)-4,4-dimethyl-pent-1-enyl]-benzaldehyde

: 1-{2-[(E)-3-(tert-Butyl-dimethyl-silanyloxy)-4,4-dimethyl-pent-1-enyl]-phenyl}-ethanol

Conditions

Conditions	Yield
In diethyl ether	100%

: 917-64-6
methyl magnesium iodide

: 183549-74-8
3-(7,7-Dimethyl-1,4-dioxa-spiro[4.5]dec-6-yl)-propionaldehyde

: 183549-76-0
4-(7,7-Dimethyl-1,4-dioxa-spiro[4.5]dec-6-yl)-butan-2-ol

Conditions

Conditions	Yield
	100%

: 917-64-6
methyl magnesium iodide

: 828932-99-6
4-benzyloxy-5,6,8-trimethoxy-3-(prop-2'-enyl)naphthalene-2-carbaldehyde

: 828933-03-5
4-benzyloxy-2-(1''-hydroxyethyl)-5,6,8-trimethoxy-3-(prop-2'-enyl)-naphthalene

Conditions

Conditions	Yield
With methyl iodide In diethyl ether at 25℃; for 1h;	100%

: 847469-01-6
(R)-2-(2-(benzyloxy)-1-phenylethyl)isoindoline-1,3-dione

: 917-64-6
methyl magnesium iodide

: 847469-02-7
2-((R)-2-Benzyloxy-1-phenyl-ethyl)-3-hydroxy-3-methyl-2,3-dihydro-isoindol-1-one

Conditions

Conditions	Yield
In tetrahydrofuran; diethyl ether at -10℃; for 4h;	100%

: 917-64-6
methyl magnesium iodide

: 92862-87-8
(rac)-3-(4-methylphenyl)-3-methylcyclohexanone

: (1S,3R)-1,3-Dimethyl-3-p-tolyl-cyclohexanol

Conditions

Conditions	Yield
In diethyl ether at 0℃; for 0.5h;	100%

: 917-64-6
methyl magnesium iodide

: 26218-75-7
methyl 6-Bromopicolinate

: 638218-78-7
2-(6-bromopyridin-2- yl)propan-2-ol

Conditions

Conditions	Yield
In diethyl ether at 20℃; for 0.5h; Inert atmosphere;	100%
In diethyl ether at 20℃; for 0.0833333h; Inert atmosphere;	85%
In diethyl ether at 20℃; for 0.0833333h; Inert atmosphere;	85%

: 917-64-6
methyl magnesium iodide

: 218780-54-2
ethyl [1-(methylsulfonyl)piperidin-4-ylidenyl]cyanoacetate

: 218780-55-3
ethyl [4-methyl-1-(methylsulfonyl)piperidin-4-yl]cyanoacetate

Conditions

Conditions	Yield
With copper(l) chloride In tetrahydrofuran; diethyl ether at 0 - 20℃; for 3h;	100%

: 917-64-6
methyl magnesium iodide

: 42460-90-2
(S)-Pyrrolidine-2-carboxylic acid methyl ester; compound with trifluoro-acetic acid

: 672324-99-1
C2HF3O2*C7H15NO

Conditions

Conditions	Yield
In tetrahydrofuran; diethyl ether at 0 - 25℃; for 16h;	100%

: 917-64-6
methyl magnesium iodide

: 656257-69-1
2-bromo-N-methyl-N-(methyloxy)-4-pyridinecarboxamide

: 111043-06-2
1-(2-bromo-4-pyridinyl)ethanone

Conditions

Conditions	Yield
Stage #1: methyl magnesium iodide; 2-bromo-N-methyl-N-(methyloxy)-4-pyridinecarboxamide In tetrahydrofuran; diethyl ether at 0 - 5℃; for 2h; Stage #2: With water; ammonium chloride In tetrahydrofuran; diethyl ether	100%

: 917-64-6
methyl magnesium iodide

: 40320-60-3
N-benzhydryl 3-azetidinone

: 40320-63-6
1-benzhydryl-3-methylazetidin-3-ol

Conditions

Conditions	Yield
In tetrahydrofuran; diethyl ether at 0℃; for 1h;	100%
Stage #1: methyl magnesium iodide; N-benzhydryl 3-azetidinone In diethyl ether at 0℃; for 1h; Grignard Reaction; Stage #2: With methanol In diethyl ether; dichloromethane	68%

: 917-64-6
methyl magnesium iodide

: 12181-92-9, 71327-35-0, 36249-94-2
(+)-(1S)-tricarbonyl(2-methoxybenzaldehyde)chromium

: (1S)-o-CH3OC6H4CHOHCH3-(S)-Cr(CO)3

Conditions

Conditions	Yield
In tetrahydrofuran -78°C.;	100%

: 917-64-6
methyl magnesium iodide

: 210223-43-1
(2,2'-ethylenebis(N,N'-(triisopropylsilyl)anilido))ZrCl2

: (2,2'-ethylenebis(N,N'-(triisopropylsilyl)anilido))ZrMe2

Conditions

Conditions	Yield
In not given elem. anal.;	100%

: 917-64-6
methyl magnesium iodide

: 1204978-36-8
(R)-4-(6-chloro-4,5-dimethyl-pyridazin-3-yl)-2-methyl-3,4,5,6-tetrahydro-2H-[1,2']bipyrazinyl-5'-carboxylic acid methyl ester

: 2-[(R)-4-(6-Chloro-4,5-dimethyl-pyridazin-3-yl)-2-methyl-3,4,5,6-tetrahydro-2H-[1,2']bipyrazinyl-5'-yl]-propan-2-ol

Conditions

Conditions	Yield
Stage #1: methyl magnesium iodide; (R)-4-(6-chloro-4,5-dimethyl-pyridazin-3-yl)-2-methyl-3,4,5,6-tetrahydro-2H-[1,2']bipyrazinyl-5'-carboxylic acid methyl ester In tetrahydrofuran; diethyl ether at -78 - 0℃; Stage #2: With water; ammonium chloride In tetrahydrofuran; diethyl ether	100%

Magnesium, iodomethyl- Chemical Properties

The Molecular Structure of Magnesium, iodomethyl- (CAS NO.917-64-6):
Molecular Formula: CH₃IMg
Molecular Weight: 166.24
Density: 1.26 g/mL at 20 °C
Product Categories: Classes of Metal Compounds;Grignard Reagents;Grignard Reagents & Alkyl Metals;Mg (Magnesium) Compounds;Synthetic Organic Chemistry;Typical Metal Compounds;AlkylChemical Synthesis;Grignard Reagents;Organic Bases;Organometallic Reagents;Synthetic Reagents
ACD/LogP: 1.09
ACD/LogD (pH 5.5): 1.09
ACD/LogD (pH 7.4): 1.09
ACD/BCF (pH 5.5): 3.97
ACD/BCF (pH 7.4): 3.97
ACD/KOC (pH 5.5): 93.32
ACD/KOC (pH 7.4): 93.32
Enthalpy of Vaporization: 8.17 kJ/mol
Vapour Pressure: 205000 mmHg at 25°C

Magnesium, iodomethyl- Safety Profile

Toxic. Explosive reaction with thiophosphoryl chloride or vanadium trichloride. A Grignard reagent. When heated to decomposition it emits toxic fumes of I⁻. See also IODIDES and MAGNESIUM COMPOUNDS.
Hazard Codes: Highly F+, Corrosive C
Risk Statements: 12-14/15-22-34-66-67
R12:Extremely flammable
R14/15: Reacts violently with water, liberating extremely flammable gases
R22: Harmful if swallowed
R34: Causes burns
R66: Repeated exposure may cause skin dryness or cracking
R67: Vapours may cause drowsiness and dizziness
Safety Statements: 16-26-36/37/39-43-45-7/8
S16: Keep away from sources of ignition
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice|
S36/37/39: Wear suitable protective clothing, gloves and eye/face protection
S43: In case of fire use ... (there follows the type of fire-fighting equipment to be used.)
S45: In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
7/8: Keep container tightly closed and dry
RIDADR: UN 3399 4.3/PG 1
WGK Germany: 1
F: 1-3-10
F1: Sensitive to air and humidity
F3: Hygroscopic
F10: Keep under argon
HazardClass: 4.2
PackingGroup: I

Magnesium, iodomethyl- Specification

Magnesium, iodomethyl- (CAS NO.917-64-6) is also called as Iodomethylmagnesium ; Magnesium, iodomethyl- .

Product Name

METHYLMAGNESIUM IODIDE

Synthetic route

Magnesium, iodomethyl- Chemical Properties

Magnesium, iodomethyl- Safety Profile

Magnesium, iodomethyl- Specification

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