Conditions | Yield |
---|---|
In tetrahydrofuran; benzene at -20 - 20℃; for 1.5h; Inert atmosphere; Schlenk technique; | 99% |
Conditions | Yield |
---|---|
In tetrahydrofuran at 0℃; for 5h; Inert atmosphere; | 99% |
Conditions | Yield |
---|---|
In tetrahydrofuran at 0℃; for 1h; Inert atmosphere; | 99% |
the dicamphorsulfonate of (1S,2S,4S,5S)-2,5-diphenylcyclohexane-1,4-diol
sodium cyclopentadienylide
Conditions | Yield |
---|---|
With sodium hydride In 1,2-dimethoxyethane 1.) 0 deg C, 2.5 h; 2.) reflux, 4 h; | 98% |
n-butyllithium
bis(trimethylsilyl)aminodichloroborane
sodium cyclopentadienylide
Conditions | Yield |
---|---|
In hexane N2 atmosphere, addn. of soln. of borane to suspension of sodium cyclopentadiene at room temp., stirring (room temp., 2 h), addn. of BuLi at 0°C, warming to room temp., stirring (1 h); removement of volatiles (high vacuum), extn. (hexane, overnight), filtration, drying (vacuum); | 98% |
Conditions | Yield |
---|---|
In 2-methyltetrahydrofuran at 0℃; for 8h; Inert atmosphere; | 98% |
Conditions | Yield |
---|---|
In tetrahydrofuran at 0℃; for 3h; Inert atmosphere; | 98% |
sodium cyclopentadienylide
Conditions | Yield |
---|---|
Stage #1: phenylmenthyl methanesulfonate; sodium cyclopentadienylide In tetrahydrofuran for 12h; Heating; Stage #2: With n-butyllithium In hexane; pentane at 20℃; for 12h; Further stages.; | 97% |
Conditions | Yield |
---|---|
In tetrahydrofuran at 0℃; for 4h; Inert atmosphere; | 97% |
zirconium tetrachloride bis(tetrahydrofuran) complex
bis(trimethylsilyl)aminodichloroborane
sodium cyclopentadienylide
[((CH3)3Si)2NB(η(5)-cyclopentadienyl)2]ZrCl2
Conditions | Yield |
---|---|
With BuLi In diethyl ether; hexane N2 atm., (borane, NaCp (hexane, 0°C), warming to room temp., stirring (2 h), filtration, washing (Et2O), BuLi (hexane, 0°C), warming to room temp., stirring (16 h), Zr complex and Et2O (-70°C), warming to room temp, stirring (2 h); filtration, pptn. (-30°C); elem. anal.; | 96% |
Conditions | Yield |
---|---|
In tetrahydrofuran at -20℃; for 3.5h; Inert atmosphere; | 96% |
Conditions | Yield |
---|---|
In tetrahydrofuran at 0℃; for 1.5h; Inert atmosphere; | 96% |
Conditions | Yield |
---|---|
In tetrahydrofuran at -78 - 20℃; Inert atmosphere; | 95% |
Conditions | Yield |
---|---|
In tetrahydrofuran at -50 - -45℃; for 3h; Inert atmosphere; | 95% |
Conditions | Yield |
---|---|
In tetrahydrofuran at -30℃; for 2.5h; Inert atmosphere; | 95% |
Conditions | Yield |
---|---|
In tetrahydrofuran at 0℃; for 6h; Inert atmosphere; | 93% |
N,N,N',N'-tetramethylsuccinamide
sodium cyclopentadienylide
4-cyclopenta-2,4-dienylidene-4-dimethylamino-N,N-dimethyl-butyramide
Conditions | Yield |
---|---|
Stage #1: N,N,N',N'-tetramethylsuccinamide With triethyloxonium fluoroborate In dichloromethane at -30 - 20℃; Stage #2: sodium cyclopentadienylide In tetrahydrofuran at -40℃; | 92% |
Conditions | Yield |
---|---|
Stage #1: chloro-trimethyl-silane; sodium cyclopentadienylide In tetrahydrofuran at 0℃; for 2h; Inert atmosphere; Schlenk technique; Stage #2: With n-butyllithium In hexane at 0℃; for 12h; | 92% |
zirconium tetrachloride bis(tetrahydrofuran) complex
(dimethylamino)dibromoborane
sodium cyclopentadienylide
[(CH3)2NB(η(5)-cyclopentadienyl)2]ZrCl2
Conditions | Yield |
---|---|
With BuLi In diethyl ether; hexane byproducts: NaBr; N2 atm., (borane, NaCp (hexane, 0°C), warming to room temp., stirring (2 h), filtration, washing (Et2O), BuLi (hexane, 0°C), warming to room temp., stirring (16 h), Zr complex and Et2O (-70°C), warming to room temp, stirring (2 h); filtration, pptn. (-30°C); elem. anal.; | 91% |
tris(acetonitrile)tricarbonylmolybdenum(0)
phosphoric acid
sodium cyclopentadienylide
hydrido(tricarbonyl)(cyclopentadienyl)molybdenum
Conditions | Yield |
---|---|
Stage #1: tris(acetonitrile)tricarbonylmolybdenum(0); sodium cyclopentadienylide In tetrahydrofuran Inert atmosphere; Stage #2: phosphoric acid In tetrahydrofuran; water Reagent/catalyst; | 90% |
Conditions | Yield |
---|---|
Stage #1: triethylsilyl chloride; sodium cyclopentadienylide In tetrahydrofuran at 0℃; for 4h; Inert atmosphere; Schlenk technique; Stage #2: With n-butyllithium In hexane at 0℃; for 12h; | 90% |
sodium cyclopentadienylide
Conditions | Yield |
---|---|
With calcium borohydride In tetrahydrofuran at 20℃; for 1h; | 89.7% |
(2,7-di-tert-butyl-9H-fluoren-9-yl)chloro(dimethyl)silane
sodium cyclopentadienylide
Cyclopenta-2,4-dienyl-(2,7-di-tert-butyl-9H-fluoren-9-yl)-dimethyl-silane
Conditions | Yield |
---|---|
With N,N,N,N,N,N-hexamethylphosphoric triamide In diethyl ether for 4h; | 88% |
2-Chloroethyl chloroformate
sodium cyclopentadienylide
2-Cyclopentadienylidene-1,3-dioxolane
Conditions | Yield |
---|---|
In acetonitrile at 25℃; for 1h; Product distribution; influence of reagents ratio, solvent and base nature on the yield of reaction; further solvents, further bases; | 86% |
In acetonitrile at 25℃; for 1h; | 86% |
2,6-bis(chloromethyl)pyridine
sodium cyclopentadienylide
2,6-bis(methylenecyclopentadienyl)pyridine disodium salt
Conditions | Yield |
---|---|
In tetrahydrofuran | 85% |
bis(trimethylsilyl)aminodichloroborane
hafnium tetrachloride
sodium cyclopentadienylide
[((CH3)3Si)2NB(η(5)-cyclopentadienyl)2]HfCl2
Conditions | Yield |
---|---|
With BuLi In diethyl ether; hexane N2 atm., (borane, NaCp (hexane, 0°C), warming to room temp., stirring (2 h), filtration, washing (Et2O), BuLi (hexane, 0°C), warming to room temp., stirring (16 h), HfCl4 and Et2O (-70°C), warming to room temp, stirring (2 h); filtration, pptn. (-30°C); elem. anal.; | 85% |
(2-chloroethyl)dimethylamine hydrochloride
sodium cyclopentadienylide
<2-(Dimethylamino)ethyl>cyclopentadien
Conditions | Yield |
---|---|
With N,N,N,N,N,N-hexamethylphosphoric triamide In tetrahydrofuran for 4h; Heating; | 83% |
Conditions | Yield |
---|---|
at 40 - 105℃; for 2.5h; Schlenk technique; Inert atmosphere; | 83% |
Conditions | Yield |
---|---|
In tetrahydrofuran for 24h; Heating; | 82% |
choro(fluoren-9-yl)diphenylsilane
sodium cyclopentadienylide
cyclopentadienyl(fluoren-9-yl)diphenylsilane
Conditions | Yield |
---|---|
With N,N,N,N,N,N-hexamethylphosphoric triamide In diethyl ether for 4h; | 82% |
The IUPAC name of Sodium cyclopentadienide is sodium cyclopenta-1,3-diene. With the CAS registry number 4984-82-1, it is also named as Sodium, 2,4-cyclopentadienide. The product's other registry numbers are 152846-23-6; 223905-48-4; 27081-05-6; 28260-50-6; 36683-96-2; 38785-12-5; 38841-18-8; 63936-05-0; 73500-89-7. Besides, it is white to greyish or yellowish powder, which should be stored in sealed, dark, ventilated and dry place at 2-8 °C. In addition, its molecular formula is C5H5Na and molecular weight is 88.08.
The other characteristics of this product can be summarized as: (1)H-Bond Donor: 0; (2)H-Bond Acceptor: 1; (3)Rotatable Bond Count: 0; (4)Exact Mass: 88.028895; (5)MonoIsotopic Mass: 88.028895; (6)Heavy Atom Count: 6; (7)Complexity: 23.1; (8)EINECS: 225-636-8; (9)Density: 0.946 g/mL at 20 °C; (10)Flash Point: 1 °F.
Preparation of Sodium cyclopentadienide: this chemical is commercially prepared by treating Cyclopentadiene with Sodium:
2 Na + 2 C5H6 → 2 NaC5H5 + H2
Uses of Sodium cyclopentadienide: this chemical is a common reagent used for the preparation of metallocenes, such as the preparation of Ferrocene and Zirconocene dichloride:
2 NaC5H5 + FeCl2 → Fe(C5H5)2 + 2 NaCl
ZrCl4(thf)2 + 2 NaCp → Cp2ZrCl2 + 2 NaCl + 2 THF
When you are using this chemical, please be cautious about it as the following: it is highly flammable that may cause burns. It also may form explosive peroxides. Please keep away from sources of ignition. In case of contact with eyes, please rinse immediately with plenty of water and seek medical advice. And you should wear suitable protective clothing, gloves and eye/face protection. Moreover, in case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
People can use the following data to convert to the molecule structure.
(1)SMILES: [Na]C/1/C=C\C=C\1
(2)InChI: InChI=1/C5H5.Na/c1-2-4-5-3-1;/h1-5H;/rC5H5Na/c6-5-3-1-2-4-5/h1-5H
(3)InChIKey: PDTZVKVFAJGNRV-KEYBYSSPAM
(4)Std. InChI: InChI=1S/C5H5.Na/c1-2-4-5-3-1;/h1-5H
(5)Std. InChIKey: PDTZVKVFAJGNRV-UHFFFAOYSA-N
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