Product Name

  • Name

    Methyl oleate

  • EINECS 203-992-5
  • CAS No. 112-62-9
  • Article Data158
  • CAS DataBase
  • Density 0.873 g/cm3
  • Solubility Insoluble in water
  • Melting Point -20 °C
  • Formula C19H36O2
  • Boiling Point 351.4 °C at 760 mmHg
  • Molecular Weight 296.494
  • Flash Point 92.4 °C
  • Transport Information UN 1206 3/PG 2
  • Appearance colourless liquid
  • Safety 23-24/25-62-61-60-33-29-16-9
  • Risk Codes 11-38-50/53-65-67
  • Molecular Structure Molecular Structure of 112-62-9 (Methyl oleate)
  • Hazard Symbols FlammableF, HarmfulXn, DangerousN
  • Synonyms 9-Octadecenoicacid (Z)-, methyl ester;Oleic acid, methyl ester (6CI,8CI);(Z)-9-Octadecenoicacid methyl ester;ADJ 100;Agnique ME 181U;Agrique ME 181-1;CE 1897;Carolube 1885;Edenor Me 90/95V;Edenor MeTiO5;Emerest 2801;Emery 2301;Esterol 112;Exceparl M-OL;Methyl (Z)-9-octadecenoate;Methylcis-9-octadecenoate;Nissan Unister M 182A;Pastel M 181;Phytorob926-67;Priolube 1400;Priolube 1403;Radia 7060;Synative ES-ME-V;Unister M182A;Witconol 2301;cis-9-Octadecenoic acid, methyl ester;
  • PSA 26.30000
  • LogP 6.19690

Synthetic route

methanol
67-56-1

methanol

cis-Octadecenoic acid
112-80-1

cis-Octadecenoic acid

Methyl oleate
112-62-9

Methyl oleate

Conditions
ConditionsYield
With Mesoscopically Assembled SulfatedZirconia Nanoparticles at 49.84℃; for 8h; Catalytic behavior; Reagent/catalyst; Temperature;100%
With sulfuric acid; trimethyl orthoformate for 10h; Reflux;100%
With ammonium cerium(IV) nitrate at 20℃; for 2h;99%
methanol
67-56-1

methanol

trioleoylglycerol
122-32-7

trioleoylglycerol

Methyl oleate
112-62-9

Methyl oleate

Conditions
ConditionsYield
With methanesulfonic acid at 80℃;98%
With SO3H and NH2+ functional carbon-based solid acid at 100℃; under 760.051 Torr; for 8h; Catalytic behavior; Temperature; Sealed tube;95%
With sulfuric acid at 30℃; Kinetics;
stearolic acid methyl ester
1120-32-7

stearolic acid methyl ester

Methyl oleate
112-62-9

Methyl oleate

Conditions
ConditionsYield
With hydrogen; ethylenediamine In ethanol; water stereoselective reaction;97%
With ethanol; nickel Hydrogenation;
With sodium hypophosphite; Pd/Pb/C In tetrahydrofuran for 19.5833h; Ambient temperature;97 % Chromat.
With palladium diacetate; bis-(1,2-dimethylpropyl)borane 2.) THF, RT, overnight; Yield given. Multistep reaction;
cis-Octadecenoic acid
112-80-1

cis-Octadecenoic acid

trimethyl orthoformate
149-73-5

trimethyl orthoformate

Methyl oleate
112-62-9

Methyl oleate

Conditions
ConditionsYield
With sulfuric acid In methanol at 20℃;96%
cis-Octadecenoic acid
112-80-1

cis-Octadecenoic acid

diazomethyl-trimethyl-silane
18107-18-1

diazomethyl-trimethyl-silane

Methyl oleate
112-62-9

Methyl oleate

Conditions
ConditionsYield
In methanol; diethyl ether; toluene at 20℃; for 0.5h;96%
In methanol; diethyl ether; toluene at 20℃; for 0.5h;
In hexane at 30℃; for 0.166667h;
O-methyl-N-cyclohexyl-N\-methylpolystyrene isourea

O-methyl-N-cyclohexyl-N\-methylpolystyrene isourea

cis-Octadecenoic acid
112-80-1

cis-Octadecenoic acid

Methyl oleate
112-62-9

Methyl oleate

Conditions
ConditionsYield
In acetonitrile at 120℃; for 0.0833333h; microwave irradiation;96%
octadec-9-enoic acid N',N'-dimethyl-hydrazide
914805-17-7

octadec-9-enoic acid N',N'-dimethyl-hydrazide

methanol
67-56-1

methanol

Methyl oleate
112-62-9

Methyl oleate

Conditions
ConditionsYield
With Dowex 50WX8-100 at 70℃; for 24h;94%
benzaldehyde dimethyl acetal
1125-88-8

benzaldehyde dimethyl acetal

Methyl oleate
112-62-9

Methyl oleate

Conditions
ConditionsYield
With boron trifluoride diethyl etherate In chloroform at 61℃; for 4h; Acylation;93%
epoxidized methyl oleate
2566-91-8

epoxidized methyl oleate

Methyl oleate
112-62-9

Methyl oleate

Conditions
ConditionsYield
With aluminium(III) iodide In acetonitrile; benzene for 1h;92%
C27H52N2O3
914805-23-5

C27H52N2O3

methanol
67-56-1

methanol

Methyl oleate
112-62-9

Methyl oleate

Conditions
ConditionsYield
With Dowex 50WX8-100 at 20℃; for 12h;92%
sodium methylate
124-41-4

sodium methylate

1-[(Z)-octadec-9-enoyl]-1,3-dicyclohexylurea
155235-91-9

1-[(Z)-octadec-9-enoyl]-1,3-dicyclohexylurea

A

Methyl oleate
112-62-9

Methyl oleate

B

1,3-Dicyclohexylurea
2387-23-7

1,3-Dicyclohexylurea

Conditions
ConditionsYield
In methanol at 0℃; for 3h; Product distribution; different acylureas, reagent, solvent and reaction temperature;A 68%
B 90%
methanol
67-56-1

methanol

trioleoylglycerol
122-32-7

trioleoylglycerol

A

Methyl oleate
112-62-9

Methyl oleate

B

glycerol
56-81-5

glycerol

Conditions
ConditionsYield
With sulfonated carbonized β-cyclodextrin CD-3 at 80℃; under 15001.5 Torr; for 12h; Catalytic behavior; Pressure; Autoclave;A 90%
B n/a
vanadia at 150℃; for 24h; Product distribution / selectivity;A 88%
B 32%
With manganese titanate at 200℃; under 37503.8 Torr; for 24h; Mechanism; Reagent/catalyst; Temperature; Flow reactor;A 87%
B 49%
methanol
67-56-1

methanol

high oleic sunflower oil

high oleic sunflower oil

Methyl oleate
112-62-9

Methyl oleate

Conditions
ConditionsYield
86%
cis-Octadecenoic acid
112-80-1

cis-Octadecenoic acid

poly(styrene-co-divinylbenzene)-supported methyl sulfonate, loading rate of SO3Me: ca. 4.0 mmol/g

poly(styrene-co-divinylbenzene)-supported methyl sulfonate, loading rate of SO3Me: ca. 4.0 mmol/g

Methyl oleate
112-62-9

Methyl oleate

Conditions
ConditionsYield
With potassium carbonate In acetonitrile for 21h; Heating;72%
methanol
67-56-1

methanol

C21H42N2O
36460-68-1

C21H42N2O

Methyl oleate
112-62-9

Methyl oleate

Conditions
ConditionsYield
With Dowex 50WX8-100 at 70℃; for 24h;70%
methanol
67-56-1

methanol

cyanolipid N-IIb
88400-46-8

cyanolipid N-IIb

Methyl oleate
112-62-9

Methyl oleate

Conditions
ConditionsYield
With lithium hydroxide for 48h; Heating; characterization;65%
cis-Octadecenoic acid
112-80-1

cis-Octadecenoic acid

Methyl oleate
112-62-9

Methyl oleate

Conditions
ConditionsYield
With diethyl ether
In diethyl ether at 5 - 15℃;78 mg
In diethyl ether for 2h; Ambient temperature;29.6 g
cis-Octadecenoic acid
112-80-1

cis-Octadecenoic acid

tetramethylammonium
51-92-3

tetramethylammonium

Methyl oleate
112-62-9

Methyl oleate

Conditions
ConditionsYield
With methanol dann Erhitzen des entstandenen Tetramethylammoniumoleats;
Methyl stearate
112-61-8

Methyl stearate

Methyl oleate
112-62-9

Methyl oleate

Conditions
ConditionsYield
With ethene; nickel at 220℃;
methanol
67-56-1

methanol

cis-Octadecenoic acid
112-80-1

cis-Octadecenoic acid

toluene-4-sulfonic acid
104-15-4

toluene-4-sulfonic acid

Methyl oleate
112-62-9

Methyl oleate

Conditions
ConditionsYield
at 30℃; Rate constant;
at 40℃; Rate constant;
nonan-1-al
124-19-6

nonan-1-al

methyl 9-chlorononanoate
22457-33-6

methyl 9-chlorononanoate

Methyl oleate
112-62-9

Methyl oleate

Conditions
ConditionsYield
(i) NaI, MeCOEt, (ii) Ph3P, (iii) /BRN= 1236701/, NaOMe, DMF; Multistep reaction;
methanol
67-56-1

methanol

cis-Octadecenoic acid
112-80-1

cis-Octadecenoic acid

A

Methyl oleate
112-62-9

Methyl oleate

B

methyl 10-oxooctadecanoate
870-10-0

methyl 10-oxooctadecanoate

C

10-hydroxy stearic acid methyl ester
423184-25-2

10-hydroxy stearic acid methyl ester

D

methyl (S)-10-hydroxyoctadecanoate
423184-30-9

methyl (S)-10-hydroxyoctadecanoate

Conditions
ConditionsYield
With hydrogenchloride 1.) 30 deg C, 3 d, Corynebacterium sp. S-401, 2.) r. t., 2 d; Multistep reaction;
methanol
67-56-1

methanol

cyanolipid N-IId

cyanolipid N-IId

Methyl oleate
112-62-9

Methyl oleate

Conditions
ConditionsYield
With lithium hydroxide for 48h; Heating; characterization;
methanol
67-56-1

methanol

cyanolipid N-IIc

cyanolipid N-IIc

Methyl oleate
112-62-9

Methyl oleate

Conditions
ConditionsYield
With lithium hydroxide for 48h; Heating; characterization;
cis-Octadecenoic acid
112-80-1

cis-Octadecenoic acid

Methyl oleate
112-62-9

Methyl oleate

Conditions
ConditionsYield
In methanol; benzene for 0.5h; Ambient temperature; Yield given;
sulfuric acid In methanol
Multi-step reaction with 2 steps
1: chloroform-d1 / Inert atmosphere; Cooling
2: chloroform-d1 / Inert atmosphere; Cooling
View Scheme
With toluene-4-sulfonic acid In methanol at 70℃; for 2h; Temperature;
With methanol In water at 24.84℃; for 4h; Kinetics; Temperature;
methyl (9E)-octadec-9-enoate
2462-84-2

methyl (9E)-octadec-9-enoate

Methyl oleate
112-62-9

Methyl oleate

Conditions
ConditionsYield
zinc sulfide In methanol at 25℃; Quantum yield; Product distribution; Irradiation; other catalysts, other solvents;
In pentane for 0.333333h; Product distribution; Kinetics; Irradiation; at 185 nm, photostationary state at 185, 214, and 229 nm;76 % Turnov.
With 2-hydroxyethanethiol; dinitrogen monoxide; tert-butyl alcohol at 22℃; Product distribution; Equilibrium constant; Kinetics; Further Variations:; absorbed dose of radiation; γ-Irradiation;
methyl (9E)-octadec-9-enoate
2462-84-2

methyl (9E)-octadec-9-enoate

A

Methyl oleate
112-62-9

Methyl oleate

B

Methyl stearate
112-61-8

Methyl stearate

Conditions
ConditionsYield
With hydrogen; nickel(II) acetylacetonate; triethylaluminum In cyclohexane at 25℃; under 982.6 Torr; Thermodynamic data; ΔE(excit.);
Methyl linoleate
112-63-0

Methyl linoleate

A

Methyl oleate
112-62-9

Methyl oleate

B

methyl (9E)-octadec-9-enoate
2462-84-2

methyl (9E)-octadec-9-enoate

C

Methyl stearate
112-61-8

Methyl stearate

D

cis-12-octadecenoic acid methyl ester
2733-86-0

cis-12-octadecenoic acid methyl ester

Conditions
ConditionsYield
With hydrogen; bis(acetylacetonate)nickel(II); triethylaluminum In cyclohexane at 25℃; under 1197.1 Torr; Product distribution; Rate constant; other fatty acid esters, var. temp. and pressures;
methyl linoleate
18287-20-2

methyl linoleate

A

methyl petroselinate
2777-58-4

methyl petroselinate

B

methyl 6(E)-octadecenoate
14620-36-1

methyl 6(E)-octadecenoate

C

Methyl oleate
112-62-9

Methyl oleate

D

methyl (9E)-octadec-9-enoate
2462-84-2

methyl (9E)-octadec-9-enoate

E

Methyl stearate
112-61-8

Methyl stearate

F

trans-methyl 8-octadecenoate
26528-50-7

trans-methyl 8-octadecenoate

Conditions
ConditionsYield
With hydrogen; palladium In ethanol at 24℃; Product distribution; potencial controlled catalytic hydrogenation of other unsaturated fatty acid esters, effects of potential, electrolytes, solvents, double bond distribution;
Methyl oleate
112-62-9

Methyl oleate

A

nonan-1-al
124-19-6

nonan-1-al

B

methyl ester of azelaic acid aldehyde
1931-63-1

methyl ester of azelaic acid aldehyde

Conditions
ConditionsYield
Stage #1: Methyl oleate With ozone In dichloromethane at -78℃;
Stage #2: With triphenylphosphine In dichloromethane at -78 - 23℃; for 18h;
A 100%
B 100%
With N-methyl-2-indolinone; ozone at 0℃;A 74%
B 96%
With ozone; acetic acid; zinc 1.) MeOH, CH2Cl2, -78 deg C, 2.) MeOH, CH2Cl2, 30 min; Multistep reaction. Yields of byproduct given;
Methyl oleate
112-62-9

Methyl oleate

methyl 9,10-dibromostearate
25456-04-6

methyl 9,10-dibromostearate

Conditions
ConditionsYield
With bromine In chloroform100%
With bromine
With bromine at 0℃;
With bromine In diethyl ether for 0.25h;
With bromine In tetrachloromethane at 0℃;
Methyl oleate
112-62-9

Methyl oleate

epoxidized methyl oleate
2566-91-8

epoxidized methyl oleate

Conditions
ConditionsYield
With 3-chloro-benzenecarboperoxoic acid In dichloromethane for 12h;100%
With tert.-butylhydroperoxide; [MoO3(2,2'-bipyridine)] In 1,2-dichloro-ethane at 75℃; for 24h; Catalytic behavior; Reagent/catalyst; Solvent; Time;99%
With formic acid; dihydrogen peroxide at 20℃;97%
Methyl oleate
112-62-9

Methyl oleate

erythro-9,10-dihydroxyoctadecanoic acid methyl ester
1115-01-1, 3639-30-3, 3639-31-4, 38172-86-0, 41757-66-8, 79815-14-8, 95975-76-1

erythro-9,10-dihydroxyoctadecanoic acid methyl ester

Conditions
ConditionsYield
With osmium(VIII) oxide; 4-methylmorpholine N-oxide In water; acetone; tert-butyl alcohol at 20℃; for 24h;100%
With osmium(VIII) oxide; water; potassium carbonate; potassium hexacyanoferrate(III) In tert-butyl alcohol99%
With cethyltrimethylammonium permanganate In dichloromethane at 20℃; for 100h;37%
Methyl oleate
112-62-9

Methyl oleate

2,4,4-trimethyl-1-pentyl hypophosphorous acid
144900-28-7

2,4,4-trimethyl-1-pentyl hypophosphorous acid

10-[hydroxy-(2,4,4-trimethylpentyl)phosphinoyl]octadecanoic acid methyl ester
1189189-07-8

10-[hydroxy-(2,4,4-trimethylpentyl)phosphinoyl]octadecanoic acid methyl ester

Conditions
ConditionsYield
With di-tert-amyl peroxide at 140℃; for 6h; Inert atmosphere;100%
Methyl oleate
112-62-9

Methyl oleate

9-{hydroxy-[1-(7-methoxycarbonylheptyl)decyl]phosphinoyl}octadecanoic acid methyl ester

9-{hydroxy-[1-(7-methoxycarbonylheptyl)decyl]phosphinoyl}octadecanoic acid methyl ester

Conditions
ConditionsYield
With di-tert-amyl peroxide; hypophosphorous acid at 140℃; for 5h; Inert atmosphere;100%
diiodomethane
75-11-6

diiodomethane

Methyl oleate
112-62-9

Methyl oleate

9,10-methyleneoctadecanoic acid methyl ester
10152-62-2

9,10-methyleneoctadecanoic acid methyl ester

Conditions
ConditionsYield
Stage #1: Methyl oleate With diethylzinc In hexane; dichloromethane at -5 - 0℃; for 1h; Inert atmosphere;
Stage #2: diiodomethane In hexane; dichloromethane at 20℃; Inert atmosphere;
100%
Methyl oleate
112-62-9

Methyl oleate

cholesterol
57-88-5

cholesterol

cholesterol oleate
303-43-5

cholesterol oleate

Conditions
ConditionsYield
With iron(III)-acetylacetonate In n-heptane at 105℃; for 22h; Inert atmosphere;99%
In hexane at 30℃; for 72h; Corynebacterium sp. S-401;16%
With Candida rugosa lipase at 40℃; under 15.0012 - 30.0024 Torr; for 48h;
With Lipozyme IM at 80℃; under 15.0012 - 30.0024 Torr; for 48h;
Methyl oleate
112-62-9

Methyl oleate

methyl 9,10-dihydroxy stearate
1115-01-1

methyl 9,10-dihydroxy stearate

Conditions
ConditionsYield
With phosphotungstic acid; dihydrogen peroxide In water at 80℃; pH=Ca. 1; Catalytic behavior; Kinetics; Temperature; Reagent/catalyst; chemoselective reaction;99%
With dihydrogen peroxide; magnesium sulfate; methyltrioxorhenium(VII) In tert-butyl alcohol at 25℃; for 24h;92%
With osmium(VIII) oxide; 4-methylmorpholine N-oxide In tetrahydrofuran; water at 20℃; for 2h;85%
Conditions
ConditionsYield
With formic acid; dihydrogen peroxide In water at 0 - 23℃; for 24h;98.8%
With tris(2,4-pentanedionato)ruthenium(III); Pyridine-2,6-dicarboxylic acid; dihydrogen peroxide In water; acetonitrile at 25℃; for 4h;97%
With tert.-butylhydroperoxide In decane for 2h; Reflux;97%
Methyl oleate
112-62-9

Methyl oleate

methyl (Z)-2-((Z)-hexadec-7-en-1-yl)-3-oxoicos-11-enoate
66587-44-8

methyl (Z)-2-((Z)-hexadec-7-en-1-yl)-3-oxoicos-11-enoate

Conditions
ConditionsYield
With tributyl-amine; titanium tetrachloride In toluene at -5 - 0℃; for 1h; Inert atmosphere;98%
With tributyl-amine; titanium tetrachloride In toluene at 0 - 5℃; for 1h; Inert atmosphere;93%
With sodium hydride; xylene
With sodium hydride In 1,2-dimethoxyethane
Methyl oleate
112-62-9

Methyl oleate

oleoyl alcohol
143-28-2

oleoyl alcohol

Conditions
ConditionsYield
With isopropyl alcohol In hexane at 0℃; for 0.0833333h; Bouveault-Blanc Reduction; Inert atmosphere;98%
With C32H36ClNO2P2Ru; potassium tert-butylate; hydrogen In tetrahydrofuran at 120℃; under 38002.6 Torr; for 20h; Autoclave; Green chemistry;98%
With lithium aluminium tetrahydride In tetrahydrofuran at 0 - 20℃; for 24h;97%
Methyl oleate
112-62-9

Methyl oleate

7-methyl-1-octanol
2430-22-0

7-methyl-1-octanol

9,10-epoxystearic acid isononanyl ester

9,10-epoxystearic acid isononanyl ester

Conditions
ConditionsYield
With dihydrogen peroxide In water at 50℃; for 24h; Inert atmosphere; Enzymatic reaction;98%
Methyl oleate
112-62-9

Methyl oleate

methyl ester of azelaic acid aldehyde
1931-63-1

methyl ester of azelaic acid aldehyde

Conditions
ConditionsYield
Stage #1: Methyl oleate With ozone In dichloromethane
Stage #2: With dimethylsulfide In dichloromethane
97%
With oxygen; ozone; 4-methylmorpholine N-oxide In dichloromethane at 0℃;96%
With oxygen; ozone; 4-methylmorpholine N-oxide In dichloromethane at -78 - 20℃; for 2.41667h;93%
Methyl oleate
112-62-9

Methyl oleate

phenylphosphinic acid
1779-48-2

phenylphosphinic acid

10-(hydroxyphenylphosphinoyl)octadecanoic acid methyl ester
1189188-92-8

10-(hydroxyphenylphosphinoyl)octadecanoic acid methyl ester

Conditions
ConditionsYield
With di-tert-amyl peroxide at 140℃; for 5h; Inert atmosphere;97%
diiodomethane
75-11-6

diiodomethane

Methyl oleate
112-62-9

Methyl oleate

cis-9,10-methyleneoctadecanoic acid mthyl ester
3971-54-8, 5135-07-9, 10152-62-2, 79795-84-9

cis-9,10-methyleneoctadecanoic acid mthyl ester

Conditions
ConditionsYield
Stage #1: diiodomethane With 2,4,6-Cl3C6H2OZnEt In dichloromethane at -40℃;
Stage #2: Methyl oleate In dichloromethane at 20℃;
96%
With copper In 1,2-dimethoxyethane at 80 - 90℃; for 4h; Irradiation; ultrasound;20%
Stage #1: Methyl oleate With diethylzinc In hexane; dichloromethane at -5 - 0℃;
Stage #2: diiodomethane In hexane; dichloromethane at 20℃;
With diethylzinc In dichloromethane
Methyl oleate
112-62-9

Methyl oleate

N,N'-bis(2-hydroxyethyl)ethylene diamine
4439-20-7

N,N'-bis(2-hydroxyethyl)ethylene diamine

N,N'-bis(oleoyl)di(hydroxyethyl)ethylenediamine

N,N'-bis(oleoyl)di(hydroxyethyl)ethylenediamine

Conditions
ConditionsYield
With potassium hydroxide at 180 - 185℃; for 6h; Time;96%
methanol
67-56-1

methanol

Methyl oleate
112-62-9

Methyl oleate

carbon monoxide
201230-82-2

carbon monoxide

dimethyl 1,19-nonadecandioate
23130-41-8

dimethyl 1,19-nonadecandioate

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); methanesulfonic acid; 1,2-bis[di(t-butyl)phosphinomethyl]benzene at 80℃; under 22502.3 Torr; for 22h; Autoclave; Inert atmosphere;95%
With methanesulfonic acid; palladium diacetate; 1,2-bis[di(t-butyl)phosphinomethyl]benzene at 90℃; under 15001.5 Torr; for 22h;86%
With 1,2-bis{(di-tert-butylphosphino)methyl}benzene palladium ditriflate at 90℃; under 15001.5 Torr; for 90h; Glovebox; Schlenk technique; Inert atmosphere;85%
1,1,1,4,4,4-hexafluoro-2(Z)-butene
692-49-9

1,1,1,4,4,4-hexafluoro-2(Z)-butene

Methyl oleate
112-62-9

Methyl oleate

A

(Z)-methyl 11,11,11-trifluoro-9-undecenoate

(Z)-methyl 11,11,11-trifluoro-9-undecenoate

B

(Z)-1,1,1-trifluoro-2-undecene
133512-62-6

(Z)-1,1,1-trifluoro-2-undecene

Conditions
ConditionsYield
With C47H71ClMoN2O In benzene at 22℃; for 4h; Glovebox; Inert atmosphere; stereoselective reaction;A 95%
B 67%
With C52H73ClMoN2O In benzene at 22℃; for 0.25h; Inert atmosphere; Glovebox;A 95%
B 67%
Methyl oleate
112-62-9

Methyl oleate

1-amino-3-(dimethylamino)propane
109-55-7

1-amino-3-(dimethylamino)propane

(9Z)-N-[3-(dimethylamino)propyl]octadec-9-enamide
109-28-4

(9Z)-N-[3-(dimethylamino)propyl]octadec-9-enamide

Conditions
ConditionsYield
With zeolite at 115 - 120℃; for 12h; Dean-Stark;95%
Methyl oleate
112-62-9

Methyl oleate

(Z)-octadec-9-en-1,1-d2-1-ol

(Z)-octadec-9-en-1,1-d2-1-ol

Conditions
ConditionsYield
With ethyl [2]alcohol; sodium In hexane; mineral oil at 0 - 20℃; for 0.166667h; Bouveault-Blanc Reduction; Inert atmosphere;95%
Methyl oleate
112-62-9

Methyl oleate

stearic acid hydrazide
4130-54-5

stearic acid hydrazide

Conditions
ConditionsYield
With hydrazine hydrate94%
With hydrazine hydrate In ethanol for 8h; Reflux;82%
With ethanol; water; hydrazine hydrate
D-sorbitol
50-70-4

D-sorbitol

Methyl oleate
112-62-9

Methyl oleate

sodium Oleate
143-19-1

sodium Oleate

sorbitol hexaoleate

sorbitol hexaoleate

Conditions
ConditionsYield
With potassium carbonate at 144℃; under 0.1 - 10 Torr; for 6.65h; var. temp., reaction time, mole ratios of edducts;94%
With potassium carbonate at 144℃; under 0.1 - 10 Torr; for 6.65h;94%

Methyl oleate Chemical Properties

Product Name:(Z)-9-Octadecenoic acid methyl ester(112-62-9)
CAS No:112-62-9
MF: C19H36O2
MW: 296.49
mp : -20 °C 
bp : 218 °C
density : 0.874 g/mL at 20 °C(lit.)
vapor pressure  :10 mm Hg ( 205 °C)
refractive index : n20/D 1.452(lit.)
Fp : >230 °F
storage temp. : -20°C
Appearance:Clear to amber liquid.
Solubility in water:Insoluble  
Synonyms of (Z)-9-Octadecenoic acid methyl ester(112-62-9): cis-oleic acid,methyl ester`s Synonyms: C18:1 (CIS-9) METHYL ESTER;EMERY OLEIC ACID ESTER;DELTA 9 CIS OCTADECENOIC ACID METHYL ESTER;CIS-OLEIC ACID METHYL ESTER;CIS-9-OCTADECENOIC ACID METHYL ESTER;METHYL OLEATE;METHYLOCTADECENOATE;METHYL (Z)-9-OCTADECENOATE
Molecular Structure of (Z)-9-Octadecenoic acid methyl ester(112-62-9):

Methyl oleate Uses

Intermediate for detergents, emulsifiers, wetting agents, stabilizers, textiles treatment, plasticizers for duplicating inks, rubbers, waxes, chromatographic reference standard

Methyl oleate Toxicity Data With Reference

RTECS : RK0895000
RTECS Class:Tumorigen

Ingestion:  cis-oleic acid,methyl ester may cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
Inhalation: cis-oleic acid,methyl ester may cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
cis-oleic acid,methyl ester may also cause skin and eye irritation.

Methyl oleate Consensus Reports

Stability:Stable at room temperature in closed containers under normal storage and handling conditions.

First aid measures:
Ingestion: If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation: Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Skin: Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.

Storage: Store in a cool, dry, well-ventilated area away from incompatible substances. Keep containers tightly closed.
Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.

Methyl oleate Safety Profile

Hazard Codes : F,Xn,N
Risk Statements :11-38-50/53-65-67
Safety Statements : 23-24/25-62-61-60-33-29-16-9
RIDADR : UN 1206 3/PG 2
WGK Germany : 1
F : 8-23

Methyl oleate Specification

cis-oleic acid,methyl ester`s Categories: Biochemistry;Fatty Acid Esters (Plasticizer);Functional Materials;Higher Fatty Acids & Higher Alcohols;Plasticizer;Unsaturated Higher Fatty Acid Esters;Analytical Chemistry;Fatty Acid Methyl Esters (GC Standard);Standard Materials for GC

Personal Protection: Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.

Fire Fighting:Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. To extinguish fire use water spray, dry chemical, carbon dioxide, or appropriate foam.

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